Issue 0, 1971
From the journal:

Journal of the Chemical Society A: Inorganic, Physical, Theoretical


Crystal and molecular structure of [bis(diphenylphosphino)methane]-tetracarbonylmolybdenum

K. K. Cheung,   T. F. Lai  and  K. S. Mok  

Abstract

[Bis(diphenylphosphino)methane]tetracarbonylmolybdenum crystallises in the monoclinic system, space group P21/c, with Z= 4 in a unit cell of dimensions a= 16·33, b= 9·44, c= 18·02 Å, β= 103·8°. After Fourier and least-squares refinement the final R index is 0·112 for 4438 independent reflections. The co-ordination round the molybdenum atom is approximately octahedral. The Mo–C bonds (mean 1·93 Å)trans to phosphorus atoms are significantly shorter than those (mean 2·04 Å)trans to carbon atoms. The mean Mo–P distance is 2·518 Å.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/J19710001644
Article type
Paper

J. Chem. Soc. A, 1971, 1644-1647

Permissions

Request permissions

Crystal and molecular structure of [bis(diphenylphosphino)methane]-tetracarbonylmolybdenum

K. K. Cheung, T. F. Lai and K. S. Mok, J. Chem. Soc. A, 1971, 1644 DOI: 10.1039/J19710001644

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements