Issue 0, 1970
From the journal:

Journal of the Chemical Society A: Inorganic, Physical, Theoretical


Some reactions of rhenium(V) chloride

D. A. Edwards  and  R. T. Ward  

Abstract

The results of some spectroscopic measurements on rhenium(V) chloride are discussed. The reactions of this chloride with either sulphur dioxide or arsenic(III) oxide lead to mixtures of rhenium(VI) oxide tetrachloride and rhenium(III) chloride. With anhydrous tin(II) chloride the pentachloride is quantitatively reduced to the trichloride. The pentachloride is reduced by 2,2′-bipyridyl(bipy) to give ReCl4(bipy), and ammonolysis occurs with liquid ammonia to give [ReCl3(NH2)2,2NH3]n. The oxopentabromorhenate(V) ion results from the reaction of the pentachloride with 48% hydrobromic acid.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/J19700001617
Article type
Paper

J. Chem. Soc. A, 1970, 1617-1620

Permissions

Request permissions

Some reactions of rhenium(V) chloride

D. A. Edwards and R. T. Ward, J. Chem. Soc. A, 1970, 1617 DOI: 10.1039/J19700001617

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements