Issue 24, 1985

6,7-Dimethylene-3-thiabicyclo[3.2.0]heptane-3,3-dioxide, a masked form of [4]dendralene and conjunctive reagent for tandem annelations

Abstract

Previous limitations of highly reactive [4]dendralene [3,4-dimethylenehexa-1,5-diene (1)] as a tandem annelating reagent in Diels–Alder reactions are overcome by use of its masked form, 6,7-dimethylene-3-thiabicyclo[3.2.0]-heptane-3,3dioxide (2), and subsequent extrusion of SO2 under flash vaccum pyrolytic conditions.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1985, 1785-1786

6,7-Dimethylene-3-thiabicyclo[3.2.0]heptane-3,3-dioxide, a masked form of [4]dendralene and conjunctive reagent for tandem annelations

C. M. Buchan, J. I. G. Cadogan, I. Gosney and W. J. Henry, J. Chem. Soc., Chem. Commun., 1985, 1785 DOI: 10.1039/C39850001785

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