SCHEDULED MAINTENANCE
The alkylation reactions of co-ordinated N2 in [M(N2)2(dppe)2](M = Mo or W; dppe = Ph2PCH2CH2PPh2) proceed via a rate-controlling loss of one dinitrogen ligand, co-ordination of alkyl halide, homolytic splitting of the carbon–halogen bond, and attack of the carboncentred free radical upon the remaining dinitrogen ligand.
J. Chatt, R. A. Head, G. J. Leigh and C. J. Pickett, J. Chem. Soc., Chem. Commun., 1977, 299 DOI: 10.1039/C39770000299
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