Issue 11, 2000
From the journal:

Chemical Communications

Novel hepta-coordinated molybdenum(ii) and tungsten(ii) carbene complexes by oxidative decarbonylation of Mo(0) and W(0) carbene complexes

Monika Jaeger,a   Rüdiger Stumpf,a   Carsten Trolla  and  Helmut Fischer*a  

* Corresponding authors

a Fachbereich Chemie, Universität Konstanz, Fach M727, Konstanz, Germany.
E-mail: hfischer@dg6.chemie.uni-konstanz.de

Abstract

C,O-Chelated tetracarbonyl[o-methoxyphenyl(methoxy)- carbene] complexes of molybdenum(0) and tungsten(0) react with tin tetrahalides SnX4 (X = Cl, Br, I) by oxidative decarbonylation and incorporation of two halides to form novel chelated hepta-coordinated Fischer-type tricarbonyl- (bishalogeno)carbene molybdenum(II) and tungsten(II) complexes

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Article information

DOI
https://doi.org/10.1039/B002228O
Article type
Communication
Submitted
16 Mar 2000
Accepted
17 Apr 2000
First published
16 May 2000

Chem. Commun., 2000, 931-932

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Novel hepta-coordinated molybdenum(II) and tungsten(II) carbene complexes by oxidative decarbonylation of Mo(0) and W(0) carbene complexes

M. Jaeger, R. Stumpf, C. Troll and H. Fischer, Chem. Commun., 2000, 931 DOI: 10.1039/B002228O

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