Skip to main content
Log in

Mercury and cadmium pnictidehalides: the inverted Zintl phases

  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

The structures of the mercury and cadmium pnictidehalides MaZbXc (M = Cd, Hg; Z = P, As, Sb; X = Cl, Br, I) are discussed on the basis of the Zintl--Klemm concept. Primary attention is paid to the relationship between the crystal and electronic structures of the compounds in question.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. R. Nesper, Prog. Solid State Chem., 1990, 20, 1.

    Google Scholar 

  2. J.-T. Zhao and J. D. Corbett, Inorg. Chem., 1995, 34, 378.

    Google Scholar 

  3. R. Ramirez, R. Nesper, H. G. von Schnering, and M. C. Bohm, J. Phys. Chem. Solids, 1987, 48, 51.

    Google Scholar 

  4. C. Zheng and R. Hoffmann, Z. Naturforsch., Teil B, 1986, 41, 292.

    Google Scholar 

  5. R. Hoffmann and C. Zheng, J. Phys. Chem., 1985, 89, 4175.

    Google Scholar 

  6. T. Y. Kuromoto, S. M. Kauzlarich, and D. J. Webb, Chem. Mater., 1992, 4, 435.

    Google Scholar 

  7. A. V. Shevelkov, E. V. Dikarev, R. V. Shpanchenko, and B. A. Popovkin, J. Solid State Chem., 1995, 114, 379.

    Google Scholar 

  8. R. Nesper, J. Curda, and H. G. von Schnering, Angew. Chem., Int. Ed. Engl., 1986, 25, 350.

    Google Scholar 

  9. B. Eisenmann and R. Kniep, Z. Anorg. Allg. Chem., 1991, 589–590, 213.

    Google Scholar 

  10. K. H. Lii and R. C. Haushalter, J. Solid State Chem., 1992, 67, 374.

    Google Scholar 

  11. J.-T. Zhao and J. D. Corbett, Inorg. Chem., 1994, 33, 5721.

    Google Scholar 

  12. E. Zintl and W. Dullenkopf, Z. Phys. Chem., 1932, B16, 195.

    Google Scholar 

  13. P. C. Schmidt, D. Stahl, B. Eisenmann, R. Kniep, V. Egert, and J. Kubler, J. Solid State Chem., 1992, 97, 93.

    Google Scholar 

  14. M. Asbrand, F. J. Berry, B. Eisenmann, R. Kniep, L. E. Smart, and R. C. Thied, J. Solid State Chem., 1995, 118, 397.

    Google Scholar 

  15. R. B. King, Inorg. Chem., 1989, 28, 3048.

    Google Scholar 

  16. G. Menge and H. G. von Schnering, Z. Anorg. Allg. Chem., 1976, 422, 219.

    Google Scholar 

  17. W. Jeitschko and D. J. Braun, Acta Crystallogr., Sect. B, 1978, 34, 3196.

    Google Scholar 

  18. D. J. Braun and W. Jeitschko, Z. Anorg. Allg. Chem., 1978, 445, 157.

    Google Scholar 

  19. H. Krebs, K. H. Müller, and G. Zürn, Z. Anorg. Allg. Chem., 1956, 285, 15.

    Google Scholar 

  20. M. Llunell, S. Alvarez, P. A. Alemany, and R. Hoffmann, Inorg. Chem., 1996, 35, 4683.

    Google Scholar 

  21. A. Rebbah, J. Yazbeck, and A. Deschanvres, Rev. Chim. Miner., 1981, 19, 43.

    Google Scholar 

  22. A. V. Shevelkov, E. V. Dikarev, and B. A. Popovkin, Zh. Neorgan. Khim., 1997, 42, 1242 [Russ. J. Inorg. Chem., 1997, 42 (Engl. Transl.)].

    Google Scholar 

  23. A. V. Shevelkov, L. N. Reshetova, and B. A. Popovkin, J. Solid State Chem., 1998, 137, 138.

    Google Scholar 

  24. P. C. Donohue, J. Solid State Chem., 1972, 5, 71.

    Google Scholar 

  25. I. Kassama, M. Kheit, and A. Rebbah, J. Solid State Chem., 1994, 113, 248.

    Google Scholar 

  26. M. M. Shatruk, L. N. Reshetova, A. V. Shevelkov, and B. A. Popovkin, Zh. Neorg. Khim., 2000, 45, 565 [Russ. J. Inorg. Chem., 2000, 45 (Engl. Transl.)].

    Google Scholar 

  27. A. Rebbah, J. Yazbeck, and A. Deschanvres, Acta Crystallogr., Sect. B, 1980, 36, 1747.

    Google Scholar 

  28. A. Rebbah, J. Yazbeck, and A. Deschanvres, Acta Crystallogr., Sect. B, 1980, 36, 1744.

    Google Scholar 

  29. L. Suchow and N. R. Stemple, J. Electrochem. Soc., 1963, 110, 766.

    Google Scholar 

  30. A. Rebbah, J. Yazbeck, A. Leclaire, and A. Deschanvres, Acta Crystallogr., Sect. B, 1980, 36, 771.

    Google Scholar 

  31. A. V. Shevelkov, L. N. Reshetova, and B. A. Popovkin, J. Solid State Chem., 1997, 134, 282.

    Google Scholar 

  32. S. M. Gasinets, M. V. Potorii, I. D. Olekseyuk, E. A. Yantso, and M. I. Markovich, Ukr. Khim. Zh., 1990, 56, 123.

    Google Scholar 

  33. A. V. Shevelkov, E. V. Dikarev, and B. A. Popovkin, J. Solid State Chem., 1994, 113, 116.

    Google Scholar 

  34. J. Gallay, G. Allais, and A. Deschanvres, Acta Crystallogr., Sect. B, 1975, 31, 2274.

    Google Scholar 

  35. A. Rebbah, A. Leclaire, J. Yazbeck, and A. Deschanvres, Acta Crystallogr., Sect. B., 1979, 35, 2197.

    Google Scholar 

  36. A. V. Shevelkov, E. V. Dikarev, and B. A. Popovkin, J. Solid State Chem., 1991, 93, 331.

    Google Scholar 

  37. L. N. Reshetova, A. V. Shevelkov, and B. A. Popovkin, Zh. Koordinats. Khim., 1999, 25, 819 [Russ. J. Coord. Chem., 1999, 25 (Engl. Transl.)].

    Google Scholar 

  38. P. Lemoult, C. R. Acad. Sci., 1907, 9, 1175.

    Google Scholar 

  39. A. V. Olenev, Degree Thesis, Moscow State University, Moscow, 1998, 70 pp. (in Russian).

  40. A. V. Shevelkov, E. V. Dikarev, and B. A. Popovkin, J. Solid State Chem., 1996, 126, 24.

    Google Scholar 

  41. A. V. Olenev, A. V. Shevelkov, and B. A. Popovkin, J. Solid State Chem., 1998, 142, 14.

    Google Scholar 

  42. A. V. Shevelkov, M. Yu. Mustyakimov, M. M. Shatruk, and B. A. Popovkin, Zh. Neorgan. Khim., 1998, 43, 1069 [Russ. J. Inorg. Chem., 1998, 43 (Engl. Transl.)].

    Google Scholar 

  43. A. V. Shevelkov, E. V. Dikarev, and B. A. Popovkin, Z. Kristallogr., 1994, 209, 583.

    Google Scholar 

  44. A. V. Shevelkov, M. Yu. Mustyakimov, E. V. Dikarev, and B. A. Popovkin, J. Chem. Soc., Dalton Trans., 1996, 147.

  45. M. Ledésert, A. Rebbah, and Ph. Labbé, Z. Kristallogr., 1990, 192, 223.

    Google Scholar 

  46. A. V. Shevelkov, E. V. Dikarev, and B. A. Popovkin, J. Solid State Chem., 1993, 104, 77.

    Google Scholar 

  47. A. V. Shevelkov, E. V. Dikarev, and B. A. Popovkin, Zh. Neorgan. Khim., 1995, 40, 1496 [Russ. J. Inorg. Chem., 1995, 40 (Engl. Transl.)].

    Google Scholar 

  48. Ph. Labbé, M. Ledésert, B. Raveau, and A. Rebbah, Z. Kristallogr., 1989, 187, 117.

    Google Scholar 

  49. A. V. Shevelkov, E. V. Dikarev, and B. A. Popovkin, J. Solid State Chem., 1992, 98, 133.

    Google Scholar 

  50. H. Puff and H. Gotta, Z. Anorg. Allg. Chem., 1966, 343, 225.

    Google Scholar 

  51. A. V. Shevelkov, E. V. Dikarev, and B. A. Popovkin, Z. Anorg. Allg. Chem., 1994, 620, 389.

    Google Scholar 

  52. A. F. Wells, Structural Inorganic Chemistry, 5th ed., Clarendon Press, Oxford, 1984.

    Google Scholar 

  53. H. G. von Schnering, Angew. Chem., Int. Ed. Engl., 1981, 20, 33.

    Google Scholar 

  54. H. G. von Schnering and W. Hönle, Chem. Rev., 1988, 88, 243.

    Google Scholar 

  55. R. J. Gillespie and I. Hargittai, The VSEPR Model of Molecular Geometry, Allyn and Bacon, Boston, 1991.

    Google Scholar 

  56. P. C. Donohue, J. Solid State Chem., 1973, 6, 587.

    Google Scholar 

  57. E. N. Morozova, Degree Thesis, Moscow State University, Moscow, 1997, 61 pp. (in Russian).

  58. M. M. Shatruk, Ph. D. Thesis (Chem.), Moscow State University, Moscow, 2000, 164 pp. (in Russian).

  59. M. M. Shatruk, A. V. Olenev, A. V. Shevelkov, and B. A. Popovkin, Zh. Neorgan. Khim., 1997, 42, 1610 [Russ. J. Inorg. Chem., 1997, 42 (Engl. Transl.)].

    Google Scholar 

  60. J. Winter, Magnetic Resonance in Metals, Clarendon Press, Oxford, 1971, 297 pp.

    Google Scholar 

  61. L. A. Bengtsson-Kloo and A. V. Shevelkov, Final Report on the SI Grant, Lund University, 1998, 7 pp.

  62. J. H. Ammeter, H. B. Bürgi, J. C. Thibeaut, and R. Hoffmann, J. Am. Chem. Soc., 1978, 100, 3686.

    Google Scholar 

  63. A. V. Shevelkov, VI European Conf. Solid State Chem., Book of Abstracts (Zürich, September 17–20), Zürich, 1997, ML7.

  64. M. Yu. Mustyakimov, Degree Thesis, Moscow State University, Moscow, 1995, 70 pp. (in Russian).

  65. J. Clark and K. J. Range, Z. Naturforsch., Teil B, 1976, 31, 158.

    Google Scholar 

  66. Chemistry, Structure and Bonding of Zintl Phases and Ions, Ed. S. M. Kauzlarich, VCH Publishers, New York, 1996, 245.

    Google Scholar 

  67. D. Huang and J. D. Corbett, Inorg. Chem., 1998, 37, 5007.

    Google Scholar 

  68. M. M. Shatruk, K. A. Kovnir, and A. V. Shevelkov, VII European Conf. Solid State Chem., Book of Abstracts (Madrid, September 15–18), Madrid, 1999, O11.

  69. M. M. Shatruk, K. A. Kovnir, A. V. Shevelkov, I. A. Presniakov, and B. A. Popovkin, Inorg. Chem., 1999, 38, 3455.

    Google Scholar 

  70. G. J. Miller, Eur. J. Inorg. Chem., 1998, 523.

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Shevelkov, A.V., Shatruk, M.M. Mercury and cadmium pnictidehalides: the inverted Zintl phases. Russian Chemical Bulletin 50, 337–352 (2001). https://doi.org/10.1023/A:1011351532249

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1011351532249

Navigation