Skip to main content
Log in

Nanoscale Iron Particles for Environmental Remediation: An Overview

  • Published:
Journal of Nanoparticle Research Aims and scope Submit manuscript

Abstract

Nanoscale iron particles represent a new generation of environmental remediation technologies that could provide cost-effective solutions to some of the most challenging environmental cleanup problems. Nanoscale iron particles have large surface areas and high surface reactivity. Equally important, they provide enormous flexibility for in situ applications. Research has shown that nanoscale iron particles are very effective for the transformation and detoxification of a wide variety of common environmental contaminants, such as chlorinated organic solvents, organochlorine pesticides, and PCBs. Modified iron nanoparticles, such as catalyzed and supported nanoparticles have been synthesized to further enhance the speed and efficiency of remediation. In this paper, recent developments in both laboratory and pilot studies are assessed, including: (1) synthesis of nanoscale iron particles (10–100nm, >99.5% Fe) from common precursors such as Fe(II) and Fe(III); (2) reactivity of the nanoparticles towards contaminants in soil and water over extended periods of time (e.g., weeks); (3) field tests validating the injection of nanoparticles into aquifer, and (4) in situ reactions of the nanoparticles in the subsurface.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  • DOE (US Department of Energy), 2002. http://www.science. doe.gov/grants/Fr02-03.html.

  • Elliott D. & W. Zhang, 2001. Field assessment of nanoparticles for groundwater treatment. Environ. Sci. Technol. 35, 4922–4926.

    Google Scholar 

  • EPA (US Environmental Protection Agency), 2003a. Superfund National Priorities List (NPL). http://www.epa.gov/ superfund/sites/npl/index.htm.

  • EPA (US Environmental Protection Agency), 2003b. Underground storage tanks. http://www.epa.gov/swerust1/cat/ index.htm.

  • EPA (US Environmental Protection Agency), 2003c. Databases of innovative technologies. http://www.epa.gov/tio/databases/.

  • EPA (US Environmental Protection Agency), 2003d. Technology Innovation Office, Permeable Reactive Barriers. http:// clu-in.org/.

  • EPA (US Environmental Protection Agency), 2003e. Workshop on Nanotechnology and the Environment. August 28-29, 2002. Arlington, Virginia. P50-51 EPA/600/R-02/080.

  • Gillham R.W. & S.F. O'Hannesin, 1994. Enhanced degradation of halogenated aliphatics by zero-valent iron. Ground Water 32, 958–967.

    Google Scholar 

  • Glazier R., R. Venkatakrishnan, F. Gheorghiu, L. Walata, R. Nash & W. Zhang, 2003. Nanotechnology takes root. Civil Engineering 73(5), 64–69.

    Google Scholar 

  • Lien H., 2000. Nanoscale bimetallic particles for dehalogenation of halogenated aliphatic compounds. Unpublished Dissertation, Lehigh University, Bethlehem, Pennsylvania.

    Google Scholar 

  • Lien H. & W. Zhang, 1999. Reactions of chlorinated methanes with nanoscale metal particles in aqueous solutions. J. Environ. Eng. 125(11), 1042–1047.

    Google Scholar 

  • Lien H. & W. Zhang, 2001. Complete dechlorination of chlorinated ethenes with nanoparticles. Colloids Surfaces A 191, 97–105.

    Google Scholar 

  • Masciangioli T. & W. Zhang, 2003. Environmental nanotechnology: Potential and pitfalls. Environ. Sci. Technol. 37, 102A–108A.

    Google Scholar 

  • O'Hannesin S.F. & R.W. Gillham, 1998. Long-term performance of an in situ -ironwall- for remediation ofVOCs. GroundWater 36, 164–170.

    Google Scholar 

  • Orth W.S. & R.W. Gillham, 1996. Dechlorination of trichloroethene in aqueous solution using Fe(0). Environ. Sci. Technol. 30, 66–71.

    Google Scholar 

  • Ponder S.M., J.G. Darab & T.E. Mallouk, 2000. Remediation of Cr(VI) and Pb(II) aqueous solutions using supported, nanoscale zero-valent iron. Environ. Sci. Technol. 34, 2564–2569.

    Google Scholar 

  • Ponder S., J.G. Darab, J. Bucher, D. Caulder, I. Craig, L. Davis, N. Edelstein, W. Lukens, H. Nitsche, L. Rao, D.K. Shuh & T.E. Mallouk. 2001. Surface chemistry and electrochemistry of supported zerovalent iron nanoparticles in the remediation of aqueous metal contaminants. Chem. Mater. 13(2), 479–486.

    Google Scholar 

  • Schrick B., J. Blough, A. Jones & T.E. Mallouk, 2002. Hydrodechlorination of trichloroethylene to hydrocarbons using bimetallic nickel-iron nanoparticles. Chem. Mater. 14(12), 5140–5147.

    Google Scholar 

  • Wang C. & W. Zhang, 1997. Nanoscale metal particles for dechlorination of PCE and PCBs. Environ. Sci. Technol. 31(7), 2154–2156.

    Google Scholar 

  • Xu Y. & W. Zhang, 2000. Subcolloidal Fe/Ag particles for reductive dehalogenation of chlorinated benzenes. Indus. Eng. Chem. Res. 39(7), 2238–2244.

    Google Scholar 

  • Zhang W., C. Wang & H. Lien, 1998. Catalytic reduction of chlorinated hydrocarbons by bimetallic particles. Catal. Today 40(4), 387–395.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Zhang, Wx. Nanoscale Iron Particles for Environmental Remediation: An Overview. Journal of Nanoparticle Research 5, 323–332 (2003). https://doi.org/10.1023/A:1025520116015

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1025520116015

Navigation