Technetium Tetrachloride Revisited: A Precursor to Lower-Valent Binary Technetium Chlorides

Johnstone, Erik V.; Poineau, Frederic; Forster, Paul M.; Ma, Longzou; Hartmann, Thomas; Cornelius, Andrew; Antonio, Daniel; Sattelberger, Alfred P.; Czerwinski, Kenneth R.

doi:10.1021/ic301011c

Title: Technetium Tetrachloride Revisited: A Precursor to Lower-Valent Binary Technetium Chlorides

Journal Article · Mon Jul 09 00:00:00 EDT 2012 · Inorganic Chemistry

DOI:https://doi.org/10.1021/ic301011c· OSTI ID:1307429

Johnstone, Erik V. ^[1]; Poineau, Frederic ^[1]; Forster, Paul M. ^[1]; Ma, Longzou ^[2]; Hartmann, Thomas ^[2]; Cornelius, Andrew ^[3]; Antonio, Daniel ^[3]; Sattelberger, Alfred P. ^[4]; Czerwinski, Kenneth R. ^[1]

Univ. of Nevada, Las Vegas, NV (United States). Dept. of Chemistry
Univ. of Nevada, Las Vegas, NV (United States). Harry Reid Center for Environmental Studies
Univ. of Nevada, Las Vegas, NV (United States). Dept. of Physics and Astronomy
Univ. of Nevada, Las Vegas, NV (United States). Dept. of Chemistry; Argonne National Lab. (ANL), Argonne, IL (United States)

Technetium (Tc) is the lightest element that doesn't occur in nature. At UNLV, our radiochemistry program gives us access to Tc and the ability to make various Tc compounds. Here we describe the preparation and characterization of TcCl₄. The Tc atom is found to have a magnetic moment and magnetically orders at low temperature. As discerning trends in the transition metals, of which Tc is one, is important for understanding all transition metal compounds, this research is relevant to understanding these materials.

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Research Organization:: Univ. of Nevada, Las Vegas, NV (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0005278; 47824B

OSTI ID:: 1307429

Report Number(s):: DOE-UNLV-05278

Journal Information:: Inorganic Chemistry, Vol. 51, Issue 15; ISSN 0020-1669

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 14 works

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References (37)

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From Tc ^VII to Tc ^I ; facile syntheses of bis-arene complexes [ ^99(m) Tc(arene) ₂ ] ⁺ from pertechnetate Benz, Michael; Braband, Henrik; Schmutz, Paul Chemical Science, Vol. 6, Issue 1 https://doi.org/10.1039/c4sc02461c	journal	January 2015

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36 MATERIALS SCIENCE
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Technetium
Magnetism
Transition Metal

Title: Technetium Tetrachloride Revisited: A Precursor to Lower-Valent Binary Technetium Chlorides

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