Recycling high volume Fe-rich fayalite slag in blended alkali-activated materials: Effect of ladle and blast furnace slags on the fresh and hardened state properties

https://doi.org/10.1016/j.jobe.2022.105436Get rights and content
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Highlights

  • Fe-rich fayalite slag upcycling in blended alkali-activated materials (AAMs) was elucidated.

  • The incorporation of ladle slag (LS) or blast furnace slag (BFS) provided additional Ca and Al needed for higher reactivity.

  • The addition of LS or BFS improved the fresh and hardened properties of the AAMs at ambient temperature.

  • Embedding LS or BFS results in a denser microstructure of the mortars.

  • The results provided an insight for designing eco-friendly AAMs for use in building and construction industry.

Abstract

The valorization of Fe-rich fayalite slag (FS) as a precursor for alkali-activated materials (AAMs) is hampered by its low reactivity at ambient temperature. Here, FS was blended with waste-based reactive co-binders such as ladle slag (LS) and blast furnace slag (BFS) to improve the fresh and hardened state properties of the AAMs for potential construction applications. The results showed that the incorporation of LS and BFS as an additional source of Ca and Al accelerated the reaction kinetics and influenced the binder gel type and formation mechanism. In all the mixes, Fe, Si and Na are present in the evolving binder gel. In addition to these elements, the binder gel of the blended formulations is also rich in higher quantities of Ca and Al and showed possible formation of C-A-S-H and C-(N)-A-S-H together with the development of andradite, a calcium ferrosilicate hydrate phase formed from chemical interaction between FS and co-binders; it indicates that both FS and co-binder participated in the binder gel formation. Furthermore, the nucleating and filling effects of co-binders improved the workability, ultrasonic pulse velocity and mechanical properties; this also densified the structure and lowered the water absorption and permeable porosity of the blended mortars. The compressive strength of blended mortars was above 20 MPa, thus satisfying the strength requirements of building materials according to ASTM C62. The results of this study emphasize the reuse potential of FS with other waste streams in producing eco-friendly AAMs, which can have a wide range of construction applications.

Keywords

Blended mortar
Ladle slag
Blast furnace slag
Fe-rich fayalite slag
Alkali-activated materials
Geopolymers

Data availability

Data will be made available on request.

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