On the Way to Carbene and Carbyne Complexes*
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50 Years of Passion for Organometallic Chemistry
2023, Journal of Organometallic ChemistryAlkylidene Complexes of the Group 3 Metals and Lanthanides
2022, Comprehensive Organometallic Chemistry IV: Volume 1-15A quantum chemical investigation of the influence of solvent polarity on the structural, electronic, spectroscopic properties and hyperpolarizability in Molybdenum Silylidyne complex CpMo(CO)<inf>2</inf>([tbnd]Si–Ph)
2018, Journal of Molecular LiquidsCitation Excerpt :The synthesis, structure, reactivity and properties of theses complexes stimulated many studies in the organometallics area [2–6]. They are contributed in numerous catalytic transformations [7–11]. In comparison, there are silicon analogues of the alkylidyne complexes [12], a series of compounds featuring metalgermanium, metaltin, or metallead triple bonds have been obtained by reacting carbonyl metalates [13,14].
Recent advances in the chemistry of transition metal–silicon/germanium triple-bonded complexes
2018, Coordination Chemistry ReviewsCitation Excerpt :This value, however, is also shifted downfield in comparison with the corresponding signal of the precursor, i.e., bromosilylene complex 39 (74.8 ppm). As documented in several review articles [1–8], carbyne complexes react with various organic substrates at the MC triple bonds and are used for transformation of organic molecules. Germylyne and silylyne complexes are also expected to show interesting reactivity arising from the ME triple bonds (E = Ge, Si).
Non-heteroatom-substituted alkylidene complexes of groups 10 and 11
2018, Coordination Chemistry ReviewsCitation Excerpt :Under these conditions products resulting from H2 splitting were detected. The reactivity of the nucleophilic palladium alkylidene containing coordinated PMe3, i.e. (PCcarbeneP)Pd (PMe3), towards C–H bonds of different acidity was also tested (Scheme 14) [43]. For instance, PhCCH, with pKa = 28.7, underwent C–H addition across the Pd–C bond, with formation of the alkenyl-(PCalkylP)–Pd(II) complex, [PC(H)alkylP]Pd (CCPh).
Synthesis of Organometallic Compounds
2017, Modern Inorganic Synthetic Chemistry: Second Edition
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A Nobel lecture translated by P. Legzdins and G.O. Wiedersatz, Technical Uni-versity, Munich. Copyright © The Nobel Foundation, 1974.