The oxidation of aldehydes to acids with calcium hypochlorite [Ca(OCl)2]
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Chemical decontamination of methamphetamine and ephedrine using household hypochlorite bleach
2023, Forensic ChemistrySimple and low-cost transition metal-free borophosphate glass catalyst for aromatic alcohol oxidation by sodium hypochlorite
2022, Journal of Materials Research and TechnologyCitation Excerpt :Stevens and co-workers applied “Swimming Pool Chlorine” (an inexpensive commercial sodium hypochlorite solution) to oxidize secondary alcohols to ketones [21] and diols/aldehydes to their respective ketones and methyl esters [22]. At the same time, calcium hypochlorite was applied to oxidize secondary methyl ethers into ketones [23], aldehydes to their corresponding carboxylic acids [24], secondary alcohols to ketones, primary alcohols to esters, and ethers to esters [25]. All these applications report hypochlorite as a versatile, effective, safer, and potential substitute for traditional chromium VI salts [3] and pyridine-based [4] oxidants in organic synthesis.
Oxidation of petroleum-based byproducts diformyltricyclodecanes (DFTD) with O<inf>2</inf> under catalyst-free and ultra-low temperature
2020, Chinese Journal of Chemical EngineeringSelective solvent free oxidation of aldehydes to carboxylic acids over anchored 12-tungstophosphoric acid using different oxidants
2015, Journal of the Taiwan Institute of Chemical EngineersCitation Excerpt :But these conventional oxidants based on chromium [7–9], produce copious amounts of undesirable waste. Other reagents that have been reported in the literature to achieve such a transformation include oxone [10], calcium hypochlorite [11] and 2-hydroperoxyhexafluoro-2-propanol [12]. However, these processes make excessive use of oxidants and organic solvents.
Efficient method for the oxidation of aldehydes and diols with tert-butylhydroperoxide under transition metal-free conditions
2013, TetrahedronCitation Excerpt :For example, metal-mediated oxidations were reported employing Ca,9 Ni,10 Se,11 Mg,12 W,13 Co,14 Pd,15 V,16 Mo,17 and Au.18 Sedelmeier, Ley, and Baumann together disclosed to achieve oxidation of aldehydes to carboxylic acids employing stoichiometric amount of oxidant KMnO4/NaH2PO4.19 The combination of metal catalyst CuCl,20 AgNO3,21 Bi2O3,22 with stoichiometric oxidants TBHP or H2O2 were also described in literature.
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Dreyfus Teacher-Scholar 1979–1984.