Nickel carbonyl: toxicity and human health
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Cited by (53)
Hydrogenation of CO and CO<inf>2</inf>: Contributions of IR operando studies
2023, Catalysis TodayCitation Excerpt :Weakly adsorbed CO, for instance on metallic copper, could readily desorb, while strongly bound species could be dissociated or react with redox oxides present, as observed with ceria-based catalysts near [45] or at room temperature [46,47]. An insidious pitfall of using feeds containing CO is the potential presence of the (highly toxic [48,49]) volatile compound Ni(CO)4, which may result in catalyst and cell contaminations. An example can be found in a study dealing with CO reactivity over mixed oxides of ceria and zirconia [50], in which the authors did not realize that their feed was contaminated with Ni(CO)4, as evidenced by the presence of a band near 2055 cm-1 typical of this compound [51] (Fig. 4).
On the reality of negatively charged supported gold nanoparticles
2023, Journal of CatalysisThe emergence of zerovalent carbon compounds from structural curiosities to organocatalysts
2023, Cell Reports Physical ScienceIn situ formation of Ni(CO)<inf>4</inf> contaminant during IR analyses using a metal-containing reaction cell
2022, Catalysis Science and Technology
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