Sur de nouvelles phases sulfurées ternaires du molybdène

https://doi.org/10.1016/0022-4596(71)90095-8Get rights and content

Abstract

The authors describe the preparation of new sulfides of formula MIIMonSn + 1. If M = Ag, Sn, Ca, Sr, Pb, Ba, they are stoichiometric; if M = Ni, Co, Fe, Cr, Mn, Cu, Mg, Zn, Cd, solid solutions are observed with 2 ⩽ n ⩽ 6. Another series of formula M2MonSn + 1 was also prepared, where M = alkali metal and n = 2 or 5. The crystallographic properties are investigated: the phases obtained are generally rhomboedral, with an eventual triclinic distortion.

Références (10)

  • M. Sergent et al.

    C.R. Acad. Sci. C

    (1965)
  • M. Sergent

    Thèse de Doctorat d'Etat

    (1969)
  • R. Chevrel et al.

    C.R. Acad. Sci. C

    (1968)
  • J. Guillevic et al.

    Bull. Soc. Fr. Minéral. Cristallogr.

    (1970)
  • R. Chevrel et al.

    C.R. Acad. Sci. C

    (1970)
There are more references available in the full text version of this article.

Cited by (486)

  • Chevrel phase: A review of its crystal structure and electrochemical properties

    2023, Progress in Natural Science: Materials International
View all citing articles on Scopus
View full text