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A Revised Periodic Table: With the Lanthanides Repositioned

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Abstract

The lanthanide elements from lanthanum to lutetium inclusive are incorporated into the body of the periodic table. They are subdivided into three sub-groups according to their important oxidation states: La to Sm, Eu to Tm, Yb and Lu, so that Eu and Yb fall directly below Ba; La, Gd, Lu form a column directly below Y; Ce and Tb fall in a vertical line between Zr and Hf. Pm falls below Tc; both are radioactive, and not naturally occurring. The elements with easily attained 2+ and 4+ oxidation states are grouped and clearly differentiated. Gadolinium has an important position as the centre of four triads in the block of elements that surround it– La, Gd, Lu; Ba, Gd, Hf; Eu, Gd, Tb; Yb, Gd, Ce. This new arrangement has the advantages of compactness, simplicity and clarity – there are no tie lines; and important oxidation states of these metals are emphasized. The actinides are also accommodated within this system, and element 114 falls naturally below lead in Group 14.

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References

  • Bartlett J. Pliny the Elder, Ex Africa semper aliquid novi, p. 117; Ecclesiastes I:9, and there is no new thing under the sun, p. 26. Familiar Quotations, 15th edn. London: Macmillan, 1980.

  • WH. Brock (1992) The Fontana History of Chemistry Harper Collins London 327

    Google Scholar 

  • NM. Brooks (2002) ArticleTitleDeveloping the Periodic Law: Mendeleev’s Work During 1869–1871 Found. Chem. 4 127–147 Occurrence Handle10.1023/A:1016022129746

    Article  Google Scholar 

  • ED. Cater (1978) ArticleTitleHigh Temperature Chemistry of Rare Earth Compounds: Dramatic Examples of Periodicity J. Chem. Educ. 55 697–701

    Google Scholar 

  • RM. Caven GD. Lander (1939) Systematic Inorganic Chemistry 6th edn Blackie Glasgow 28

    Google Scholar 

  • F.A. Cotton, G. Wilkinson, C.A. Murillo and M. Bochmann. Advanced Inorganic Chemistry, 6th edn. New York: John Wiley, 1999, pp. 1108–1129.

  • S.A. Cotton. Scadium, Yttrium and the Lanthanides. In R.B. King (Ed.), Encyclopedia of Inorganic Chemistry, Vol. 7, p. 3596. New York: John Wiley, 1994.

  • MW. Cronyn (2003) ArticleTitleThe Proper Place for Hydrogen in the Periodic Table J. Chem. Educ. 80 947–951

    Google Scholar 

  • E.S. Dana. A Textbook of Mineralogy, 4th edn. rev. W.E. Ford. New York: John Wiley, 1932, pp. 526, 620, 634.

  • HC. Deming (1925) General Chemistry John Wiley New York 190

    Google Scholar 

  • D. Vault Particlede (1944) J. Chem. Educ. 21 575–581

    Google Scholar 

  • J. Donohue. The Structures of the Elements. New York: John Wiley, 1974, pp. 88–95 (cerium), 103–105 (gadolinium), 124 (summary of physical characteristics).

  • B.E. Douglas, D.H. McDaniel and J.J. Alexander. Concepts and Models of Inorganic Chemistry, 3rd edn. New York: John Wiley, 1994, pp. 28–29, 732–738.

  • J. Emsley (1989) The Elements Clarendon Press Oxford 241–245

    Google Scholar 

  • HG. Friedman GR. Choppin DG. Feuerbacher (1964) ArticleTitleThe Shapes of the f Orbitals J. Chem. Educ. 41 354–358

    Google Scholar 

  • N.N. Greenwood and A. Earnshaw. Chemistry of the Elements. Oxford: Pergamon, 1984, pp. 1104–1107, 1114–1115, 1423–1434.

  • F.A. Hart. Scandium, Yttrium and the Lanthanides. In G. Wilkinson, R.D.Gillard and J.A. McCleverty (Eds.), Comprehensive Coordination Chemistry. Vol. 3, pp. 1059–1127. Oxford: Pergamon, 1987.

  • D.C. Hoffman and D.M. Lee. Chemistry of the Heaviest Elements–One Atom at a Time. J.Chem. Educ. 76: 332–347, 1999. Note the unusual format of the actinide series in the periodic table on p. 334.

    Google Scholar 

  • J.A. Huheey, E.A. Keiter and R.L. Keiter. Inorganic Chemistry 4th edn. New York: Harper Collins, 1993, pp. 114–117 (M3+ radii), pp. 599–612.

  • A.J. Ihde. The Development of Modern Chemistry. New York: Dover, 1984. Brauner, p. 252; Werner, 254; Rare earths, 374; Moseley and Bohr, 588–594.

  • WB. Jensen (1982) ArticleTitleThe Positions of Lanthanum (Actinium) and Lutetium (Lawrencium) in the Periodic Table J. Chem. Educ. 59 634–636

    Google Scholar 

  • DA. Johnson (1980) ArticleTitlePrinciples of Lanthanide Chemistry J. Chem. Educ. 57 475–477

    Google Scholar 

  • DA. Johnson (1982) Some Thermodynamic Aspects of Inorganic Chemistry. 2nd edn CUP Cambridge 158–168

    Google Scholar 

  • M. Kaji DI. Mendeleev’s (2002) ArticleTitleConcept of Chemical Elements and The Principles of Chemistry Bull. Hist. Chem. 27 4–16

    Google Scholar 

  • PJ. Karol (2002) ArticleTitleThe Mendeleev-Seaborg Periodic Table: Through Z = 1138 and Beyond J. Chem. Educ. 79 60–63

    Google Scholar 

  • RN. Keller (1962) ArticleTitleEnergy Level Diagrams and Extranuclear Building of the Elements J. Chem. Educ. 39 289–293

    Google Scholar 

  • H. Kragh (2001) ArticleTitleThe First Subatomic Explanations of the Periodic System Found. Chem. 3 129–143 Occurrence Handle10.1023/A:1011448410646

    Article  Google Scholar 

  • T.S. Kuhn. The Structure of Scientific Revolutions, 2nd edn. Chicago: U. of Chicago Press, 1970, pp. 59, 62, 71, 80, 85, 109 especially.

  • M. Laing (1989) ArticleTitleThe Periodic Table–again Educ. Chem. 26 177–178

    Google Scholar 

  • M. Laing (1999) ArticleTitleThe Knight’s Move in the Periodic Table Educ. Chem. 36 160–161

    Google Scholar 

  • M. Laing (2001a) ArticleTitlePeriodic Patterns J. Chem. Educ. 78 877

    Google Scholar 

  • M. Laing (2001b) ArticleTitleMelting Point, Density, and Reactivity of Metals J. Chem. Educ. 78 1054–1058

    Google Scholar 

  • M. Laing (2001c) ArticleTitleHow Useful is Electron Configuration s2? Educ. Chem. 38 161–163

    Google Scholar 

  • PF. Lang BC. Smith (2003) ArticleTitleIonization Energies of Atoms and Atomic Ions J. Chem. Educ. 80 938–946

    Google Scholar 

  • EG. Mazurs (1974) Graphic Representations of the Periodic System During One Hundred Years 2nd edn U of Alabama Press Alabama 40–42

    Google Scholar 

  • J.W. Mellor G.D. Parkes (Eds) (1951) Mellor’s Modern Inorganic Chemistry Longmans Green, London

    Google Scholar 

  • T. Moeller (1965) The Chemistry of the Lanthanides Chapman and Hall London

    Google Scholar 

  • T. Moeller (1970) ArticleTitlePeriodicity and the Lanthanides and Actinides J. Chem. Educ. 47 417–423

    Google Scholar 

  • Moeller T. The Lanthanides. In J.C. Bailar, H.J. Emeleus, R. Nyholm and A.F. Trotman-Dickenson (Eds), Comprehensive Inorganic Chemistry. Vol 4, pp. 1–101, especially p. 6 and 21. Oxford: Pergamon, 1973.

  • H.G.J. Moseley. The High Frequency Spectra of the Elements. Phil. Mag. 26: 1024–1034, 1913, and 27: 703–713, 1914.

  • RV. Parish (1977) The Metallic Elements Longman London 142–155

    Google Scholar 

  • JR. Partington (1937) A Text-Book of Inorganic Chemistry 5th edn. Macmillan London 411

    Google Scholar 

  • KS. Pitzer (1979) ArticleTitleRelativistic Effects on Chemical Properties Acc. Chem. Res. 12 271–276 Occurrence Handle10.1021/ar50140a001

    Article  Google Scholar 

  • P. Pyykkö JP. Desclaux (1979) ArticleTitleRelativity and the Periodic System of Elements Acc. Chem. Res. 12 276–281

    Google Scholar 

  • P. Pyykkö (2002) ArticleTitleRelativity, Gold, Closed-Shell Interactions Angewandte Chemie International Edition. 41 3573–3578

    Google Scholar 

  • H. Remy. Treatise on Inorganic Chemistry, Vol II, pp. 30–43, 478–501; tables 54 and 55. Amsterdam: Elsevier, 1956.

  • R. Rich. Periodic Correlations. New York: Benjamin, 1965, pp. 2, 3, 4, 61, 80.

  • RT. Sanderson (1964) ArticleTitleA Rational Periodic Table J. Chem. Educ. 41 187–189

    Google Scholar 

  • RT. Sanderson (1967) Inorganic Chemistry Reinhold New York

    Google Scholar 

  • E. Scerri. The Periodic Table: The Ultimate Paper Tool in Chemistry. In E.Klein (Ed.), Tools and Modes of Representation in the Laboratory Sciences, pp. 163–177. Dordrecht: Kluwer Academic, 2001.

  • GT. Seaborg (1945) ArticleTitleThe Chemical and Radioactive Properties of the Heavy Elements Chem. Eng. News 23, December 10 2190–2193

    Google Scholar 

  • GT. Seaborg (1969) ArticleTitleProspects for Further Considerable Extension of the Periodic Table J. Chem. Educ. 46 626–634 Occurrence Handle10.1021/ed046p626

    Article  Google Scholar 

  • W.F. Sheehan. Physical Chemistry. Quoted in H.H. Sisler. Electronic Structure, Properties, and the Periodic Law, p. 33. New York, Reinhold, 1963. Boston: Allyn and Bacon, 1961.

  • NV. Sidgwick (1950) The Chemical Elements and Their Compounds Vol 1. Clarendon Press Oxford 439–457

    Google Scholar 

  • T. Ternstrom (1964) ArticleTitleA Periodic Table J. Chem. Educ. 41 190–191

    Google Scholar 

  • ER. Tufte (1983) The Visual Display of Quantitative Information Cheshire. Graphics Press Conn 51

    Google Scholar 

  • JW. Spronsen Particlevan (1969) The Periodic System of Chemical Elements Elsevier Amsterdam 260–284

    Google Scholar 

  • RC. Vickery (1953) Chemistry of the Lanthanons Butterworths London 11–58

    Google Scholar 

  • R.C. Vickery. Scandium, Yttrium and the Lanthanides. In J.C. Bailar, H.J. Emeleus, R. Nyholm and A.F. Trotman-Dickenson. (Eds.), Comprehensive Inorganic Chemistry. Vol. 3, pp. 329–353, especially p. 331. Oxford: Pergamon, 1973.

  • M.E. Weeks. Discovery of the Elements 6th edn. J. Chem. Educ. p. 671–683, 695–727.PA: Easton, 1956.

  • A. Werner (1908) New Ideas on Inorganic Chemistry (Translated from the 2nd German edition) Longmans London

    Google Scholar 

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Laing, M. A Revised Periodic Table: With the Lanthanides Repositioned. Found Chem 7, 203–233 (2005). https://doi.org/10.1007/s10698-004-5959-9

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