Abstract
The crystal structure of Triphenylphosphine Oxide, C18H15PO, was reinvestigated using Mo-Kα radiation λ=0.71069 Å,μ(Mo-Kα)=1.36 cm−1.M r=278.1, orthohombic,Pbca,a=29.089(3),b=9.1347(9),c=11.261(1) Å,V=2992.2 Å3,Z=4,D x=1.235 Mg m−3. The structure was refined by full-matrix least-squares toR=0.040 andR w=0.036 for 1848 unique reflections and 182 variables. Improved bond lengths and angles were obtained; O-P is 1.479(2) Å, weighted means of P-C is 1.803(1) Å, O-P-C is 112.6(1)° and C-P-C is 106.2(1)°.
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Al-Farhan, K. (1988) Ph.D., X-ray studies of manganese compound (University of Manchester).
Al-Farhan, K., Beagley, B., El-Syrafi, O., Gott, G., McAuliff, C., MacRoyr, P., and Pritchard, R. (1990)J. Chem. Soc. Dalton Trans. 1243.
Antipin, M., Kalinin, A., Struchkov, Yu., Matrosov, E., and Kabachnik, M. (1980)Kristallografiya 25, 514.
Bandoli, G., Bortolozzo, G., Clemente, D., Croatto, U., and Panattoni, C. (1970)J. Chem. Soc. A, 2778.
Daly, J. (1964)J. Chem. Soc. 3799.
Davenport, G., and Flack, H. (1990) LSQPL, Xtal3.O reference manual. Hall, S., and Stewart, J. (eds.). (Universities of Western Australia and Maryland, Lamb: Perth).
Declereq, J., Germain, G., Putzeys, J., Rona, S., and Van Meerssche (1974)Cryst. Struct. Comm. 3, 579.
Edward, P. (1982)Mathematical techniques in crystallography and material science (Springer-Verlag), p. 97.
Keller, E. (1988) SCHAKAL 88B/V16, Kristallographisches Institut der Albert-Ludwigs-Universitaet, FRG.
Olthof-Hazekap, R. (1990)NEWMAN, Xtal3.0 reference manual.
Hall, S., and Stewart, J. (eds.), (Universities of Western Australia and Maryland, Lamb: Perth).
Sheldrick, G. (1976)SHELX76, A program for crystal structure determination (University of Cambridge, England).
Stout, G., and Jensen, L. (1968)X-ray structure determination: A practical guide (Macmillan Publishing Co., Inc., New York), p. 241.
TEXSAN-TEXRAY (1985)Structure analysis package. Molecular Structure Corporation.
Thierbach, D., and Huber, F. (1979)Z. Anorg. Allg. Chem. 451, 137.
Thierbach, D., and Huber, F. (1981)Z. Anorg. Allg. Chem. 477, 101.
Thierbach, D., and Huber, F., and Freut, H. (1980)Acta Crystallogr. B 36, 974.
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Al-Farhan, K.A. Crystal structure of triphenylphosphine oxide. Journal of Crystallographic and Spectroscopic Research 22, 687–689 (1992). https://doi.org/10.1007/BF01160986
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DOI: https://doi.org/10.1007/BF01160986