Abstract
First, fundamental properties (structure, acid and redox properties) and advantages of solid polyoxometalate catalysts (catalyst design by acid and redox control, molecularity, unusual reaction field and unique basicity) are explained. Then, the mechanism of alcohol dehydration elucidated by direct observation of reaction intermediates by solid-state NMR and the very high activity of Cs2.5H0.5PW12O40 are described. Finally several industrial applications of polyoxometalate catalysts are briefly introduced placing stress on the role of unique chemical properties of polyoxometalates.
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References
M. Misono:Catal. Rev. Sci. Eng. 29, 269 (1987);30, 339 (1988).
M. Misono, K. Sakata, Y. Yoneda, and W. Y. Lee: Proc. 7th Intern. Congr. Catal., Tokyo, 1980, Kodansha, Tokyo-Elsevier, Amsterdam, p. 1047 (1981).
T. Okuhara, S. Tatematsu, K. Y. Lee, and M. Misono:Bull. Chem. Soc. Jpn. 62, 717 (1989); M. Misonoet al., ibid. 55, 400 (1982).
H. Niiyamaet al.:J. Chem. Eng. Soc. Jpn. 23, 143 (1990);24, 417 (1991).
N. Mizuno and M. Misono:J. Phys. Chem. 93, 89 (1989); N. Mizuno, T. Watanabe, and M. Misono:ibid. 94, 890 (1990).
K. Y. Lee, T. Arai, S. Nakata, S. Asaoka, T. Okuhara, and M. Misono:J. Am. Chem. Soc. 114, 2836 (1992).
N. Mizuno, T. Watanabe, H. Mori, and M. Misono:J. Catal. 123, 157 (1990).
S. Tatematsu, T. Hibi, T. Okuhara, and M. Misono:Chem. Lett., 865 (1984).
T. Okuhara, T. Nishimura, K. Ohasi, and M. Misono:Chem. Lett., 1201 (1990); T. Nishimura, T. Okuhara, and M. Misono:Appl. Catal. 73, L7 (1991).
T. Nishimura, T. Okuhara, and M. Misono:Shokubai (Catalyst) 33, 420 (1991); H. Watanabe, T. Nishimura, S. Nakata, T. Okuhara, and M. Misono: 63rd National Meeting of Chem. Soc. Jpn, March (1992).
T. Nishimura, T. Okuhara, and M. Misono:Chem. Lett., 1695 (1991).
T. Okuhara, T. Nishimura, H. Watanabe, and M. Misono:J. Mol. Catal. 74, 247 (1992).
M. Misono and N. Nojiri:Appl. Catal. 64, 1 (1990).
N. Mizuno, T. Watanabe, and M. Misono:Bull. Chem. Soc. Jpn. 64, 243 (1991).
M. Misono, T. Okuhara, and N. Mizuno: in ‘Successful Design of Catalysts’, T. Inui (ed.), Elsevier, Amsterdam;Stud. Surf. Sci. Catal. 44, 267 (1989).
V. W. Day, M. F. Frederic, W. G. Klemperer, and R.-S. Liu:J. Am. Chem. Soc. 101, 491 (1979); R. D. Adamset al.:J. Chem. Soc., 256 (1979).
M. Ueshima, H. Tsuneki, and N. Shimizu:Hyomen 24, 582 (1986).
A. Aoshima, S. Yamamatsu, and T. Yamaguchi, Nippon Kagaku Kaishi: 233 (1990); 976, 984 (1987).
K. Urabe, K. Fujita, and Y. Izumi:Shokubai (Catalyst) 22, 223 (1980); I. V. Kozhevnikovet al.:Kin. Katal. 30, 50 (1989).
T. Baba and Y. Ono:J. Mol. Catal. 37, 317 (1986).
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Misono, M. Catalytic chemistry of solid polyoxometalates and their industrial applications. Mol Eng 3, 193–203 (1993). https://doi.org/10.1007/BF00999633
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DOI: https://doi.org/10.1007/BF00999633