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Polymerization of 1,2-dimethylenecyclobutane by organolithium initiators

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The possibility of polymerizing 1,2-dimethylenecyclobutane with organolithium initiators has been demonstrated. The microstructure of the polymers obtained is determined by the nature of the solvent; in a hydrocarbon medium the 1,4-structural unit is mainly. formed, while in a polar solvent the 1,2-structural unit predominates.

  2. 2.

    The anionic copolymerization constants of 1,2-dimethylenecyclobutane with butadiene in hydrocarbon and polar media have been determined.

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Authors and Affiliations

  1. A. V. Topchiev Institute of Petrochemical Synthesis, Academy of Sciences of the USSR, Moscow

    A. V. Yurkovetskii, V. L. Kofman & K. L. Makovetskii

Authors
  1. A. V. Yurkovetskii
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  2. V. L. Kofman
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  3. K. L. Makovetskii
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 1993–1995, September, 1988.

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Yurkovetskii, A.V., Kofman, V.L. & Makovetskii, K.L. Polymerization of 1,2-dimethylenecyclobutane by organolithium initiators. Russ Chem Bull 37, 1782–1784 (1988). https://doi.org/10.1007/BF00962487

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  • DOI: https://doi.org/10.1007/BF00962487

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