Paper Titles

Study of the Destructive Properties of Biodegradable Wood-Filled Composite Material
p.290

Technology of Production of Diamond-Abrasive Composites with Metal Matrix
p.296

The Study of Heat and Mass-Exchange Processes during the Drying of Granulate of Hydrophobic Polymers
p.301

Mechanical Properties of Superconcentrates Based on Ethylene-Vinyl Acetate Copolymer and Microcrystalline Cellulose
p.306

Synthesis of Poly(Ethylene 2,5-Furanoate): I. Kinetics of 2,5-Dimethyl Ester of Furandicarboxylic Acid Transesterification
p.311

Studies of Microwave Electromagnetic Field Influence on Adhesion Strength of the “Matrix-Fiber” Contact Zone on the Example of the Elementary Cell of a Certified Polymeric Composite Material
p.317

Studying the Effect of Temperature, Static Load and Nanodimensional Defects on the Mechanical Properties of Polyethylene Film at Uniaxial Extension
p.325

Destruction of Epoxy-Based Composite Materials under the Influence of Impact Load
p.331

Formation of the Structure and Properties of Epoxy-Based Composite Materials
p.336

HomeMaterials Science ForumMaterials Science Forum Vol. 992Synthesis of Poly(Ethylene 2,5-Furanoate): I....

Synthesis of Poly(Ethylene 2,5-Furanoate): I. Kinetics of 2,5-Dimethyl Ester of Furandicarboxylic Acid Transesterification

Article Preview

Abstract:

The kinetics of the 2,5-dimethyl ester of furandicarboxylic acid transesterification in the presence of various catalysts at different temperatures was investigated. It was shown that the catalytic activity follows the order: Mn (OAc)₂ < Co (OAc)₂ < Zn (OAc)₂< Ti (OBu)₄. The transesterification catalyzed by Ti (OBu)₄ leads to the formation of the polymers with the higher molecular weight compared to Me (OAc)₂.

You might also be interested in these eBooks

FarEastCon - Materials and Construction II

Info:

Periodical:

Materials Science Forum (Volume 992)

Pages:

311-316

DOI:

https://doi.org/10.4028/www.scientific.net/MSF.992.311

Citation:

Cite this paper

Online since:

May 2020

Authors:

Tatyana A. Molodtsova*, E.V. Boldyreva, V.A. Klushin

Keywords:

2,5-Dimethyl Ester of Furandicarboxylic, Poly(Ethylene 2,5-Furanoate), Ti(OBu)₄, Transesterification

Export:

RIS, BibTeX

Price:

Permissions:

Request Permissions

* - Corresponding Author

[1] A. Gandini, Green Chem. 13 (2011) 1061.

[2] M.A.R. Meier, J.O. Metzger, U.S. Schubert, Chem. Soc. Rev. 36 (2007) 1788.

[3] C. Vilela, A.F. Sousa, A.C. Fonseca, A.C. Serra, J.F.J. Coelho, C.S.R. Freire, and A.J.D Silvestre, Polym. Chem. 5 (2014) 3119.

[4] J. Saeng-On, D. Aht-ong, Polymers from Renewable Resources. 3 (2017) 91.

[5] A. Gandini, T.M. Lacerda, Prog. Polym. Sci. 48 (2015) 1.

[6] I. Delidovich, P.J.C. Hausoul, L. Deng, R. Pfützenreuter, M. Rose, and R. Palkovits, Chem. Rev. 116 (2016) 1540.

DOI: 10.1021/acs.chemrev.5b00354

[7] J.J. Bozell and G.R. Petersen, Green Chem. 12 (2010) 539.

[8] J. J. E. Eerhart, A. P. C. Faaij, and M. K. Patel, Energy Environ. Sci. 5 (2012) 6407.

[9] E. De Jong, M.A. Dam, L. Sipos, and G.-J.M. Gruter, ACS Symp. Ser. 1 (2012) 1105.

[10] A.F. Sousa, C. Vilela, A.C. Fonseca, M. Matos, C.S.R. Freire, G.-J.M. Gruter, J.F.J. Coelho, and A.J.D. Silvestre, Polym. Chem. 6 (2015) 5961.

[11] G.Z. Papageorgiou, D.G. Papageorgiou, Z. Terzopoulou, and D.N. Bikiaris, Eur. Polym. J. 83 (2016) 202.

[12] S.K. Burgess, J.E. Leisen, B.E. Kraftschik, Ch.R. Mubarak, R. M. Kriegel, and W.J. Koros, Macromolecules. 47 (2014) 1383.

DOI: 10.1021/ma5000199

[13] E. de Jong, A. Higson, P. Walsh, and M. Wellisch, Biofuels, Bioprod. Bioref. 6 (2012) 606.

DOI: 10.1002/bbb.1360

[14] V.M. Chernyshev, O.A. Kravchenko and V.P. Ananikov, Russ. Chem. Rev. 86 (2017) 357.

[15] D.V. Chernysheva, V.A. Klushin, A.F. Zubenko, L.S. Pudova, O.A. Kravchenko, and N.V. Smirnova., Mend. Commun. (in press).

[16] K. Pang, R. Kotek, A. Tonelli, Prog. Polym. Sci. 31 (2006) 1009.

[17] R.J.I. Knoop, W. Vogelzang, J. van Haveren, and D.S. van Es. J. Polym. Sci. Part A: Polym. Chem. 51 (2013) 4191.

DOI: 10.1002/pola.26833

[18] J. Ma, X .Yu, J. Xu, Y., Polymer. 53 (2012) 4145.

[19] Z. Terzopoulou, E. Karakatsianopoulou, N. Kasmi, V. Tsanaktsis, N. Nikolaidis, M. Kostoglou, G. Z. Papageorgiou, D. A. Lambropoulou, and D. N. Bikiaris, Polym. Chem. 8 (2017) 6895.

DOI: 10.1039/c7py01171g

[20] K. Tomita and H. Ida, Polymer. 14 (1973) 55.

[21] B. Saha, M. Streat, Reactive & Functional Polymers. 40 (1999) 13.

[22] E. Santacesaria, F. Trulli, L. Minervini, M. Di Serio, R. Tesser, and S. Contessa, J. Appl. Polym. Sci. 54 (1994) 1371.

DOI: 10.1002/app.1994.070540919

[23] F. Pilati, P. Manaresi, B. Fortunate, A. Munari and P. Monari, Polymer. 24 (1983) 1479.

[24] J. Otton, S. Ratton, V.A. Vasnev, G.D. Markova, K.M. Nametov, V.I. Bakhmutov, L.I. Komarova, S.V. Vinogradova, and V.V. Korshak, J. Polym. Sci., Part A. 26 (1988) 2199.

DOI: 10.1002/pola.1988.080260816

[25] G.D. Lei and K.Y. Choi, Industrial & engineering chemistry research. 31 (1992) 769.