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Licensed Unlicensed Requires Authentication Published by De Gruyter April 30, 2013

Processing-induced Properties in Glassy Polymers

Development of the Yield Stress in PC

  • L. E. Govaert , T. A. P. Engels , E. T. J. Klompen , G. W. M. Peters and H. E. H. Meijer

Abstract

A new method is employed to directly predict the development of yield stress distributions in injection molded products of glassy polymers. The approach is based on the results of a study on the temperature dependence of the evolution of yield stress during annealing of polycarbonate below Tg. In combination with the process-related thermal history, derived from numerical simulations of the injection molding process, an estimate of the yield stress distribution throughout a product can be obtained. Computed yield stresses of injection molded plates prove to be in excellent agreement with the experimental values, including their dependence on mold temperature and plate thickness.


Mail address: L. E. Govaert, Dutch Polymer Institute, Section Materials Technology, Eindhoven University of Technology, P.O. Box 513, NL-5600 MB, Eindhoven, Netherlands E-mail:

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Received: 2004-10-10
Accepted: 2005-1-26
Published Online: 2013-04-30
Published in Print: 2005-05-01

© 2005, Carl Hanser Verlag, Munich

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