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Coordination Chemistry of Europium(III) Ion Towards Acylpyrazolone Ligands

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Abstract

Two Eu(III) complexes were synthesized using 4-acylpyrazolone ligands: 3-methyl-4-(4-methylbenzoyl)-1-phenylpyrazol-5-one (HPMMBP) and 3-methyl-1-phenyl-4-(4-phenylbenzoyl)-pyrazol-5-one (HPPMBP). The composition of the obtained solid complexes was determined as Eu(PMMBP)3·C2H5OH and Eu(PPMBP)3·3H2O based on elemental analysis and was further studied by IR, NMR and TG-TSC data. The lanthanoid complexation in solid state and in solution during liquid-liquid extraction (molecular diluent and ionic liquid) is discussed.

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Acknowledgments

The authors are grateful to FP7-PEOPLE-Marie Curie ActionsIEF for the financial support of the project INNOVILLN (622906) 2014-2016.

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Authors and Affiliations

  1. Department of General and Inorganic Chemistry, University of Chemical Technology and Metallurgy, 8 Kliment Okhridski blvd., 1756, Sofia, Bulgaria

    Maria Atanassova

  2. Institute of Organic Chemistry with Centre of Phytochemistry, Bulgarian Academy of Sciences, Acad. G. Bonchev street, Block 9, BG, 1113, Sofia, Bulgaria

    Vanya Kurteva

  3. University of Grenoble Alpes, 38000 Grenoble, France

    Isabelle Billard

  4. CNRS, LEPMI, UMR 5279, 1130 rue de la piscine 38000 Grenoble, France

    Maria Atanassova & Isabelle Billard

Authors
  1. Maria Atanassova
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  2. Vanya Kurteva
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  3. Isabelle Billard
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Correspondence to Maria Atanassova.

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Atanassova, M., Kurteva, V. & Billard, I. Coordination Chemistry of Europium(III) Ion Towards Acylpyrazolone Ligands. ANAL. SCI. 31, 917–922 (2015). https://doi.org/10.2116/analsci.31.917

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  • DOI: https://doi.org/10.2116/analsci.31.917

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