Skip to main content
SpringerLink
Log in

Adsorption Behavior of Metal Ions on Cross-linked Chitosan and the Determination of Oxoanions after Pretreatment with a Chitosan Column

  • Published:
Analytical Sciences Aims and scope Submit manuscript

Abstract

The adsorption behavior of 60 elements at the 10 ng ml–1 level on high-porous cross-linked chitosan in a packed mini-column was systematically examined. The chitosan used could adsorb anionic species quantitatively as oxoanions or chloro complex anions of metals, such as Ti, V, Mo, W, Ga, Bi, Au(III), Pt(IV) and Pd(II), in sample solutions by an ion-exchange mechanism, and could adsorb some metal ions by a chelating mechanism. Most of the metal ions adsorbed on the chitosan were eluted with 1 M nitric acid, and other noble metals, such as Au, Pt and Pd, were eluted by a solution containing 1 M hydrochloric acid and 0.05 M thiourea. The adsorption fraction of metal ions was investigated by measuring metal ions in eluates by ICP-MS. By using the proposed column pretreatment method, metal ions present as their oxoanions in river-water samples, such as Ti, V, Mo, W, Ga and Bi, were collected on the cross-linked chitosan, eluted and determined. The method was applied to an analysis of reference materials distributed by the Japan Society for Analytical Chemistry: JAC 0031 and JAC 0032. The analytical results agreed closely with other reference values.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. R. A. A. Muzzarelli and O. Tubertini, Talanta, 1971, 18, 853.

    Article  CAS  Google Scholar 

  2. R. A. A. Muzzarelli and R. Rocchetti, Talanta, 1974, 21, 1137.

    Article  CAS  Google Scholar 

  3. P. Udaybhaskar, Leela Iyengar, and A. V. S. Prabhakara Rao, J. Appl. Polym. Sci., 1990, 39, 739.

    Article  CAS  Google Scholar 

  4. R. Maruca, B. J. Suder, and J. P. Wightman, J. Appl. Polym. Sci., 1982, 27, 4827.

    Article  CAS  Google Scholar 

  5. C. A. Eiden, C. Jewell, and J. P. Wightman, J. Appl. Polym. Sci., 1980, 25, 1587.

    Article  CAS  Google Scholar 

  6. K. Kurita, T. Sannan, and Y. Iwakura, J. Appl. Polym. Sci., 1979, 23, 511.

    Article  CAS  Google Scholar 

  7. C. Peniche-Covas, L. W. Alvarez, and W. Arguelles-Monal, J. Appl. Polym. Sci., 1992, 46, 1147.

    Article  CAS  Google Scholar 

  8. S. Hirano, Y. Kondo, and Y. Nakazawa, Carbohydrate Res., 1982, 100, 431.

    Article  CAS  Google Scholar 

  9. K. Ohga, Y. Kurauchi, and H. Yanase, Bull. Chem. Soc. Jpn., 1987, 60, 444.

    Article  Google Scholar 

  10. K. Inoue, Y. Baba, and K. Yoshizuka, Bull. Chem. Soc. Jpn., 1993, 66, 2915.

    Article  CAS  Google Scholar 

  11. K. Inoue and Y. Baba, J. Ion Exchange, 1997, 8, 115.

    Article  CAS  Google Scholar 

  12. Y. Koyama and A. Taniguti, J. Appl. Polym. Sci., 1986, 31, 1951.

    Article  CAS  Google Scholar 

  13. K. Kurita, Y. Koyama, and A. Taniguchi, J. Appl. Polym. Sci., 1986, 31, 1169.

    Article  CAS  Google Scholar 

  14. G. L. Rorrer, T-Y. Hsien, and J. D. Way, Ind. Eng. Chem. Res., 1993, 32, 2170.

    Article  CAS  Google Scholar 

  15. K.-H. Lee, M. Oshima, T. Takayanagi, and S. Motomizu, Anal. Sci., 2000, 16, 731.

    Article  CAS  Google Scholar 

  16. A. Itoh, K. Iwata, S. Ji, T. Yabutani, C. Kimata, H. Sawatari, and H. Haraguchi, Bunseki Kagaku, 1998, 47, 109.

    Article  CAS  Google Scholar 

  17. S. Suzuki, Y. Okada, and S. Hirai, Bunseki Kagaku, 1997, 46, 223.

    Article  CAS  Google Scholar 

  18. L. G. Sillen, “Stability constants, Section I: Inorganic ligands”, 1964, (Special publication, no.17), Chemical Society, London.

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Okayama University, Tsushimanaka, Okayama, 700-8530, Japan

    Yunhua Gao, Kyue-Hyung Lee, Mitsuko Oshima & Shoji Motomizu

Authors
  1. Yunhua Gao
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Kyue-Hyung Lee
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Mitsuko Oshima
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Shoji Motomizu
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Shoji Motomizu.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Gao, Y., Lee, KH., Oshima, M. et al. Adsorption Behavior of Metal Ions on Cross-linked Chitosan and the Determination of Oxoanions after Pretreatment with a Chitosan Column. ANAL. SCI. 16, 1303–1308 (2000). https://doi.org/10.2116/analsci.16.1303

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.2116/analsci.16.1303

Search

Navigation