Skip to main content
Log in

Size Dependent Electroluminescence from CdSe Nanocrystallites (Quantum Dots)

  • Published:
MRS Online Proceedings Library Aims and scope

Abstract

We obtain spectrally narrow (FWHM < 40 nm) electroluminescence from nearly monodisperse CdSe nanocrystallites (quantum dots) incorporated into thin films of polyvinyl carbazole (PVK) and an oxadiazole derivative (PBD) sandwiched between aluminum and ITO electrodes. The electroluminescence and photoluminescence spectra are nearly identical at room temperature and are tunable from ~530 nm to ~650 nm by varying the size of the dots. Voltage studies at 77K indicate that while only the dots electroluminesce at the lower voltages, both the dots and the PVK matrix electroluminesce at higher applied voltages. Variable temperature studies indicate that the electroluminescence efficiency increases substantially as the films are cooled down to cryogenic temperatures.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. See for example, L. E. Brus, Appl. Phys. A 53, 465 (1991) and references therein.

    Article  Google Scholar 

  2. At the time of preparation of this manuscript V. Colvin, M. Schlamp, and A. P. Alivisatos, Nature 370, 354 (1994), reported similar electroluminescence results from devices of CdSe crystallites/PPV with ITO and Mg/Ag electrodes.

    Article  CAS  Google Scholar 

  3. J. H. Burroughes, D. D. C. Bradley, A. R. Brown, R. N. Marks, K. Mackay, R. H. Friend, P. L. Burn, and A. B. Holmes, Nature 347, 539 (1990).

    Article  CAS  Google Scholar 

  4. D. Braun and A. J. Heeger, Appl. Phys. Lett. 58, 1982 (1991).

    Article  CAS  Google Scholar 

  5. P. L. Burn, A. B. Holmes, A. Kraft, D. D. C. Bradley, A. R. Brown, R. H. Friend, and R. W. Gymer, Nature 356, 47 (1992)

    Article  CAS  Google Scholar 

  6. C. Zhang, H. von Seggern, K. Pakbaz, B. Krabbel, H. W. Schmidt, and A. J. Heeger, Synth. Met. 62, 35 (1994).

    Article  CAS  Google Scholar 

  7. C. B. Murray, D. J. Norris and M. G. Bawendi, J. Am. Chem. Soc. 115, 8706 (1993).

    Article  CAS  Google Scholar 

  8. J. Mort and G. Pfister, Electronic Properties of Polymers, (Wiley Interscience, New York, 1982), pp. 215–265

    Google Scholar 

  9. R. H. Partridge, Polymer 24, 748 (1983).

    Article  CAS  Google Scholar 

  10. P. L. Burn, A. B. Holmes, A. Kraft, A. R. Brown, D. D. C. Bradley, and R. H. Friend, Mat. Res. Soc. Symp. Proc. 247, 647 (1992).

    Article  CAS  Google Scholar 

  11. M. G. Bawendi, P. J. Carroll, W. L. Wilson, and L. E. Brus, J. Chem. Phys. 96, 946 (1992)

    Article  CAS  Google Scholar 

  12. M. Nirmal, C. B. Murray and M. G. Bawendi, Phys. Rev. B 50, 2293 (1994).

    Article  CAS  Google Scholar 

  13. M. Pope and C. E. Swenberg, Electronic Processes in Organic Crystals, (Oxford University Press, New York, 1982).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Dabbousi, B.O., Onitsuka, O., Rubner, M.F. et al. Size Dependent Electroluminescence from CdSe Nanocrystallites (Quantum Dots). MRS Online Proceedings Library 358, 707 (1994). https://doi.org/10.1557/PROC-358-707

Download citation

  • Published:

  • DOI: https://doi.org/10.1557/PROC-358-707

Navigation