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Lithium-air and lithium-sulfur batteries

  • Electrochemical Energy Storage to Power the 21st Century
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Abstract

Reducing our dependence on fossil fuels increases the demand for energy storage. Lithium-ion batteries have transformed portable electronics and will continue to be important but cannot deliver the step change in energy density required in the longer term in markets such as electric vehicles and the storage of electricity from renewables. There are a few alternatives. Here we describe two: Li-air and Li-sulfur batteries. We compare the energy densities of Li-ion, Li-air, and Li-S and discuss their differences and the challenges facing Li-air and Li-S, many of which are materials related.

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References

  1. G. Girishkumar, B. McCloskey, A.C. Luntz, S. Swanson, W. Wilcke, J. Phys. Chem. Lett. 1, 2193 (2010).

    Article  CAS  Google Scholar 

  2. X. Ji, L.F. Nazar, J. Mater. Chem. 20, 9821 (2010).

    Article  CAS  Google Scholar 

  3. A. Kraytsberg, Y. Ein-Eli, J. Power Sources 196, 886 (2011).

    Article  CAS  Google Scholar 

  4. J.-S. Lee, S.T. Kim, R. Cao, N.-S. Choi, M. Liu, K.T. Lee, J. Cho, Adv. Energy. Mater. 1, 34 (2011).

    Article  CAS  Google Scholar 

  5. K.M. Abraham, Z. Jiang, J. Electrochem. Soc. 143, 1 (1996).

    Article  CAS  Google Scholar 

  6. C.Ó. Laoire, S. Mukerjee, E.J. Plichta, M.A. Hendrickson, K.M. Abraham, J. Electrochem. Soc. 158, A302 (2011).

  7. T. Ogasawara, A. Débart, M. Holzapfel, P. Novák, P.G. Bruce, J. Am. Chem. Soc. 128, 1390 (2006).

    Article  CAS  Google Scholar 

  8. S.J. Visco, B.D. Katz, Y.S. Nimon, L.D. DeJonghe, U.S. Patent 7,282,295 (2007).

  9. A. Débart, A.J. Paterson, J. Bao, P.G. Bruce, Angew. Chem. Int. Ed. 47, 4521 (2008).

    Article  Google Scholar 

  10. Y.-C. Lu. H.A. Gasteiger, E. Crumlin, R. McGuire, Y. Shao-Horn, J. Am. Chem. Soc. 132, 12170 (2010).

    Article  CAS  Google Scholar 

  11. C.O. Laoire, S. Mukerjee, K.M. Abraham, E.J. Plichta, M.A. Hendrickson, J. Phys. Chem. C 113, 20127 (2009).

    Article  CAS  Google Scholar 

  12. C.O. Laoire, S. Mukerjee, K.M. Abraham, E.J. Plichta, M.A. Hendrickson, J. Phys. Chem. C 114, 9178 (2010).

    Article  CAS  Google Scholar 

  13. F. Mizuno, S. Nakanishi, Y. Kotani, S. Yokoishi, H. Iba, Electrochemistry 78, 403 (2010).

    Article  CAS  Google Scholar 

  14. S.A. Freunberger, L.J. Hardwick, Z. Peng, V. Giordani, Y. Chen, P. Maire, P. Novák, J.-M. Tarascon, P.G. Bruce, Meet. Abstr. Electrochem. Soc. 1003, 830 (2010).

    Google Scholar 

  15. S.A. Freunberger, Y. Chen, Z. Peng, J.M. Griffin, L.J. Hardwick, F. Barde, P. Novak, P.G. Bruce, J. Am. Chem. Soc., 133, 8040 (2011).

    Article  CAS  Google Scholar 

  16. G. Girishkumar, B. McCloskey, A.C. Luntz, S. Swanson, W. Wilcke, J. Phys. Chem. Lett. 1, 2193 (2010).

    Article  CAS  Google Scholar 

  17. J. Zhang, W. Xu, W. Liu, J. Power Sources, 195, 7438 (2010).

    Article  CAS  Google Scholar 

  18. G.Q. Zhang, J.P. Zheng, R. Liang, C. Zhang, B. Wang, M. Hendrickson, E.J. Plichta, J. Electrochem. Soc. 157, A953 (2010).

  19. X.-H. Yang, P. He, Y.-Y. Xia, Electrochem. Commun. 11, 1127 (2009).

    Article  CAS  Google Scholar 

  20. W. Xu, J. Xiao, D. Wang, J. Zhang, J.-G. Zhang, Electrochem. Solid-State Lett. 13, A48 (2010).

  21. J. Read, J. Electrochem. Soc. 149, A1190 (2002).

  22. J. Read, K. Mutolo, M. Ervin, W. Behl, J. Wolfenstine, A. Driedger, D. Foster J. Electrochem. Soc. 150, A1351 (2003).

  23. J.A. Zhang, W. Xu, W. Liu, J. Power Sources 195, 7438 (2010).

    Article  CAS  Google Scholar 

  24. K.M. Abraham, S.B. Brummer, in Lithium Batteries, J.P. Gabano, Ed. (Academic Press, London, 1983).

  25. N. Imanishi, S. Hasegawa, T. Zhang, A. Hirano, Y. Takeda, O. Yamamoto, J. Power Sources 185, 1392 (2008).

    Article  CAS  Google Scholar 

  26. T. Zhang, N. Imanishi, Y. Shimonishi, A. Hirano, J. Xie, Y. Takeda, O. Yamamoto, N. Sammes, J. Electrochem Soc. 157, A214 (2010).

  27. S. Hasegawa, N. Imanishi, T. Zhang, J. Xie, A. Hirano, Y. Takeda, O. Yamamoto, J. Power Sources 189, 371 (2009).

    Article  CAS  Google Scholar 

  28. P. Stevens, G. Toussaint, G. Caillon, P. Viaud, P. Vinatier, C. Cantau, O. Fichet, C. Sarrazindan, M. Mallouki, ESC Trans. 28, 1 (2010).

    CAS  Google Scholar 

  29. D. Herbert, J. Ulam, U.S. Patent 3043896 (1962).

  30. R.D. Rauh, K.M. Abraham, G.F. Pearson, J.K. Surprenant, S.B. Brummer, J. Electrochem. Soc. 126, 523 (1979).

    Article  CAS  Google Scholar 

  31. T.D. Kaun, P.A. Nelson, L. Redey, D.R. Vissers, G.L. Henriksen, Electrochim. Acta 38, 126 (1993).

    Article  Google Scholar 

  32. K.M. Abraham, R.D. Rauh, S.B. Brummer, Electrochim. Acta 23, 501 (1978).

    Article  CAS  Google Scholar 

  33. Y.F.Y. Yao, J.T. Kummer, J. Inorg. Nucl. Chem. 29, 2453 (1967).

    Article  CAS  Google Scholar 

  34. J.T. Kummer, N. Weber, Proc. Power Sources Conf. 37 (1967).

  35. R.D. Rauh, F.S. Shuker, J.M. Marston, S.B. Brummer, J. Inorg. Nucl. Chem. 39, 1761 (1977).

    Article  CAS  Google Scholar 

  36. R.D. Rauh, G.F. Pearson, S.B. Brumner, Proc. 12th IECEC (1997), pp. 283.

  37. H.-S. Ryu, H.-J. Ahn, K.-W. Kim, J.-H. Ahn, K.-K. Cho, T.-H. Nam, J.-U. Kim, G.-B. Cho, J. Power Sources 201, 163 (2006).

    Google Scholar 

  38. M.-Y. Chu, U.S. Patent 5,686,201 (1997).

  39. L.X. Yuan, J.K. Feng, X.P. Ai, Y.L. Cao, S.L. Chen, H.X. Yang, Electrochem. Commun. 8, 610 (2006).

    Article  CAS  Google Scholar 

  40. J. Wang, S.Y. Chew, Z.W. Zhao, S. Ashraf, D. Wexler, J. Chen, S.H. Ng, S.L. Chou, H.K. Liu, Carbon 46, 229 (2008).

    Article  CAS  Google Scholar 

  41. J.H. Shin, E.J. Cairns, J. Power Sources 177, 537 (2008).

    Article  CAS  Google Scholar 

  42. J.H. Shin, E.J. Cairns, J. Electrochem. Soc. 155, A368 (2008).

  43. D. Aurbach, E. Pollak, R. Elazari, G. Salitra, C.S. Kelley, J. Affinito J. Electrochem. Soc. 156, A694 (2009).

  44. R. Mercier, J.-P. Malugani, B. Fahys, G. Robert, Solid State Ionics 5, 663 (1981).

    Article  CAS  Google Scholar 

  45. A. Pradel, M. Ribes, Solid State Ionics 18/19, 351 (1986).

  46. A. Hayashi, R. Ohtsubo, T. Ohtomo, F. Mizuno, M. Tatsumisago, J. Power Sources 183, 422 (2008).

    Article  CAS  Google Scholar 

  47. S.J. Visco, M.Y. Chu, U.S. Patent 6,210,832 (2001).

  48. W. Zheng, Y.W. Liu, X.G. Hu, C.F. Zhang, Electrochim. Acta 51, 1330 (2006).

    Article  CAS  Google Scholar 

  49. L. Yuan, H. Yuan, X. Qiu, L. Chen, W. Zhu, J. Power Sources 189, 1141 (2009).

    Article  CAS  Google Scholar 

  50. X.L. Ji, K.T. Lee, L.F. Nazar, Nat. Mater. 8, 500 (2009).

    Article  CAS  Google Scholar 

  51. http://www.sionpower.com/technology.html/technology.html

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Authors and Affiliations

  1. School of Chemistry, University of St. Andrews, UK

    Peter G. Bruce & Laurence J. Hardwick

  2. Northeastern University Center for Renewable Energy Technologies, Boston, MA, USA

    K. M. Abraham

Authors
  1. Peter G. Bruce
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  2. Laurence J. Hardwick
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  3. K. M. Abraham
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Correspondence to Peter G. Bruce.

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Bruce, P.G., Hardwick, L.J. & Abraham, K.M. Lithium-air and lithium-sulfur batteries. MRS Bulletin 36, 506–512 (2011). https://doi.org/10.1557/mrs.2011.157

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  • DOI: https://doi.org/10.1557/mrs.2011.157

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