Abstract
In order to improve dimensional stability and durability of wood, furfurylation of poplar and Chinese fir wood using newly developed furfuryl alcohol (FA) formulation combined with a common vacuum and pressure impregnation process was studied. An orthogonal experiment was designed to optimize the furfurylation process for the two wood species. The weight percent gain (WPG), equilibrium moisture content (EMC), anti-swelling efficiency (ASE), modulus of rupture (MOR), modulus of elasticity (MOE), as well as resistance to mold, decay fungi, and termites were evaluated. The results showed that nearly all the properties of the furfurylated wood could be improved to various extents. The average ASE of the furfurylated Chinese fir and poplar could reach as high as 80, 71, 92% and 79, 90, 75% in tangential and radial directions, and by volume, respectively, higher than most previously reported wood modification processes. Furthermore, the modified wood had excellent biological durability, with nearly 100% mold resistance, strong decay and termite resistance. Finally, processing parameters with 50% FA, 105–115 °C curing temperature, and 5–8 h curing time were therefore recommended for pilot-scale production of furfurylated poplar and Chinese fir wood based on range analysis.
Funding source: National Natural Science Foundation of China
Award Identifier / Grant number: 31800474
Award Identifier / Grant number: 31770600
Funding source: National Key R&D Program of China
Award Identifier / Grant number: 2017YFD0600803
Funding source: State Special Research Fund of Forestry Public Welfare of China
Award Identifier / Grant number: 201404510
Acknowledgments
Dr. Guo Fei is highly appreciated for revising the manuscript.
Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.
Research funding: We are grateful for the financial support from National Natural Science Foundation of China (No. 31800474, No. 31770600) and National Key R&D Program of China (No. 2017YFD0600803), as well as State Special Research Fund of Forestry Public Welfare of China (No. 201404510).
Employment or leadership: None declared.
Honorarium: None declared.
References
Ashaari, Z., Lee, S.H., Mustamel, M.N., and Salleh, N.F.M. (2015). Strength improvement of jelutong (dyera costulata) wood via phenolic resin treatments. J Indian Acad Wood Sci. 12, 132–136. https://doi.org/10.1007/s13196-015-0156-0.Search in Google Scholar
Bastani, A., Adamopoulos, S., and Militz, H. (2015). Water uptake and wetting behaviour of furfurylated, N-methylol melamine modified and heat-treated wood. Eur. J. Wood Prod. 73, 627. https://doi.org/10.1007/s00107-015-0919-8.Search in Google Scholar
Bryne, L.E. and Walinder, M.E.P. (2010). Ageing of modified wood. Part 1: Wetting properties of acetylated, furfurylated, and thermally modified wood. Holzforschung 64: 295–304, https://doi.org/10.1515/HF.2010.040.Search in Google Scholar
Cristensen, I.V., Ottosen, L.M., Ribeiro, A.B., and Villumsen, A. (2005). Electrodialytic removal of Cu, Cr and As from treated wood. In: Lichtfouse, E., Schwarzbauer, J., Robert, D. (Eds.), Environmental chemistry. Springer, Berlin, Heidelberg, pp. 235–241.10.1007/3-540-26531-7_22Search in Google Scholar
Dong, Y., Yan, Y., Zhang, S., Li, J., and Wang, J. (2015). Flammability and physical-mechanical properties assessment of wood treated with furfuryl alcohol and nano-SiO2. Eur. J. Wood Prod. 73: 457–464, https://doi.org/10.1007/s00107-015-0896-y.Search in Google Scholar
Ehmcke, G., Pilgård, A., Koch, G., and Richer, K. (2017). Topochemical analyses of furfuryl alcoholmodified radiata pine (Pinus radiata) by UMSP, light microscopy and SEM. Holzforschung 71, 821–831. https://doi.org/10.1515/hf-2016-0219.Search in Google Scholar
Epmeier, H., Johansson, M., and Kliger, R. (2007). Material properties and their interrelation in chemically modified clear wood of Scots pine. Holz Roh-Werkst. 61, 34–42. https://doi.org/10.1515/HF.2007.007.Search in Google Scholar
Esteves, B., Nunes, L., and Pereira, H. (2011). Properties of furfurylated wood (Pinus pinaster). Eur. J. Wood Prod. 69, 521–525. https://doi.org/10.1007/s00107-010-0480-4.Search in Google Scholar
Gao, X., Dong, Y., Wang, K., Chen, Z., Yan, Y., Li, J., and Zhang, S. (2017). Improving dimensional and thermal stability of poplar wood via aluminum-based sol-gel and furfurylation combination treatment. BioResources 12: 3277–3288, https://doi.org/10.15376/biores.12.2.3277-3288.Search in Google Scholar
Gascón-Garrido, P., Oliver-Villanueva, J.V., Ibiza-Palacios, M.S., Militz, H., Mai, C., and Adamopoulos, S. (2013). Resistance of wood modified with different technologies against Mediterranean termites (Reticulitermes spp.). Int. Biodeter. Biodegr. 82: 13–16, https://doi.org/10.1016/j.ibiod.2012.07.024.Search in Google Scholar
Gobakken, L.R. and Westin, M. (2008). Surface mould growth on five modified wood substrates coated with three different coating systems when exposed outdoors. Int. Biodeter. Biodegr. 62: 397–402, https://doi.org/10.1016/j.ibiod.2008.03.004.Search in Google Scholar
Goldstein, I.S. (1955). The impregnating of wood to impart resistance to alkali and acid. Forest Ptod. J.5: 265–267.Search in Google Scholar
Hadi, Y.S., Westin, M., Rasyid, E., (2005). Resistance of furfurylated wood to termite attack. Forest Prod. J. 55, 85–88. https://doi.org/10.1007/s00107-005-0048-x.Search in Google Scholar
Herold, N., Dietrich, T., Grigsby, W.J., Franich, R.A., Winkler, A., Buchelt, B., and Pfriem, A. (2013). Effect of maleic anhydride content and ethanol dilution on the polymerization of furfuryl alcohol in wood veneer studied by differential scanning calorimetry. BioResources 8: 1064–1075, https://doi.org/10.15376/biores.8.1.1064-1075.Search in Google Scholar
Herold, N., Lenz, C., and Pfriem, A. (2014). Changes in cell wall dimensions during the different stages of furfuryl alcohol modification. BioResources 9: 4756–4763, https://doi.org/10.15376/biores.9.3.4756-4763.Search in Google Scholar
Hill, C.A.S. (2007). Wood modification: chemical, thermal and other processes. John Wiley & Sons.Search in Google Scholar
Hill, C.A.S., Hale, M.D., Ormondroyd, G.A., and Kwon, J.H. (2006). The decay resistance of anhydride modified Corsican pine exposed to the brown rot fungus Coniophora puteana. Holzforschung 60: 625–629, https://doi.org/10.1515/HF.2006.105.Search in Google Scholar
Kherroub, D.E., Belbachir, M., and Lamouri, S. (2015). Study and optimization of the polymerization parameter of furfuryl alcohol by Algerian modified clay. Arab. J. Sci. Eng. 40: 143–150, https://doi.org/10.1007/s13369-014-1512-x.Search in Google Scholar
Kielmann, B.C., Butter, K., and Mai, C. (2018). Modification of wood with formulations of phenolic resin and iron-tannin-complexes to improve material properties and expand colour variety. Eur. J. Wood Prod. 76: 259–267, https://doi.org/10.1007/s00107-017-1180-0.Search in Google Scholar
Kong, L., Guan, H., and Wang, X. (2018). In situ polymerization of furfuryl alcohol with ammonium dihydrogen phosphate in poplar wood for improved dimensional stability and flame retardancy. ACS Sustain. Chem. Eng. 6, 3349–3357, https://doi.org/10.1021/acssuschemeng.7b03518.Search in Google Scholar
Lande, S., Westin, M., and Schneider, M. (2004a). Properties of furfurylated wood. Scand J. Forest Res. 19, 22–30. https://doi.org/10.1080/0282758041001915.Search in Google Scholar
Lande, S., Eikenes, M., and Westin, M. (2004b). Chemistry and ecotoxicology of furfurylated wood. Scand J. Forest Res. 19: 14–21, https://doi.org/10.1080/02827580410017816.Search in Google Scholar
Lande, S., Westin, M., and Schneider, M. (2008). Development of modified wood products based on furan chemistry. Mol. Cryst. Liq. Cryst. 484, 367–378. https://doi.org/10.1080/15421400801901456.Search in Google Scholar
Leemon, N.F., Ashaari, Z., Uyup, M.K.A., Bakar, E.S., Tahir, P.M., Saliman, M.A.R., Ghani, M.A., and Lee, S.H. (2015). Characterisation of phenolic resin and nanoclay admixture and its effect onimpregwood. Wood Sci. Technol. 49, 1209–1224. https://doi.org/10.1007/s00226-015-0754-4.Search in Google Scholar
Li, Y., Chu, D., Liu, Y., and Mu, J. (2016). Flame retardant and anti-mold property of poplar treated with chitosan metal complex/ N-P flame retardant. N Chem. Mater 44 (in Chinese), 246–248.Search in Google Scholar
Li, W.J., Wang, H.K., Ren, D., Yu, Y.S., and Yu, Y. (2015). Wood modification with furfuryl alcohol catalysed by a new composite acidic catalyst. Wood Sci. Technol. 49, 845–856. https://doi.org/10.1007/s00226-015-0721-0.Search in Google Scholar
Militz, H., Schaffert, S., Peters, B.C., and Fitzgerald, C.J. (2011). Termite resistance of DMDHEU-treated wood. Wood Sci. Technol. 45, 547–557. https://doi.org/10.1007/s00226-010-0345-3.Search in Google Scholar
Nguyen, C.T., Wagenführ, A., and Dai, V.H. (2012). The effects of thermal modification on the properties of two Vietnamese bamboo species, part I: effects on physical properties. BioResources 7: 5355–5366, https://doi.org/10.15376/biores.8.1.981-993.Search in Google Scholar
Nordstierna, L., Lande, S., Westin, M., Karlsson, O., and Furó, I. (2008). Towards novel wood-based materials: Chemical bonds between lignin-like model molecules and poly (furfuryl alcohol) studied by NMR. Holzforschung 62, 709–713. https://doi.org/10.1515/hf.2008.110.Search in Google Scholar
Obataya, E. and Minato, K. (2008). Potassium acetate-catalyzed acetylation of wood: extraordinarily rapid acetylation at 120°C. Wood Sci. Technol. 42: 567, https://doi.org/10.1007/s00226-008-0179-4.Search in Google Scholar
Okon, K.E., Lin, F., Lin, X., Chen, C., Chen, Y., and Huang, B. (2017). Modification of Chinese fir (cunninghamia lanceolata l.) wood by silicone oil heat treatment with micro-wave pretreatment. Holz Roh Werkst.2: 1–8, https://doi.org/10.1007/s00107-017-1165-z.Search in Google Scholar
Pan, C., Ruan, G., Chen, H., and Zhang, D. (2015). Toxicity of sodium fluoride to subterranean termites and leachability as a wood preservative. Eur. J. Wood Prod. 73, 97–102. https://doi.org/10.1007/s00107-014-0849-x.Search in Google Scholar
Pfriem, A., Dietrich, T., and Buchelt, B. (2012). Furfuryl alcohol impregnation for improved plasticization and fixation during the densification of wood. Holzforschung 66, 215–218. https://doi.org/10.1515/hf.2011.134.Search in Google Scholar
Pilgård, A. and Alfredsen, G. (2009). A better understanding of the mode of action of furfurylated wood. In: Proceedings of the 5th meeting of the Nordic-Baltic Network in Wood Material Science and Engineering (WSE), October 1–2, Copenhagen, Denmark, pp. 13–19.Search in Google Scholar
Pilgård, A., Treu, A., Zeeland, A.N.T.V., Gosselink, R.J.A., and Westin, M. (2010). Toxic hazard and chemical analysis of leachates from furfurylated wood. Environ. Toxicol. Chem. 29, 1918–1924. https://doi.org/10.1002/etc.244.Search in Google Scholar PubMed
Pries, M., Wagner, R., Kaesler, K.H., Militz, H., and Mai, C. (2013). Acetylation of wood in combination with polysiloxanes to improve water-related and mechanical properties of wood. Wood Sci. Technol. 47, 685–699. https://doi.org/10.1007/s00226-013-0535-x.Search in Google Scholar
Ringman, R., Beck, G., and Pilgård, A. (2019). The importantce of moisture for brown rot degradation of modified wood: a critical discussion. Forests 10, 1–22. https://doi.org/10.3390/f10060522.Search in Google Scholar
Ringman, R., Pilgård, A., and Brischke, C. (2014). Mode of action of brown rot decay resistance in modified wood: a review. Holzforschung 68, 239–246. https://doi.org/10.1515/hf-2013-0057.Search in Google Scholar
Schneider, M.H., Phillips, J.G., and Lande, S. (2000). Physical and mechanical properties of wood polymer composites. J. For. Eng. 11, 83–89. https://doi.org/10.1080/08435243.2000.10702748.Search in Google Scholar
Sejati, P.S., Imbert, A., Gérardin-Charbonnier, C., Stéphane, D., Fredon, E., Masson, E., Nandika, D., Priadi, T., and Gérardin, T. (2017). Tartaric acid catalyzed furfurylation of beech wood. Wood Sci. Technol. 51: 379–394, https://doi.org/10.1007/s00226-016-0871-8.Search in Google Scholar
Stamm, A.J. (1977). Dimensional stabilization of wood with furfuryl alcohol resin. In: Goldstein, I. (Ed.), Wood technilogy: chemical aspect, Vol. 43, American Chemical Society, Washington DC, pp. 141–149.10.1021/bk-1977-0043.ch009Search in Google Scholar
Thygesen, L.G., Barsberg, S., and Venås, T.M. (2010). The fluorescence characteristics of furfurylated wood studied by fluorescence spectroscopy and confocal laser scanning microscopy. Wood Sci. Technol. 44, 51–65. https://doi.org/10.1007/s00226-009-0255-4.Search in Google Scholar
Treu, A., Pilgard, A., Puttmann, S., Krause, A., and Westin, M. (2009). Material properties of furfurylated wood for window production. In: 40th Annual Meeting, International Research Group on Wood Protection, Beijing, China, pp. 1–13.Search in Google Scholar
Venås, T.M. and Rinnan, Å. (2008). Determination of weight percent gain in solid wood modified with in situ cured furfuryl alcohol by near-infrared reflectance spectroscopy. Chemometr. Intell. Lab.92: 125–130, https://doi.org/10.1016/j.chemolab.2008.02.002.Search in Google Scholar
Vetter, T.M., Depraetere, G., Janssen, C., Stevens, M., and Acker, J.V. (2008). Methodology to assess both the efficacy and ecotoxicology of preservative-treated and modified wood. Ann. Forest Sci. 65, 504. https://doi.org/10.1051/forest:2008030.10.1051/forest:2008030Search in Google Scholar
Wang, X., Liu, X., and Zhang, C. (2014). Parametric optimization and range analysis of Organic Rankine Cycle for binary-cycle geothermal plant. Energy Convers. Manag. 80: 256–265, https://doi.org/10.1016/j.enconman.2014.01.026.Search in Google Scholar
Westin, M., Rapp, A.O., and Nilsson, T. (2004). Durability of pine modified by 9 different methods. IRG/WP 04-40288. International Research Group on Wood Protection, Stockholm, Sweden.Search in Google Scholar
Yang, T., Cao, J., and Ma, E. (2019). How does delignification influence the furfurylation of wood?. Ind. Crop. Prod. 135, 91–98. https://doi.org/10.1016/j.indcrop.2019.04.019.Search in Google Scholar
Yao, M., Yang, Y., Song, J., Yu, Y., and Jiang, Y. (2017). Lignin-based catalysts for Chinese fir furfurylation to improve dimensional stability and mechanical properties. Ind. Crop. Prod. 107, 38–44. https://doi.org/10.1016/j.indcrop.2017.05.038.Search in Google Scholar
Zimmer, K., Treu, A., and McCulloh, K.A. (2014). Anatomical differences in the structural elements of fluid passage of Scots pine sapwood with contrasting treatability. Wood Sci. Technol. 48, 435–447. https://doi.org/10.1007/s00226-014-0619-2.Search in Google Scholar
© 2020 Walter de Gruyter GmbH, Berlin/Boston