Skip to main content
Log in

Correlation between the properties of hybrid ion-exchange membranes and the nature and dimensions of dopant particles

  • Published:
Nanotechnologies in Russia Aims and scope Submit manuscript

Abstract

This review is devoted to a description of the properties of hybrid membranes composed of high-molecular cation exchangers and nanoparticles of inorganic compounds. The techniques for preparing hybrid membranes, their conductive properties under high and low humidity, the selectivity of transport processes, and the mechanical characteristics are discussed. These properties are considered on the basis of a recently developed model of the semielasticity of membrane pore walls that was proposed to explain changes in membrane ionic conductivity. In this review, this model advanced further toward an explanation of other membrane properties, including their selectivity and mechanical strength.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. G. Alberti and M. Casciola, “Composite Membranes for Medium-Temperature Fuel Cells,” Annu. Rev. Mater. Res. 33, 129 (2003).

    CAS  Google Scholar 

  2. P. Jannasch, Curr. Opin. Colloid Interface Sci. 8, 96 (2003).

    CAS  Google Scholar 

  3. D. J. Jones and J. Roziere, Handbook of Fuel Cells-Fundamentals, Technology and Applications, Vol. 3: Fuel Cell Technology and Applications, Ed. by W. Vielstich, H. A. Gasteiger, and A. Lamm (Wiley, New York, 2003).

    Google Scholar 

  4. T. Xu, J. Membr. Sci. 263, 1 (2005).

    CAS  Google Scholar 

  5. A. B. Yaroslavtsev and V. V. Nikonenko, Nanotechnol. Russ. 4, 137 (2009).

    Google Scholar 

  6. A. B. Yaroslavtsev, Russ. Chem. Rev. 78, 1013 (2009).

    CAS  Google Scholar 

  7. H. Ahmad, S. K. Kamarudin, U. A. Hasran, and W. R. W. Daud, Int. J. Hydrogen Energy 35, 2160 (2010).

    CAS  Google Scholar 

  8. S. J. Peighambardoust, S. Rowshanzamir, and M. Amjadi, Int. J. Hydrogen Energy 35, 9349 (2010).

    CAS  Google Scholar 

  9. S. Bose, T. Kuila, T. X. H. Nguyen, N. H. Kim, K.-t. Lau, and J. H. Lee, Prog. Polym. Sci. 36, 813 (2011).

    CAS  Google Scholar 

  10. B. P. Tripathi and V. K. Shahi, Prog. Polym. Sci. 36, 945 (2011).

    CAS  Google Scholar 

  11. J. Maier, Solid State Chem. 23, 171 (1995).

    CAS  Google Scholar 

  12. A. B. Yaroslavtsev, Chemistry of Solids (Nauchn. Mir, Moscow, 2009) [in Russian].

    Google Scholar 

  13. A. B. Yaroslavtsev, Yu. A. Dobrovol’skii, N. S. Shaglaeva, L. A. Frolova, E. V. Gerasimova, and E. A. Sanginov, Russ. Chem. Rev. 81, 191 (2012).

    CAS  Google Scholar 

  14. E. Yu. Voropaeva, E. A. Sanginov, V. I. Volkov, A. A. Pavlov, A. S. Shalimov, I. A. Stenina, and A. B. Yaroslavtsev, Russ. J. Inorg. Chem. 53, 1536 (2008).

    Google Scholar 

  15. S. A. Novikova, E. Yu. Safronova, A. A. Lysova, and A. B. Yaroslavtsev, Mendeleev Commun. 20, 156 (2010).

    CAS  Google Scholar 

  16. V. A. Gerasin, T. A. Zubova, F. N. Bakhov, A. A. Barannikov, N. D. Merekalova, Yu. M. Korolev, and E. M. Antipov, Ross. Nanotekhnol. 2(1–2), 90 (2007).

    Google Scholar 

  17. A. B. Yaroslavtsev, V. V. Nikonenko, and V. I. Zabolotskii, Russ. Chem. Rev. 72, 393 (2003).

    CAS  Google Scholar 

  18. I. A. Stenina, A. B. Yaroslavtsev, Ph. Sistat, G. Pourcelly, and A. I. Rebrov, Desalination 170, 49 (2004).

    CAS  Google Scholar 

  19. E. Yu. Voropaeva, I. A. Stenina, and A. B. Yaroslavtsev, Russ. J. Inorg. Chem. 53, 1531 (2008).

    Google Scholar 

  20. E. Yu. Safronova and A. B. Yaroslavtsev, “Nafion-Type Membranes Modified with Modified Silica Nanoparticles,” Solid State Ionics 188, 2012 (in press).

  21. Handbook of Fuel Cells-Fundamentals, Technology and Applications, Vol. 3: Fuel Cell Technology and Applications, Ed. by W. Vielstich and H. A. Gasteiger, and A. Lamm (Wiley, London, 2003).

    Google Scholar 

  22. K. D. Kreuer, S. Paddison, E. Spohr, and M. Schuster, Chem. Rev. 104, 4637 (2004).

    CAS  Google Scholar 

  23. C. C. Liang, J. Electrochem. Soc. 120, 1289 (1973).

    CAS  Google Scholar 

  24. J. B. Wagner, Mater. Res. Bull. 15, 1691 (1980).

    CAS  Google Scholar 

  25. J. Maier, J. Phys. Chem. Solids 46, 309 (1985).

    CAS  Google Scholar 

  26. J. Jamnik, H.-U. Habermeier and J. Maier, Phys. B (Amsterdam, Neth.) 204, 57 (1995).

    CAS  Google Scholar 

  27. A. A. Lysova, I. A. Stenina, S. V. Dolgopolov, Yu. G. Gorbunova, N. A. Kononenko, and A. B. Yaroslavtsev, Dokl. Phys. Chem. 427, 142 (2009).

    CAS  Google Scholar 

  28. E. Yu. Safronova, I. A. Stenina, and A. B. Yaroslavtsev, Russ. J. Inorg. Chem. 55, 13 (2010).

    CAS  Google Scholar 

  29. I. A. Stenina, E. Yu. Voropaeva, A. A. Ilyina, and A. B. Yaroslavtsev, Polym. Adv. Technol. 20, 566 (2009).

    Google Scholar 

  30. E. Yu. Voropaeva, I. A. Stenina, and A. B. Yaroslavtsev, Russ. J. Inorg. Chem. 53, 1677 (2008).

    Google Scholar 

  31. S. A. Novikova, G. Yu. Yurkov, and A. B. Yaroslavtsev, Mendeleev Commun. 20, 89 (2010).

    CAS  Google Scholar 

  32. T. D. Gierke, G. E. Munn, and F. C. Wilson, J. Polym. Sci., Polym. Phys. 19, 1687 (1981).

    CAS  Google Scholar 

  33. W. Y. Hsu and T. D. Gierke, J. Membr. Sci. 13, 307 (1983).

    CAS  Google Scholar 

  34. A. B. Yaroslavtsev, Yu. A. Karavanova, and E. Yu. Safronova, Membr. Membr. Tekhnol. 1, 3 (2011).

    Google Scholar 

  35. M. Watanabe, H. Uchida, Y. Seki, and M. Emori, J. Electrochem. Soc. 143, 3847 (1996).

    CAS  Google Scholar 

  36. H. Hagihara, H. Uchida, and M. Watanabe, Electrochim. Acta 51, 3979 (2006).

    CAS  Google Scholar 

  37. A. K. Sahu, S. Pitchumani, P. Sridhar, and A. K. Shukla, Fuel Cells 9, 139 (2009).

    CAS  Google Scholar 

  38. H. Xu, M. Wu, Y. Liu, V. Mittal, F. Kassim, B. Vieth, L. Bonville, H. R. Kunz, and J. M. Fenton, ECS Trans. 3, 561 (2006).

    CAS  Google Scholar 

  39. V. Ramani, H. R. Kunz, and J. M. Fenton, J. Membr. Sci. 232, 31 (2004).

    CAS  Google Scholar 

  40. E. Yu. Safronova, I. A. Stenina, A. A. Pavlov, V. I. Volkov, G. Yu. Yurkov, A. B. Yaroslavtsev, Russ. J. Inorg. Chem. 55, 152 (2011).

    Google Scholar 

  41. V. I. Volkov, E. V. Volkov, S. V. Timofeev, E. A. Sanginov, A. A. Pavlov, E. Yu. Safronova, I. A. Stenina, A. B. Yaroslavtsev, Russ. J. Inorg. Chem. 55, 318 (2010).

    CAS  Google Scholar 

  42. A. B. Yaroslavtsev and D. L. Gorbatchev, J. Mol. Struct. 416, 63 (1997).

    CAS  Google Scholar 

  43. A. I. Perepelkina, E. Yu. Safronova, A. S. Shalimov, and A. B. Yaroslavtsev, Membr. Membr. Tekhnol. 2, 27 (2012).

    Google Scholar 

  44. A. S. Shalimov, S. A. Novikova, I. A. Stenina, and A. B. Yaroslavtsev, Russ. J. Inorg. Chem. 51, 700 (2006).

    Google Scholar 

  45. S. A. Novikova, G. Yu. Yurkov, and A. B. Yaroslavtsev, Inorg. Mater. 46, 793 (2010).

    CAS  Google Scholar 

  46. A. A. Lysova, I. A. Stenina, Yu. G. Gorbunova, N. A. Kononenko, and A. B. Yaroslavtsev, Russ. J. Electrochem. 47, 579 (2011).

    CAS  Google Scholar 

  47. Yu. A. Karavanova, Z. M. Kas’kova, A. G. Veresov, and A. B. Yaroslavtsev, Russ. J. Inorg. Chem. 55, 479 (2010).

    CAS  Google Scholar 

  48. R. Jiang, H. R. Kunz, and J. M. Fenton, J. Membr. Sci. 272, 116 (2006).

    CAS  Google Scholar 

  49. A. D’ Epifanio, B. Mecher, E. Fabbri, A. Rainer, E. Traversa, and S. Licoccia, J. Electrochem. Soc. 154, B1148 (2007).

    Google Scholar 

  50. Y. Tominaga, I.-C. Hong, S. Asai, and M. Sumita, J. Power Sources 171, 530 (2007).

    CAS  Google Scholar 

  51. S. Ren, G. Sun, C. Li, Z. Liang, Z. Wu, W. Jin, X. Qin, and X. Yang, J. Membr. Sci. 282, 450 (2006).

    CAS  Google Scholar 

  52. H. Tang, Z. Wan, M. Pan, and S. P. Jiang, Electrochem. Commun. 9, 2003 (2007).

    CAS  Google Scholar 

  53. K. T. Adjemian, S. Srinivasan, J. Benziger, and A. B. Bocarsly, J. Power Sources 109, 356 (2002).

    CAS  Google Scholar 

  54. K. T. Adjemian, S. J. Lee, S. Srinivasan, J. Benziger, and A. B. Bocarsly, J. Electrochem. Soc. 149, A256 (2002).

    CAS  Google Scholar 

  55. Y.-F. Lin, C.-Y. Yen, C.-C. M. Ma, S.-H. Liao, C.-H. Lee, Y.-H. Hsiao, and H.-P. Lin, J. Power Sources 171, 388 (2007).

    CAS  Google Scholar 

  56. B. P. Ladewig, R. B. Knott, A. J. Hill, J. D. Riches, J. W. White, D. J. Martin, J. C. D. Costa, and G. Q. Lu, Chem. Mater. 19, 2372 (2007).

    CAS  Google Scholar 

  57. F. Pereira, K. Valle, P. Belleville, A. Morin, S. Lambert, and C. Sanchez, Chem. Mater. 20, 1710 (2008).

    CAS  Google Scholar 

  58. C. Li, G. Sun, S. Ren, J. Liu, Q. Wang, Z. Wu, H. Sun, and W. Jin, J. Membr. Sci. 272, 50 (2006).

    CAS  Google Scholar 

  59. P. Staiti, A. S. Arico, V. Baglio, F. Lufrano, E. Passalacqua, and V. Antonucci, Solid State Ionics 145, 101 (2001).

    CAS  Google Scholar 

  60. W. Xu, T. Lu, C. Liu, and W. Xing, Electrochim. Acta 50, 3280 (2005).

    CAS  Google Scholar 

  61. J. Shan, G. Vaivars, H. Luo, R. Mohamed, and V. Linkov, Pure Appl. Chem. 78, 1781 (2006).

    CAS  Google Scholar 

  62. C. H. Rhee, Y. Kim, J. S. Lee, H. K. Kim, and H. Chang, J. Power Sources 159, 1015 (2006).

    CAS  Google Scholar 

  63. Y. S. Choi, T. K. Kim, E. A. Kim, S. H. Joo, C. Pak, Y. H. Lee, H. Chang, and D. Seung, Adv. Mater. 20, 2341 (2008).

    CAS  Google Scholar 

  64. B. A. Holmberg, X. Wang, and Y. S. Yan, Microporous Mesoporous Mater. 74, 189 (2004).

    CAS  Google Scholar 

  65. Z. Chen, B. Holmberg, W. Li, X. Wang, W. Deng, R. Munoz, and Y. Yan, Chem. Mater. 18, 5669 (2006).

    CAS  Google Scholar 

  66. N. F. Uvarov, Composition Solid Electrolytes (Sib. Otd. Ross. Akad. Nauk, Novosibirsk, 2008) [in Russian].

    Google Scholar 

  67. V. V. Nikonenko, A. B. Yaroslavtsev, and G. Pourcelly, “Ion Transfer in and through Charged Membranes. Structure, Properties, Theory,” in Ionic Interactions in Natural and Synthetic Macromolecules, Ed. by A. Ciferri and A. Perico (Wiley, New Jersey, 2012), Chap. 9, p. 267.

    Google Scholar 

  68. Perfluorinated Ionomer Membranes, Ed. by A. Eisenberg and H. L. Yager (Am. Chem. Soc., Washington, 1982).

    Google Scholar 

  69. Yu. A. Panshin, S. G. Malkevich, and Ts. S. Dunaevskaya, Fluoroplasts (Khimiya, Leningrad, 1978) [in Russian].

    Google Scholar 

  70. T. A. Zawodzinski, J. M. Neeman, L. O. Sillerud, and S. Cottesfeld, J. Phys. Chem. 95, 6040 (1991).

    CAS  Google Scholar 

  71. Y. Zhang, H. Zhang, C. Bi, and X. Zhu, Electrochim. Acta 53, 4096 (2008).

    CAS  Google Scholar 

  72. F. Lufrano, V. Baglio, P. Staiti, A. Arico, and V. Antonucci, Desalination 199, 283 (2006).

    CAS  Google Scholar 

  73. L. M. de Carvalho, A. R. Tan, and G. A. de Souza, J. Appl. Polym. Sci. 110, 1690 (2008).

    Google Scholar 

  74. W.-B. Yang, H. Zhu, M. Wang, and S.-C. Zhang, J. Funct. Mater. 38, 2077 (2007).

    CAS  Google Scholar 

  75. N. H. Jalani, K. Dunn, and R. Datta, Electrochim. Acta 51, 553 (2005).

    CAS  Google Scholar 

  76. V. S. Silva, B. Ruffmann, H. Silva, V. B. Silva, A. Mendes, L. M. Madeira, and S. Nunes, J. Membr. Sci. 284, 137 (2006).

    CAS  Google Scholar 

  77. Z.-G. Shao, H. Xu, I.-M. Hsing, and H. Zhang, Chem. Eng. Commun. 194, 667 (2007).

    CAS  Google Scholar 

  78. C. Yang, S. Srinivasan, A. S. Arico, P. Creti, V. Baglio, and V. Antonucci, Electrochem. Solid State Lett. 4, A31 (2001).

    CAS  Google Scholar 

  79. P. Costamagna, C. Yang, A. B. Bocarsly, and S. Srinivasan, Electrochim. Acta. 47, 1023 (2002).

    CAS  Google Scholar 

  80. C. Yang, S. Srinivasan, A. B. Bocarsly, S. Tulyani, and J. B. Benziger, J. Membr. Sci. 237, 145 (2004).

    CAS  Google Scholar 

  81. G. Alberti, M. Casciola, D. Capitani, A. Donnadio, R. Narducci, M. Pica, and M. Sganappa, Electrochim. Acta 52, 8125 (2007).

    CAS  Google Scholar 

  82. S. Sang, Q. Wu, and K. Huang, J. Membr. Sci. 305, 118 (2007).

    CAS  Google Scholar 

  83. A. I. Fomenkov, I. Yu. Pinus, A. S. Peregudov, Ya. V. Zubavichus, A. R. Khokhlov, and A. B. Yaroslavtsev, Polym. Sci., Ser. B 49, 177 (2007).

    Google Scholar 

  84. A. S. Shalimov, A. I. Perepelkina, I. A. Stenina, A. I. Rebrov, A. B. Yaroslavtsev, Russ. J. Inorg. Chem. 54, 356 (2009).

    Google Scholar 

  85. K. Tasaki, R. DeSousa, H. B. Wang, J. Gasa, V. A. Venkatesan, P. Pugazhendhi, and R. O. Loutfy, J. Membr. Sci. 281, 570 (2006).

    CAS  Google Scholar 

  86. Y. H. Liu, B. L. Yi, Z. G. Shao, D. M. Xing, H. M. Zhang, Electrochem. Solid State 9, A356 (2006).

    CAS  Google Scholar 

  87. Z.-G. Shao, P. Joghee, and I.-M. Hsing, J. Membr. Sci. 229, 43 (2004).

    CAS  Google Scholar 

  88. H.-J. Kim, Y.-G. Shul, and H. Han, J. Power Sources 158, 137 (2006).

    CAS  Google Scholar 

  89. G. Ye, C. A. Hayden, and G. R. Goward, Macromolecules 40, 1529 (2007).

    CAS  Google Scholar 

  90. L. Wang, B. L. Yi, H. M. Zhang, and D. M. Xing, Electrochim. Acta 52, 5479 (2007).

    CAS  Google Scholar 

  91. V. Ramani, H. R. Kunz, and J. M. Fenton, J. Membr. Sci. 279, 506 (2006).

    CAS  Google Scholar 

  92. A. Mahreni, A. B. Mohamad, A. A. H. Kadhum, W. R. W. Daud, and S. E. Iyuke, J. Membr. Sci. 327, 32 (2009).

    CAS  Google Scholar 

  93. M. Helen, B. Viswanathan, and S. S. Murthy, J. Membr. Sci. 292, 98 (2007).

    CAS  Google Scholar 

  94. V. Ramani, H. R. Kunz, and J. M. Fenton, Electrochim. Acta 50, 1181 (2005).

    CAS  Google Scholar 

  95. V. Ramani, H. R. Kunz, and J. M. Fenton, J. Power Sources 152, 182 (2005).

    CAS  Google Scholar 

  96. M. Amirinejad, S. S. Madaeni, M. A. Navarra, E. Rafiee, and B. Scrosati, J. Power Sources 196, 988 (2011).

    CAS  Google Scholar 

  97. Y. Xiang, M. Yang, J. Zhang, F. Lan, and S. Lu, J. Membr. Sci. 368, 241 (2011).

    CAS  Google Scholar 

  98. V. Ramani, H. R. Kunz, and J. M. Fenton, J. Membr. Sci. 266, 110 (2005).

    CAS  Google Scholar 

  99. L. Li and Y. Wang, J. Power Sources 162, 541 (2006).

    CAS  Google Scholar 

  100. J. T. Hinatsu, M. Mizuhata, and H. Takenaka, J. Electrochem. Soc. 141, 1493 (1994).

    CAS  Google Scholar 

  101. P. Genova-Dimitrova, B. Baradie, D. Foscallo, C. Poinsignon, and J. Y. Sanchez, J. Membr. Sci. 185, 59 (2001).

    CAS  Google Scholar 

  102. M. Yamada and I. Honmia, J. Phys. Chem. B 110, 20486 (2006).

    CAS  Google Scholar 

  103. Z. Wang, H. Ni, C. Zhao, X. Li, T. Fu, and H. Na, J. Polym. Sci., Part B: Polym. Phys. 44, 1967 (2006).

    CAS  Google Scholar 

  104. R. Kannan, B. A. Kakade, and V. K. Pillai, Angew. Chem., Int. Ed. Engl. 47, 2653 (2008).

    CAS  Google Scholar 

  105. I. A. Stenina, A. A. Il’ina, I. Yu. Pinus, V. G. Sergeev, and A. B. Yaroslavtsev, Russ. Chem. Bull. 57, 2261 (2008).

    CAS  Google Scholar 

  106. N. P. Berezina, A. A.-R. Kubaisy, S. V. Timofeev, and L. V. Karpenko, J. Solid State Electrochem. 11, 378 (2006).

    Google Scholar 

  107. N. P. Berezina, N. A. Kononenko, N. V. Loza, and A. A.-R. Sycheva, Russ. J. Electrochem. 43, 1340 (2007).

    CAS  Google Scholar 

  108. Ch. Kittel’, Introduction to Physics of Solids (Nauka, Moscow, 1978) [in Russian].

    Google Scholar 

  109. V. I. Zabolotskii, K. V. Protasov, M. V. Shapafan, and A. B. Yaroslavtsev, Pat. Appl. No. 2010150228/05 (072502), Russia (December 7, 2010).

  110. O. V. Bobreshova, A. V. Parshina, K. A. Polumestnaya, E. Yu. Safronova, K. Yu. Yankina, and A. B. Yaroslavtsev, Mendeleev Commun. 22(2), 83 (2012).

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to A. B. Yaroslavtsev.

Additional information

Original Russian Text © A.B. Yaroslavtsev, 2012, published in Rossiiskie Nanotekhnologii, 2012, Vol. 7, Nos. 9–10.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Yaroslavtsev, A.B. Correlation between the properties of hybrid ion-exchange membranes and the nature and dimensions of dopant particles. Nanotechnol Russia 7, 437–451 (2012). https://doi.org/10.1134/S1995078012050175

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1995078012050175

Keywords

Navigation