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Cyclomagnesiation of nitrogen-containing 1,2-dienes with grignard compounds catalyzed by Cp2TiCl2

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Abstract

Cyclomagnesiation of nitrogen-containing 1,2-dienes with Grignard compounds in the presence of activated magnesium and Cp2TiCl2 as catalyst afforded 2,5-bis(aminoalkylidene)magnesacyclopentanes in high yield.

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Authors and Affiliations

  1. Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, pr. Oktyabrya 141, Ufa, 450075, Bashkortostan, Russia

    V. A. D’yakonov, A. A. Makarov, E. Kh. Makarova, L. M. Khalilov & U. M. Dzhemilev

Authors
  1. V. A. D’yakonov
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  2. A. A. Makarov
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  3. E. Kh. Makarova
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  4. L. M. Khalilov
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  5. U. M. Dzhemilev
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Corresponding author

Correspondence to V. A. D’yakonov.

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Original Russian Text © V.A. D’yakonov, A.A. Makarov, E.Kh. Makarova, L.M. Khalilov, U.M. Dzhemilev, 2012, published in Zhurnal Organicheskoi Khimii, 2012, Vol. 48, No. 3, pp. 357–361.

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D’yakonov, V.A., Makarov, A.A., Makarova, E.K. et al. Cyclomagnesiation of nitrogen-containing 1,2-dienes with grignard compounds catalyzed by Cp2TiCl2 . Russ J Org Chem 48, 349–353 (2012). https://doi.org/10.1134/S1070428012030025

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  • DOI: https://doi.org/10.1134/S1070428012030025

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