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Poly(N-vinylimidazole) as an efficient and recyclable catalyst of the aza-Michael reaction in water

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Abstract

Poly(N-vinylimidazole) effectively catalyzed Michael addition of 1H-1,2,4-triazole, 3,5-dimethyl-1H-1,2,4-triazole, uracil, oxazolidin-2-one, and succinimide to but-3-en-2-one, cyclohex-2-en-1-one, methyl acrylate, and methyl vinyl sulfone in water at room temperature. The catalyst can readily be regenerated and repeatedly used at least five times without loss in activity, as shown in the reaction of 1H-1,2,4-triazole with but-3-en-2-one as an example.

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Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    I. P. Beletskaya, E. A. Tarasenko & V. S. Tyurin

  2. Faculty of Chemistry, Moscow State University, Vorob’evy gory 1, Moscow, 119992, Russia

    A. R. Khokhlov

Authors
  1. I. P. Beletskaya
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  2. E. A. Tarasenko
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  3. A. R. Khokhlov
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  4. V. S. Tyurin
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Correspondence to I. P. Beletskaya.

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Original Russian Text © I.P. Beletskaya, E.A. Tarasenko, A.R. Khokhlov, V.S. Tyurin, 2010, published in Zhurnal Organicheskoi Khimii, 2010, Vol. 46, No. 4, pp. 473–478.

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Beletskaya, I.P., Tarasenko, E.A., Khokhlov, A.R. et al. Poly(N-vinylimidazole) as an efficient and recyclable catalyst of the aza-Michael reaction in water. Russ J Org Chem 46, 461–467 (2010). https://doi.org/10.1134/S1070428010040019

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  • DOI: https://doi.org/10.1134/S1070428010040019

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