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Syntheses on the basis of 2H-chromen-2-one and 2H-chromene-2-thione

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Abstract

4-Hydroxy-2H-chromen-2-one and 4-hydroxy-2H-chromene-2-thione reacted with allyl bromide, 1,1,3-trichloroprop-1-ene, and 1,3-dichlorobut-2-ene to give the corresponding ethers, which were oxidized to (2-oxo-2H-chromen-4-yloxy)acetic acid with potassium permanganate, and various derivatives of that acid were obtained. 3-(3,3-Dichloroprop-2-enyl)-7-hydroxy-4-methyl-2H-chromen-2-one and 3-(3,3-dichloroprop-2-enyl)-7-hydroxy-4-methyl-2H-chromene-2-thione were synthesized, and some their transformations were studied.

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Authors and Affiliations

  1. Erevan State University, ul. A. Manukyana 1, Erevan, 375025, Armenia

    A. A. Avetisyan & A. G. Alvandzhyan

Authors
  1. A. A. Avetisyan
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  2. A. G. Alvandzhyan
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Original Russian Text © A.A. Avetisyan, A.G. Alvandzhyan, 2006, published in Zhurnal Organicheskoi Khimii, 2006, Vol. 42, No. 7, pp. 1080–1084.

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Avetisyan, A.A., Alvandzhyan, A.G. Syntheses on the basis of 2H-chromen-2-one and 2H-chromene-2-thione. Russ J Org Chem 42, 1063–1067 (2006). https://doi.org/10.1134/S1070428006070244

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  • DOI: https://doi.org/10.1134/S1070428006070244

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