Abstract
Multilayer graphene oxide was synthesized by anodic oxidation of dispersed graphite, and the efficiency of its use as an electrode material for a supercapacitor was shown. In an alcohol suspension, the thickness of multilayer graphene oxide particles is less than 0.1 μm with an area of more than 100 μm2. The multilayer graphene oxide electrode has a high specific capacity of 107 F g–1 and a high charge retention rate of 97% after 5000 cycles at a current of 2 A g–1. The multilayer graphene oxide electrode demonstrated a maximum specific energy of 8.7 W h kg–1 at a current density of 0.1 A g–1 and a maximum power of 2291.1 W kg–1 at a current density of 4 A g–1. The impedance data at various DC voltages showed that after 5000 cycles, the charge transfer resistance increases by 26%. It was found that multilayer graphene oxide synthesized by the electrochemical method is a promising electrode material for producing a symmetric supercapacitor.
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REFERENCES
Dreyer, D.R., Jia, H.P., and Bielawski, C.W., Angew. Chem. Int. Ed. Engl., 2010, vol. 49, no. 38, pp. 6965–6968. https://doi.org/10.1002/anie.201002160
Li, Q., Guo, X., Zhang, Y., Zhang, W., Ge, C., Zhao, L., Wang, X., Zhang, H., Chen, J., Wang, Z., and Sun, L., J. Mater. Sci. Technol.. 2017, vol. 33, no. 8, pp. 793–799. https://doi.org/10.1016/j.jmst.2017.03.018
Yang, S., Lohe, M.R., Müllen, K., and Feng, X., Adv. Mater. 2016, vol. 28, no. 29, pp. 6213–6221. https://doi.org/10.1002/adma.201505326
Yakovlev, A.V., Zabudʹkov, S.L., Yakovleva, E.V., and Finaenov, A.I., Russ. J. Appl. Chem., 2006, vol. 79, no. 10, pp. 1600–1604. https://doi.org/10.1134/S1070427206100077
Wang, P., Yao, T., Sun, B., Fan, X., Dong, S., Bai, Y., and Shi, Y., Colloids Surf. A, 2017, vol. 513, pp. 396–401. https://doi.org/10.1016/j.colsurfa.2016.11.002
Yakovlev, A.V., Yakovleva, E.V., Tseluikin, V.N., Krasnov, V.V., Mostovoy, A.S., Rakhmetulina, L.A., and Frolov, I.N., Russ. J. Electrochem., 2019, vol. 55, no. 12, pp. 1196–1202. https://doi.org/10.1134/S102319351912019X
Pei, S., Wei, Q., Huang, K., Cheng, H.-M., and Ren, W., Nat. Commun., 2018, vol. 9, p. 145. https://doi.org/10.1038/s41467-017-02479-z
Cao, J., He, P., Mohammed, M., Zhao, X., Young, R., Derby, B., Kinloch, I., and Dryfe, R., J. Am. Chem. Soc., 2017, vol. 139, pp. 17446–17456. https://doi.org/10.1021/jacs.7b08515
Ali, G., Yusoff, M.M., and Chong, K.-F., ARPN J. Eng. Appl. Sci., 2016, vol. 11, no. 16, pp. 9712–9717.
Jiang, B., Tian, C., Wang, L., Sun, L., Chen, C., Nong, X., Qiao, Y., and Fu, H., Appl. Surf. Sci., 2012, vol. 258, pp. 3438–3443. https://doi.org/10.1016/j.apsusc.2011.11.091
Li, Z., Gadipelli, S., Yang, Y., and Guo, Z., Small, 2017, vol. 13, no. 44, pp. 1702474. https://doi.org/10.1002/smll.201702474
Yakovlev, A.V., Yakovleva, E.V., Tseluikin, V.N., Krasnov, V.V., Mostovoy, A.S., Vikulova, M.A., Frolov, I.H., and Rakhmetulina, L.A., Russ. J. Appl. Chem., 2020, vol. 93, no. 2, pp. 219−224. https://doi.org/10.1134/S1070427220020093
Ye, J., Zhang, H., Chen, Y., Cheng, Z., Hu, L., and Ran, Q., J. Power Sources, 2012, vol. 212, pp. 105–110. https://doi.org/10.1016/j.jpowsour.2012.03.101
Wang, J., Salihi, E., and Šiller, L., Mater. Sci. Eng. C, 2017, vol. 72, pp. 1–6. https://doi.org/10.1016/j.msec.2016.11.017
Edwards, R.S., Coleman, K.S., Nanoscale, 2013, vol. 5, no. 1, pp. 38–51. https://doi.org/10.1039/c2nr32629a
Avouris, P., Dimitrakopoulos, C., Mater. Today, 2012, vol. 15, no. 3, pp. 86–97. https://doi.org/10.1016/S1369-7021(12)70044-5
Hou, R., Gund, G.S., Qi, K., Nakhanivej, P., Liu, H., Li, F., and Park, H.S., Energy Stor. Mater., 2019, vol. 19, pp. 212–241. https://doi.org/10.1016/j.ensm.2019.03.002
Salitra, G., Soffer, A., Eliad, L., Cohen, Y., and Aurbach, D., J. Electrochem. Soc., 2000, vol. 147, pp. 2486–2493. https://doi.org/10.1149/1.1393557
Li, Z., Chen, J., Microelectron. Eng., 2008, vol. 85, no. 7, pp. 1549–1554. https://doi.org/10.1016/j.mee.2008.02.016
Fic, K., He, M., Berg, E.J., Novák, P., and Frackowiak, E., Carbon, 2017, vol. 120, pp. 281–293. https://doi.org/10.1016/j.carbon.2017.05.061
He, M., Fic, K., Frąckowiak, E., Novák, P., and Berg, E.J., ChemElectroChem., 2019, vol. 6, no. 2, pp. 566–573. https://doi.org/10.1002/celc.201801146
Liu, F., Cao, X., Cui, L., Yue, L., Jia, D., and Liu, J., J. Power Sources, 2019, vol. 421, pp. 169–178. https://doi.org/10.1016/j.jpowsour.2019.03.011
Rui, B., Yang, M., Zhang, L., Jia, Y., Shi, Y., Histed, R., and Fan, L., J. Appl. Electrochem., 2020, vol. 50, pp. 407–420. https://doi.org/10.1007/s10800-020-01397-1
ACKNOWLEDGMENTS
N.V. Gorshkov would like to thank the German Academic Exchange Service (DAAD), as well as D.A. Mikhailova (IFW Dresden) and M.V. Gorbunov (IFW Dresden) for discussing the mechanisms of accumulation of electrochemical energy by carbon materials.
Funding
Financial support for the work in carrying out the synthesis of multilayer graphene oxide by anodic oxidation of dispersed graphite and SEM was provided by the Russian Science Foundation (contract no. 19-73-10133). Preparation of a multilayer graphene oxide electrode and electrochemical tests were carried out with the financial support of the Russian Foundation for Basic Research within the framework of scientific project no. 18-29-19048.
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Translated from Zhurnal Prikladnoi Khimii, No. 3, pp. 388–396, January, 2021 https://doi.org/10.31857/S0044461821030142
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Gorshkov, N.V., Yakovleva, E.V., Krasnov, V.V. et al. Electrode for a Supercapacitor Based on Electrochemically Synthesized Multilayer Graphene Oxide. Russ J Appl Chem 94, 370–378 (2021). https://doi.org/10.1134/S1070427221030149
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DOI: https://doi.org/10.1134/S1070427221030149