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The state of palladium in the nanosized hydrogenation catalysts modified with elemental phosphorus

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Abstract

The size, nature, and surface state of nanoparticles formed by reduction of Pd(acac)2 with hydrogen in the presence of P4 have been elucidated by means of X-ray photoelectron spectroscopy, X-ray powder diffraction analysis, and transmission electron microscopy. The nanoparticles (average diameter of 5.6 nm) consist of Pd6P and palladium nanoclusters (at initial ratio P/Pd = 0.3). Dimethylammonium dihydro- and hydrophosphates are found in the surface layer of the catalyst nanoparticles. The nanoparticles are stabilized by ammonium salts formed via dimethylformamide hydrolysis.

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Authors and Affiliations

  1. Irkutsk State University, ul. K. Marksa 1, Irkutsk, 664003, Russia

    L. B. Belykh, N. I. Skripov, T. P. Stepanova & F. K. Schmidt

  2. Vinogradov Institute of Geochemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk, Russia

    V. V. Akimov & V. L. Tauson

Authors
  1. L. B. Belykh
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  2. N. I. Skripov
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  3. V. V. Akimov
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  4. V. L. Tauson
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  5. T. P. Stepanova
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  6. F. K. Schmidt
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Correspondence to L. B. Belykh.

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Original Russian Text © L.B. Belykh, N.I. Skripov, V.V. Akimov, V.L. Tauson, T.P. Stepanova, F.K. Schmidt, 2013, published in Zhurnal Obshchei Khimii, 2013, Vol. 83, No. 12, pp. 1974–1983.

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Belykh, L.B., Skripov, N.I., Akimov, V.V. et al. The state of palladium in the nanosized hydrogenation catalysts modified with elemental phosphorus. Russ J Gen Chem 83, 2260–2268 (2013). https://doi.org/10.1134/S1070363213120062

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  • DOI: https://doi.org/10.1134/S1070363213120062

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