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Some Transformations of trans-Tetrapyridine Complexes of Nitrosoruthenium: Crystal Structures of [Ru(NO)Py4(OH)](PF6)2 ⋅ (CH3)2CO and [H5O2]2[Ru(NO)Py4Cl]Cl4

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Abstract

The slow evaporation of an acetone solution containing trans-[Ru(NO)Py4(OH)]2+ cations and hexafluorophosphate anions results in the crystallization of trans-[Ru(NO)Py4(OH)](PF6)2 ⋅ (CH3)2CO (I). The reactions of trans‑[Ru(NO)Py4(OH)]Cl2 ⋅ H2O with solutions of chloric or hydrochloric acid followed by the evaporation of the reaction solutions at ambient temperature afford trans-[Ru(NO)Py4(H2O)](ClO4)3 (II) or [H5O2]2[Ru(NO)Py4Cl]Cl4 (III), respectively. The obtained chloride complex III is unstable and at ambient temperature eliminates hydrogen chloride to transform into trans-[Ru(NO)Py4Cl]Cl2 ⋅ 4H2O (IV). The crystal structures of compounds I and III are determined by X-ray structure analysis (CIF files ССDC nos. 1421042 (I) and 1421041 (III)).

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ACKNOWLEDGMENTS

The authors are grateful to N.I. Alferova for recording IR spectra and to N.P. Korotkevich for the detection of powder diffraction patterns.

This work was supported by the Complex program for basic research of the Siberian Branch of the Russian Academy of Sciences, project no. II.1.16.1.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia

    A. N. Makhinya, M. A. Il’in, I. V. Korol’kov & I. A. Baidina

  2. Novosibirsk State University, 630090, Novosibirsk, Russia

    A. N. Makhinya, M. A. Il’in & I. V. Korol’kov

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  1. A. N. Makhinya
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  2. M. A. Il’in
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  3. I. V. Korol’kov
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  4. I. A. Baidina
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Correspondence to M. A. Il’in.

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Translated by E. Yablonskaya

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Makhinya, A.N., Il’in, M.A., Korol’kov, I.V. et al. Some Transformations of trans-Tetrapyridine Complexes of Nitrosoruthenium: Crystal Structures of [Ru(NO)Py4(OH)](PF6)2 ⋅ (CH3)2CO and [H5O2]2[Ru(NO)Py4Cl]Cl4. Russ J Coord Chem 44, 613–618 (2018). https://doi.org/10.1134/S1070328418100093

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