Abstract
Prototypes of organic photovoltaic cells containing a planar phthalocyanine-fullerene hetero-junction are fabricated. The main parameters of photoconversion in such structures are measured in relation to deposition conditions of a photoactive molecular layer (vanadyl phthalocyanine) and to the material of a subcathode interface layer. It is shown that morphological changes in the vanadyl phthalocyanine layer due to a decrease in the deposition rate in vacuum improve the efficiency of the cells roughly by an order of magnitude.
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S. Grammatica and J. Mort, Appl. Phys. Lett. 38, 445 (1981).
X. J. Yu, J. B. Xu, W. Y. Cheung, and N. Ke, J. Appl. Phys. 102, 103711 (2007).
L. F. Santos, R. M. Faria, T. Del Cano, J. A. de Saja, C. J. L. Constantino, C. A. Amorim, and S. Mergulhao, J. Phys. D: Appl. Phys. 41, 125107 (2008).
Y.-L. Pan, X.-D. Liao, Y.-J. Wu, L.-B. Chen, Y.-Y. Zhao, Y.-H. Shen, F.-M. Li, S.-Y. Shen, and D.-Y. Huang, Thin Solid Films 324, 209 (1998).
M. Pfeiffer, A. Beyer, B. Plonnigs, A. Nollau, T. Fritz, K. Leo, D. Schlettwein, S. Hiller, and D. Wohrle, Sol. Energy Mater. Sol. Cells 63, 83 (2000).
T. Sakurai, T. Ohashi, H. Kitazume, M. Kubota, T. Sue- masu, and K. Akimoto, Org. Electron. 12, 966 (2011).
J. Silver, P. Lukes, P. Hey, and M. T. Ahmet, J. Mater. Chem. 1, 881 (1991).
R. Seoudi, G. S. El-Bahy, and Z. A. El Sayed, J. Mol. Struct. 753, 127 (2005).
M. Minami and M. Asai, Jpn. J. Appl. Phys. 26, 1754 (1987).
V. Kolotovska, M. Friedrich, D. R. T. Zahn, and G. Salvan, J. Cryst. Growth 291, 166 (2006).
Y. L. Pan, Y. J. Wu, L. B. Chen, Y. Y. Zhao, Y. H. Shen, F. M. Li, S. Y. Shen, and D. H. Huang, Appl. Phys. A 66, 569 (1998).
J. Ru, K. Kojima, T. Mizutani, and S. Ochiai, Jpn. J. Appl. Phys. 49, 01AE07 (2010).
S. H. Griffiths, M. S. Walker, and P. Goldstein, Mol. Cryst. Liq. Cryst. 33, 149 (1976).
T. Del Cano, V. Parra, M. L. Rodriguez-Mendez, R. F. Aroca, and J. A. De Saja, Appl. Surf. Sci. 246, 327 (2005).
J. Mizuguchi, G. Rihs, and H. R. Karfunkel, J. Phys. Chem. 99, 16217 (1995).
N. Nanai, M. Yudasaka, and Y. Ohki, Thin Solid Films 265, 1 (1995).
P. Y. Stakhira, G. L. Pakhomov, V. V. Cherpak, D. Volynyuk, G. Luka, M. Godlewski, E. Guziewicz, and Z. Hotra, Cent. Eur. J. Phys. 8, 798 (2010).
C.-F. Lin, M. Zhang, S.-W. Liu, T.-L. Chiu, and J.-H. Lee, Int. J. Mol. Sci. 12(1), 476 (2011).
G. L. Pakhomov, L. G. Pakhomov, V. V. Travkin, M. V. Abanin, P. Y. Stakhira, and V. V. Cherpak, J. Mater. Sci. 45, 1854 (2010).
M. Fronk, B. Bräuer, D. R. T. Zahn, and G. Salvan, Thin Solid Films 516, 7916 (2008).
L. Li, Q. Tang, H. Li, and W. Hu, J. Phys. Chem. B 112, 10405 (2008).
A. V. Ziminov, S. M. Ramsh, E. I. Terukov, I. N. Trapeznikova, V. V. Shamanin, and T. A. Yurre, Semiconductors 40, 1131 (2006).
T. A. Basova, V. G. Kiselev, B.-E. Schuster, H. Peisert, and T. Chasse, J. Raman Spectrosc. 40, 2080 (2009).
X. Zhang, Y. Zhang, and J. Jiang, Spectrochim. Acta A 60, 2195 (2004).
E. E. van Faassen and D. Schlettwein, in Handbook of Photochemistry and Photobiology, Vol. 3: Supramolecular Photochemistry, Ed. by H. S. Nalwa (Am. Scientific, California, 2003), pp. 355–409.
C. K. Chan, W. Zhao, A. Kahn, and I. G. Hill, Appl. Phys. Lett. 94, 203306 (2009).
C. K. Chan, E.-G. Kim, J.-L. Bredas, and A. Kahn, Adv. Funct. Mater. 16, 831 (2006).
A. Werner, F. Li, K. Harada, M. Pfeiffer, T. Fritz, K. Leo, and S. Machill, Adv. Func. Mater. 14, 255 (2004).
J. H. Oh, P. Wei, and Zh. Bao, Appl. Phys. Lett. 97, 243305 (2010).
A. G. Werner, F. Li, K. Harada, M. Pfeiffer, T. Fritz, and K. Leo, Appl. Phys. Lett. 82, 4495 (2005).
B. Maennig, J. Drechsel, D. Gebeyehu, P. Simon, F. Kozlowski, A. Werner, F. Li, S. Grundmann, S. Sonntag, M. Koch, K. Leo, M. Pfeiffer, H. Hoppe, D. Meissner, N. S. Sariciftci, I. Riedel, V. Dyakonov, and J. Parisi, Appl. Phys. A 79, 1 (2004).
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Original Russian Text © G.L. Pakhomov, V.V. Travkin, A.Yu. Luk’yanov, P.I. Stakhira, N.V. Kostiv, 2013, published in Zhurnal Tekhnicheskoi Fiziki, 2013, Vol. 83, No. 2, pp. 74–81.
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Pakhomov, G.L., Travkin, V.V., Luk’yanov, A.Y. et al. Thin-film photovoltaic cells based on vanadyl phthalocyanine and fullerene. Tech. Phys. 58, 223–230 (2013). https://doi.org/10.1134/S1063784213020175
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DOI: https://doi.org/10.1134/S1063784213020175