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Preparation of Pt/polypyrrole-ferrocene hydrogen peroxide sensitive electrode for the use as a biosensor

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Abstract

A polypyrrole electrode with ferrocene mediator is prepared and its sensitivity to hydrogen peroxide is investigated. The polypyrrole is deposited upon a 0.5 cm2 Pt plate by the polymerization of pyrrole by scanning the electrode potential between 0.0 and 0.9 V at a scan rate of 50 mV/s. The platinum/polypyrrole-ferrocene (Pt/PPy-Fc) electrode is prepared by adding ferrocene to the coverage medium. The electrode’s sensitivity to hydrogen peroxide is investigated at room temperature using 0.025 M phosphate buffer at pH 7. The working potential is 0.7 V, the concentrations of pyrrole and ferrocene are 0.2 M and 10 mM. Polypyrrole was coated on the electrode surface within 26 cycles.

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References

  1. Choi, M.M.F. and Yiv, T.P., Enzyme Microb. Techonol., 2004, vol. 34, p. 41.

    CAS  Google Scholar 

  2. Pei, J. and Li, X., Anal. Chim. Acta, 2000, vol. 414, p. 205.

    Article  CAS  Google Scholar 

  3. Laudet, E., Botting, N.P., Crayston, J.A., and Dale, N., Biosens. Bioelectron., 2003, vol. 18, p. 43.

    Google Scholar 

  4. Arai, G., Takahashi, S., and Yasumori, I., J. Electroanal. Chem., 1996, vol. 410, p. 173.

    Article  CAS  Google Scholar 

  5. Tian, F., Xu, B., Zhu, L., and Zhu, G., Anal. Chim. Acta, 2001, vol. 443, p. 9.

    Article  CAS  Google Scholar 

  6. Nakabayashi, Y. and Yoshikawa, H., Anal. Sci., 2000, vol. 16, p. 609.

    Article  CAS  Google Scholar 

  7. Razola, S., Ruiz, B.L., Diez, N.M., Mark, H.B., Jr., and Kauffman, J-M., Biosens. Bioelectron., 2002, vol. 17, p. 921.

    Article  CAS  Google Scholar 

  8. Campanella, L., Favera, G., Glancola, D., and Tomassetti, M., J. Pharm. Biomed. Anal., 2003, vol. 32, p. 737.

    CAS  Google Scholar 

  9. Kim, E.J., Haruyama, T., Yanagida, Y., Kobatake, E., and Aizawa, M., Anal. Chim. Acta, 1999, vol. 394, p. 225.

    Article  CAS  Google Scholar 

  10. Gros, P., Durliat, H., and Comtat, M., Electrochim. Acta, 2000, vol. 46, p. 643.

    CAS  Google Scholar 

  11. Umona, M. and Waller, J., Anal. Chem., 1986, vol. 58, p. 2979.

    Google Scholar 

  12. Selampinar, F., Akbulut, V., Özden, M.Y., and Toppare, L., Biomaterials, 1997, vol. 18, p. 1163.

    Article  CAS  Google Scholar 

  13. Gerard, M., Chaubey, A., and Malhotra, B.D., Biosens. Bioelectron., 2002, vol. 17, p. 345.

    Article  CAS  Google Scholar 

  14. Telefoncu, A., Biyosensörler, İzmir: Kuşadasi, 1999.

  15. Chaubey, A. and Malhotra, B.D., Biosens. Bioelectron., 2002, vol. 17, p. 441.

    Article  CAS  Google Scholar 

  16. Garcia, C.A.B., Neto, G.O., and Kubota, L.T., Anal. Chim. Acta, 1998, vol. 374, p. 201.

    Article  CAS  Google Scholar 

  17. Zhao, H., Yuan, Y., Adelojue, S., and Wallace, G.G., Anal. Chim. Acta, 2002, vol. 472, p. 113.

    Article  CAS  Google Scholar 

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Correspondence to F. Arslan.

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Published in Russian in Elektrokhimiya, 2006, Vol. 42, No. 2, pp. 160–164.

The text was submitted by the authors in English.

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Arslan, F., Yaşar, A. & Kiliç, E. Preparation of Pt/polypyrrole-ferrocene hydrogen peroxide sensitive electrode for the use as a biosensor. Russ J Electrochem 42, 137–140 (2006). https://doi.org/10.1134/S1023193506020042

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  • DOI: https://doi.org/10.1134/S1023193506020042

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