Abstract
The literature data on the effect of nanometer-scale spatial restrictions on the phase transitions and crystallizability of polymers are analyzed. It is shown that, as the volume of the polymer phase is decreased and its linear sizes take values on the order of 50 nm or less, the fundamental properties of the polymers change abruptly. The glass-transition temperature may decrease by tens of degrees, the temperature and heat of crystallization and the temperature and heat of melting may decline sharply, and the degree of crystallinity of polymers may become lower. Shredding of the polymer into nanometer sizes strongly affects the type of nucleation during its crystallization. As the length of the polymer phase is decreased, the transition from heterogeneous nucleation, which is usually observed during crystallization of bulky polymers, to homogeneous nucleation occurs through the stage of fractional crystallization. The crystallization of polymers under confined conditions is accompanied by the orientation of crystallites in the nanometer asymmetric space and is controlled by the size and morphology of restriction, the character of its interaction with the solid surface, and the ratio of the rates of nucleation and growth of crystals. The analyzed data are of great importance in the manufacture of such miniature objects as nanorods and nanowires necessary for the development and creation of modern devices used to solve important applied problems in microelectronics and biomedicine. The mentioned spatial effects should be taken into account during the creation of nanostructured films for solar cells and polymer membranes of energy separators, for the targeted delivery of drugs, and in many other fields.
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References
R. A. Andrievskii, Ross. Khim. Zh. 46 (5): 50 (2002).
I. V. Melikhov, Ross. Khim. Zh. 46 (5): 7 (2002).
C. P. Poole and F. J. Owens, Introduction to Nanotechnology (Wiley, Hoboken; New York, 2003).
I. P. Suzdalev, Nanotechnology. Physics and Chemistry of Nanoclusters, Nanostructures, and Nanomaterials (KomKniga, Moscow, 2006) [in Russian].
N. G. Rambidi and A. V. Berezkin, Physical and Chemical Foundations of Nanotechnology (Fizmatlit, Moscow, 2009) [in Russian].
A. G. Kolmakov, S. M. Barinov, and M. I. Alymov, Foundations of Technology and Application of Nanomaterials (Fizmatlit, Moscow, 2013) [in Russian].
C. L. Jackson and G. B. McKenna, J. Chem. Phys. 93 (12): 9002 (1990).
A. I. Kitaigorodskii, Molecular Crystals (Nauka, Moscow, 1971) [in Russian].
M. Alcoutlabi and G. B. McKenna, J. Phys.: Condens. Matter 17 (15), R461 (2005).
Polymer Nanocomposites, Ed. by Y.-W. Mai and Z.-Z. Yu (Woodhead Publ., Cambridge, 2006).
A. D. Pomogailo, A. S. Rozenberg, and I. E. Uflyand, Metal Nanoparticles in Polymers (Khimiya, Moscow, 2000) [in Russian].
A. L. Volynskii and N. F. Bakeev, Polym. Sci., Ser. C 53 (1): 35 (2011).
A. L. Volynskii, A. Y. Yarysheva, E. G. Rukhlya, L. M. Yarysheva, N. F. Bakeev, Russ. Chem. Rev. 83 (11): 1003 (2014).
S. S. Ivanchev and A. N. Ozerin, Polym. Sci., Ser. B 48 (7–8), 213 (2006).
L. M. Bronstein, S. N. Sidorov, and P. M. Valetsky, Russ. Chem. Rev. 73 (5): 541 (2004).
C. R. Martin, Acc. Chem. Res. 28, 61 (1995).
J. Jang, Adv. Polym. Sci. 199, 189 (2006).
A. Arinstein and E. Zussman, J. Polym. Sci., Polym. Phys. Ed. 49, 691 (2011).
D. Liang, B. S. Hsiao, and B. Chu, Adv. Drug Delivery Rev. 59, 1392 (2007).
C. P. Barnes, S. A. Sell, E. D. Boland, D. G. Simpson, G. L. Bowlin, Adv. Drug Delivery Rev. 59, 1413 (2007).
J. Martin, J. Maiz, J. Sacristan, and C. Mijangos, Polymer 53, 1149 (2012).
G. B. McKenna, Eur. Phys. J.: Spec. Top. 189, 285 (2010).
V. G. Rostiashvili, V. I. Irzhak, and B. A. Rozenberg, Glass Transitions in Polymers (Khimiya, Leningrad, 1987).
J. A. Forrest, K. Dalnoki-Veress, J. R. Stevens, and J. R. Dutcher, Phys. Rev. Lett. 77, 2002 (1996).
J. A. Forrest and K. Dalnoki-Veress, Adv. Colloid Interface Sci. 94 (1–3), 167 (2001).
J. A. Forrest, K. Dalnoki-Veress, and J. R. Dutcher, Phys. Rev. E: Stat., Nonlinear, Soft Matter Phys. 56, 5705 (1997).
M. D. Ediger and J. A. Forrest, Macromolecules 47 (2): 471 (2014).
C. M. Stafford, S. Guo, C. Harrison, and M. Y. M. Chiang, Rev. Sci. Instrum. 76 (6): 062207 (2005).
C. M. Stafford, C. Harrison, K. L. Beers, A. Karim, E. J. Amis, M. R. Vanlandingham, H.-C. Kim, W. Volksen, R. D. Miller, E. E. Simonyi, Nat. Mater. 3 (8): 545 (2004).
C. M. Stafford, B. D. Vogt, C. Harrison, D. Julthongpiput, R. Huang, Macromolecules 39 (15): 5095 (2006).
R. Huang, C. M. Stafford, and B. D. Vogt, J. Aerosp. Eng. 20 (1): 38 (2007).
N. Bowden, S. Brittain, A. G. Evans, J. W. Hutchinson, G. M. Whitesides, Nature 393, 146 (1998).
A. L. Volynskii, S. Bazhenov, O. V. Lebedeva, and N. F. Bakeev, J. Mater. Sci. 35, 547 (2000).
J. L. Keddie, R. A. L. Jones, and R. A. Cory, Europhys. Lett. 27, 59 (1994).
A. D. Schwab, D. M. G. Agra, J.-H. Kim, S. Kumar, A. Dhinojwala, Macromolecules 33, 4903 (2000).
J. A. Forrest, C. Svanberg, K. Revesz, M. Rodahl, L. M. Torell, B. Kasemo, Phys. Rev. E: Stat., Nonlinear, Soft Matter Phys. 58, 1226 (1998).
P. Scheidler, W. Kob, and K. Binder, Europhys. Lett. 59, 701 (2002).
P. Scheidler, W. Kob, and K. Binder, J. Phys. Chem. B 108, 6673.
G. D. Smith, D. Bedrov, and O. Borodin, Phys. Rev. Lett. 90, 226103 (2003).
C. E. Porter and F. D. Blum, Macromolecules 33, 7016 (2000).
R. M. Overney, C. Buenviaje, R. Luginbuhl, and F. Dinelli, J. Therm. Anal. Calorim 59, 205 (2000).
C. Bollinne, V. W. Stone, V. Carlier, and A. M. Jonas, Macromolecules 32, 4719 (1999).
B. Frank, A. P. Gast, T. R. Russel, H. R. Brown, C. Hawker, Macromolecules 29, 6531 (1996).
X. Zheng, B. B. Sauer, J. G. V. Alsten, S. A. Schwartz, M. H. Rafailovich, J. Sokolov, M. Rubinstein, Phys. Rev. Lett. 74, 407 (1995).
D. J. Pochan, E. K. Lin, S. K. Satija, and W.-L. Wu, Macromolecules 34, 3041 (2001).
J. Wang, M. Tolan, O. H. Seeck, S. K. Sinha, O. Bahr, M. H. Rafailovich, J. Sokolov, Phys. Rev. Lett. 83, 564 (1999).
A. Van der Lee, L. Hamon, Y. Holl, and Y. Grohens, Langmuir 17 (24): 7664 (2001).
L. Hartmann, W. Gorbatschow, J. Hauwede, and F. Kremer, Eur. Phys. J. E: Soft Matter Biol. Phys. 8, 145 (2002).
Y. Mi, G. Xue, and X. Lu, Macromolecules 36 (20): 7560 (2003).
Y. Mi, G. Xue, and X. Wang, Polymer 43 (25): 6701 (2002).
X. Lu, G. Xue, and Y. Mi, J. Appl. Polym. Sci. 119 (4): 2310 (2011).
L. Li, B. Li, J. Chen, D. Zhou, G. Xue, X. Liu, Polymer 45 (8): 2813 (2004).
S. C. Pilcher and W. T. Ford, Macromolecules 31 (11): 3454 (1998).
Y. Wang, C.-M. Chan, K.-M. Ng, and L. Li, Macromolecules 41 (7): 2548 (2008).
H. Yin, S. Napolitano, and A. Schönhals, Macromolecules 45 (3): 1652 (2012).
G. B. DeMaggio, W. E. Frieze, D. W. Gidley, M. Zhu, H. A. Hristov, A. F. Yee, Phys. Rev. Lett. 78 (8): 1524 (1997).
J. L. Keddie, R. A. L. Jones, and R. A. Cory, Faraday Discuss. 98, 219 (1994).
J. H. van Zanten, W. E. Wallace, and W.-L. Wu, Phys. Rev. E: Stat., Nonlinear, Soft Matter Phys. 53 (3), R2053 (1996).
Y. Grohens, M. Brogly, C. Labbe, M.-O. David, J. Schultz, Langmuir 14 (11): 2929 (1998).
H. L. Frisch and J. E. Mark, Chem. Mater. 8 (8): 1735 (1996).
H. L. Frisch, S. Maaref, Y. Xue, G. Beaucage, Z. Pu, J. E. Mark, J. Polym. Sci., Part A: Polym. Chem. 34 (4): 673 (1996).
H. Rudolph, J. Mahrholz, and K. Buchholz, Langmuir 12 (13): 3101 (1996).
C. Zhang, Y. Guo, and R. D. Priestle, J. Polym. Sci., Polym. Phys. Ed. 51, 574 (2013).
A. Sharples, Introduction to Polymer Crystallization (Edwaed Arnold LTD, London, 1966).
Yu. K. Godovskii, Crystallization of Polymers in Encyclopedia of Polymers (Sovetskaya entsiklopediya, Moscow, 1972), Vol. 1 [in Russian].
L. Mandelkern, Crystallization of Polymers (McGrawHill, New York, 1964).
P. H. Geil Polymer Single Crystlas (Interscience Publ., New York, 1964).
G. M. Bartenev and S. Ya. Frenkel’, Physics of Polymers (Khimiya, Leningrad, 1990) [in Russian].
Y.-X. Liu and E.-Q. Chen, Coord. Chem. Rev. 254 (9–10), 1011 (2010).
H. Wu, W. Wang, Y. Huang, and Z. Su, Macromol. Rapid Commun. 30, 194 (2009).
D. N. Theodorou, Macromolecules 22 (12): 4578 (1989).
K. F. Mansfield and D. N. Theodorou, Macromolecules 23 (20): 4430 (1990).
K. F. Mansfield and D. N. Theodorou, Macromolecules 24 (15): 4295 (1991).
V. A. Harmandaris, K. C. Daoulas, and V. G. Mavrantzas, Macromolecules 38 (13): 5796 (2005).
Y. Jiang, D.-D. Yan, X. Gao, C. C. Han, X.-G. Jin, L. Li, Y. Wang, C.-M. Chan, Macromolecules 36 (10): 3652 (2003).
Y.-G. Lei, C.-M. Chan, Y. Wang, K.-M. Ng, Y. Jiang, L. Lin, Polymer 44 (16): 4673 (2003).
Y.-G. Lei, C.-M. Chan, J.-X. Li, K.-M. Ng, Y. Wang, Y. Jiang, L. Li, Macromolecules 35 (18): 6751 (2002).
L. Li, C.-M. Chan, K. L. Yeung, J.-X. Li, K.-M. Ng, Y. Lei, Macromolecules 34 (2): 316 (2001).
L. Li, C.-M. Chan, J.-X. Li, K.-M. Ng, K.-L. Yeung, L.-T. Weng, Macromolecules 32 (24): 8240 (1999).
Y. Wang, C.-M. Chan, K.-M. Ng, Y. Jiang, L. Li, Langmuir 20 (19): 8220 (2004).
D. C. Bassett, Philos. Trans. R. Soc. London 348, 29 (1994).
H. D. Keith and F. J. Padden, J. Appl. Phys. 34 (8): 2409 (1963).
H. Schönherr and C. W. Frank, Macromolecules 36 (4): 1188 (2003).
Y. Ma, Y. Hu, and G. Reiter, Macromolecules 39 (15): 5159 (2006).
C. J. Ellison and J. M. Torkelson, Nat. Mater. 2, 695 (2003).
H. Li and S. Yan, Macromolecules 44 (3): 417 (2011).
J. L. Thomason and A. A. Van Rooyen, J. Mater. Sci. 27 (4): 889 (1992).
H. Ishida and P. Bussi, Macromolecules 24 (12): 3569 (1991).
K. Cho, D. Kim, and S. Yoon, Macromolecules 36 (20): 7652 (2003).
J. L. Thomason and A. A. van Rooyen, The Transcrystallised Interphase in Thermoplastic Composites in Controlled Interphases in Composite Materials, Ed. by H. Ishida (Springer Netherlands, Dordrecht, 1990).
B. Hsiao and E. H. Chen, Transcrystalline Interphase in Advanced Polymer Composites in Controlled Interphases in Composite Materials, Ed. by H. Ishida (Springer Netherlands, Dordrecht, 1990).
J. J. Varga, J. Mater. Sci. 27, 2557 (1992).
J. Varga and J. Karger-Kocsis, J. Polym. Sci., Polym. Phys. Ed. 34 (4): 657 (1996).
J. Varga, Y. Fujiwara, and A. Ille, Period. Polytech., Chem. Eng 34, 255 (1990).
J. Varga, Crystallization, Melting and Supermolecular Structure of Isotactic Polypropylene in Poly(Propylene): Structure, Blends and Composites, Ed. by J. KargerKocsis (Chapman & Hall, London, 1995), Vol. 1.
J. Varga, J. Therm. Anal. 31, 165 (1986).
X. Sun, H. Li, J. Wang, and S. Yan, Macromolecules 39 (25): 8720 (2006).
S. Y. Hobbs, Nat. Phys. Sci. 234, 12 (1971).
H. Li, X. Zhang, X. Kuang, J. Wang, D. Wang, L. Li, S. Yan, Macromolecules 37 (8): 2847 (2004).
H. Li, X. Sun, S. Yan, and J. M. Schultz, Macromolecules 41 (13): 5062 (2008).
H. Li, S. Jiang, J. Wang, D. Wang, S. Yan, Macromolecules 36 (8): 2802 (2003).
X. Sun, H. Li, X. Zhang, J. Wang, D. Wang, S. Yan, Macromolecules 39 (3): 1087 (2006).
X. Sun, H. Li, X. Zhang, D. Wang, J. M. Schultz, S. Yan, Macromolecules 43 (1): 561 (2010).
R. Andrews, D. Jacques, A. M. Rao, T. Rantell, F. Derbyshire, Y. Chen, J. Chen, R. C. Haddon, Appl. Phys. Lett. 75 (9): 1329 (1999).
B. Li and C. Y. Li, J. Am. Chem. Soc. 129 (1): 12 (2007).
O. Lourie, D. M. Cox, and H. D. Wagner, Phys. Rev. Lett. 81 (8): 1638 (1998).
O. Regev, P. N. B. ElKati, J. Loos, and C. E. Koning, Adv. Mater. 16 (3): 248 (2004).
A. Koganemaru, Y. Bin, Y. Agari, and M. Matsuo, Adv. Funct. Mater. 14 (9): 842 (2004).
E. T. Thostenson, Z. Ren, and T.-W. Chou, Compos. Sci. Technol. 61 (13): 1899 (2001).
H. E. Miltner, N. Grossiord, K. Lu, J. Loos, C. E. Koning, B. Van Mele, Macromolecules 41 (15): 5753 (2008).
B. P. Grady, F. Pompeo, R. L. Shambaugh, and D. E. Resasco, J. Phys. Chem. B 106 (23): 5852 (2002).
L. Li, B. Li, M. A. Hood, and C. Y. Li, Polymer 50 (4): 953 (2009).
C. Y. Li, L. Li, W. Cai, S. L. Kodjie, K. K. Tenneti, Adv. Mater. 17 (9): 1198 (2005).
L. Li, C. Y. Li, and C. Ni, J. Am. Chem. Soc. 128 (5): 1692 (2006).
L. Li, C. Y. Li, C. Ni, L. Rong, B. Hsiao, Polymer 48 (12): 3452 (2007).
J. Yue, Q. Xu, Z. Zhang, and Z. Chen, Macromolecules 40 (25): 8821 (2007).
Z. Zhang, Q. Xu, Z. Chen, and J. Yue, Macromolecules 41 (8): 2868 (2008).
F. Zhang, H. Zhang, Z. Zhang, Z. Chen, Q. Xu, Macromolecules 41 (12): 4519 (2008).
X. Zheng and Q. Xu, J. Phys. Chem. B 114 (29): 9435 (2010).
L. He, X. Zheng, and Q. Xu, J. Phys. Chem. B 114 (16): 5257 (2010).
R. H. Somani, L. Yang, L. Zhu, and B. S. Hsiao, Polymer 46 (20): 8587 (2005).
L. Yang, R. H. Somani, I. Sics, B. S. Hsiao, R. Kolb, H. Fruitwala, C. Ong, Macromolecules 37 (13): 4845 (2004).
B. S. Hsiao, L. Yang, R. H. Somani, C. A. Avila-Orta, L. Zhu, Phys. Rev. Lett. 94 (11): 117802 (2005).
W. Hu, D. Frenkel, and V. B. F. Mathot, Macromolecules 35 (19): 7172 (2002).
R. Y. F. Liu, T. E. Bernal-Lara, A. Hiltner, and E. Baer, Macromolecules 37 (18): 6972 (2004).
J. M. Carr, D. S. Langhe, M. T. Ponting, A. Hiltner, E. Baer, J. Mater. Res. 27 (10): 1326 (2012).
R. Y. F. Liu, Y. Jin, A. Hiltner, and E. Baer, Macromol. Rapid Commun. 24, 943 (2003).
H. Wang, J. K. Keum, A. Hiltner, E. Baer, B. Freeman, A. Rozanski, A. Galeski, Science 323, 757 (2009).
M. Ponting, Y. Lin, J. K. Keum, A. Hiltner, E. Baer, Macromolecules 43 (20): 8619 (2010).
H. Wang, J. K. Keum, A. Hiltner, and E. Baer, Macromolecules 43, 3359 (2010).
G. Zhang, P. C. Lee, S. Jenkins, J. Dooley, E. Baer, Polymer 55 (2): 663 (2014).
S. S. Ray and M. Okamoto, Prog. Polym. Sci. 28, 1539 (2003).
D. R. Paul and L. M. Robeson, Polymer 49 (15): 3187 (2008).
P. B. Messersmith and E. P. Giannelis, Chem. Mater. 6 (10): 1719 (1994).
P. B. Messersmith and E. P. Giannelis, J. Polym. Sci., Part A: Polym. Chem. 33 (7): 1047 (1995).
A. Usuki, Y. Kojima, M. Kawasumi, A. Okada, Y. Fukushima, T. Kurauchi, O. Kamigaito, J. Mater. Res. 8 (05): 1179 (1993).
K. Yano, A. Usuki, A. Okada, T. Kurauchi, O. Kamigaito, J. Polym. Sci., Part A: Polym. Chem. 31 (10): 2493 (1993).
S. D. Burnside and E. P. Giannelis, Chem. Mater. 7 (9): 1597 (1995).
R. A. Vaia, S. Vasudevan, W. Krawiec, L. G. Scanlon, E. P. Giannelis, Adv. Mater. 7 (2): 154 (1995).
P. Aranda and E. Ruiz-Hitzky, Chem. Mater. 4 (6): 1395 (1992).
J. Wu and M. M. Lerner, Chem. Mater. 5 (6): 835 (1993).
E. P. Giannelis, Adv. Mater. 8 (1): 29 (1996).
E. P. Giannelis, R. Krishnamoorti, and E. Manias, Adv. Polym. Sci. 138, 107 (1999).
R. A. Vaia, H. Ishii, and E. P. Giannelis, Chem. Mater. 5 (12): 1694 (1993).
R. A. Vaia, PhD Thesis (Cornell Univ., Ithaca, 1995).
R. A. Vaia, K. D. Jandt, E. J. Kramer, and E. P. Giannelis, Macromolecules 28 (24): 8080 (1995).
S. H. Anastasiadis, K. Karatasos, G. Vlachos, E. Manias, E. Giannelis, Phys. Rev. Lett. 84 (5): 915 (2000).
R. A. Vaia, B. B. Sauer, O. K. Tse, and E. P. Giannelis, J. Polym. Sci., Polym. Phys. Ed. 35 (1): 59 (1997).
C. L. Jackson and G. B. McKenna, J. Non-Cryst. Solids 131–133 (1): 221 (1991).
C. L. Jackson and G. B. McKenna, Chem. Mater. 8 (8): 2128 (1996).
J. Zhang, G. Liu, and J. Jonas, J. Phys. Chem. 96 (8): 3478 (1992).
F. Kremer, A. Huwe, M. Arndt, P. Behrens, W. Schwieger, J. Phys.: Condens. Matter 11 (A175) (1999).
M. Arndt, R. Stannarius, H. Groothues, E. Hempel, F. Kremer, Phys. Rev. Lett. 79 (11): 2077 (1997).
K. Chrissopoulou, K. S. Andrikopoulos, S. Fotiadou, S. Bollas, C. Karageorgaki, D. Christofilos, G. A. Voyiatzis, S. H. Anastasiadis, Macromolecules 44, 9710 (2011).
P. Apel, Radiat. Meas. 34 (1–6), 559 (2001).
G. P. Crawford, L. M. Steele, R. Ondris-Crawford, G. S. Iannacchione, C. J. Yeager, J. W. Doane, D. Finotello, J. Chem. Phys. 96 (10): 7788 (1992).
M. Steinhart, Adv. Polym. Sci. 220, 123 (2008).
R. M. Michell, A. T. Lorenzo, A. J. Müller, M.-C. Lin, H.-L. Chen, I. Blaszczyk-Lezak, J. Martin, C. Mijangos, Macromolecules 45 (3): 1517 (2012).
R. M. Michell, I. Blaszczyk-Lezak, C. Mijangos, and A. J. Müller, Polymer 54 (16): 4059 (2013).
H. Masuda and K. Fukuda, Science 268, 1466 (1995).
C. R. Martin, Science 266, 1961 (1994).
C. R. Martin, Chem. Mater. 8, 1739 (1996).
J. C. Hulteen and C. R. Martin, J. Mater. Chem. 7, 1075 (1997).
M. Steinhart, R. B. Wehrspohn, U. Gosele, and J. H. Wendorff, Angew. Chem., Int. Ed. 43, 1334 (2004).
M. Steinhart, J. H. Wendorff, A. Greiner, R. B. Wehrspohn, K. Nielsch, J. Schilling, J. Choi, U. Gösele, Science 296, 1997 (2002).
V. M. Cepak and C. R. Martin, Chem. Mater. 11, 1363 (1999).
H. Wu, W. Wang, H. Yang, and Z. Su, Macromolecules 40 (12): 4244 (2007).
K. Shin, E. Woo, Y. G. Jeong, C. Kim, J. Huh, K.-W. Kim, Macromolecules 40 (18): 6617 (2007).
J. Maiz, J. Martin, and C. Mijangos, Langmuir 28 (33): 12296 (2012).
M. Steinhart, S. Senz, R. B. Wehrspohn, U. Gösele, J. H. Wendorff, Macromolecules 36 (10): 3646 (2003).
E. Woo, J. Huh, Y. G. Jeong, and K. Shin, Phys. Rev. Lett. 98 (13): 136103 (2007).
J. L. Carvalho and K. Dalnoki-Veress, Eur. Phys. J. 34 (6): 1 (2011).
K. Lee, G. Yu, E. Woo, S. Hwang, K. Shin, Freezing and Melting in Nanopores in Adsorption and Phase Behaviour in Nanochannels and Nanotubes, Ed. by L. J. Dunne and G. Manos (Springer, London; New York, 2009).
M. Steinhart, P. Goring, H. Dernaika, M. Prabhukaran, U. Gösele, E. Hempel, T. Thurn-Albrecht, Phys. Rev. Lett. 97, 027801 (2006).
H. Wu, Z. Su, and A. Takahara, Soft Matter 8 (11): 3180 (2012).
Z. Hu, G. Baralia, V. Bayot, J.-F. Gohy, A. M. Jonas, Nano Lett. 5 (9): 1738 (2005).
J. Martin, C. Mijangos, A. Sanz, T. A. Ezquerra, A. Nogales, Macromolecules 42 (14): 5395 (2009).
R. P. Kambour, J. Polym. Sci., Part D: Macromol. Rev. 7, 1 (1973).
E. Passaglia, J. Phys. Chem. Solids 48, 1075 (1987).
A. L. Volynskii and N. F. Bakeev, Solvent Crazing of Polymers (Elsevier, Amsterdam; New York, 1996).
A. L. Volynskii and N. F. Bakeev, Structural Self-organization of Amorphous Polymers (Fizmatlit, Moscow, 2005) [in Russian].
A. L. Volynskii, T. E. Grokhovskaya, N. A. Shitov, and N. F. Bakeev, Vysokomol. Soedin., Ser. B 22 (7): 483 (1980).
A. L. Volynskii, N. A. Shitov, A. S. Chegolya, and N. F. Bakeev, Vysokomol. Soedin., Ser. B 25 (6): 393 (1983).
E. G. Rukhlya, E. A. Litmanovich, A. I. Dolinnyi, L. M. Yarysheva, A. L. Volynskii, N. F. Bakeev, Macromolecules 44, 5262 (2011).
A. L. Volynskii, E. G. Rukhlya, L. M. Yarysheva, and N. F. Bakeev, Dokl. Phys. Chem. 447 (1): 200 (2012).
A. Y. Yarysheva, D. B. Bagrov, E. G. Rukhlya, L. M. Yarysheva, A. L. Volynskii, N. F. Bakeev, Polym. Sci., Ser. A 54 (10): 779 (2012).
L. M. Yarysheva, B. N. Tarasevich, A. V. Bakirov, A. Y. Yarysheva, E. G. Rukhlya, N. S. Chvalun, A. L. Volynskii, N. F. Bakeev, Dokl. Phys. Chem. 459 (1): 177 (2014).
H. Wang, J. K. Keum, A. Hiltner, and E. Baer, Macromol. Rapid Commun. 31 (4): 356 (2010).
L. Zhu, S. Z. D. Cheng, B. H. Calhoun, Q. Ge, R.P. Quirk, E. L. Thomas, B. S. Hsiao, F. Yeh, B. Lotz, J. Am. Chem. Soc. 122 (25): 5957 (2000).
A. Taden and K. Landfester, Macromolecules 36, 4037 (2003).
D. Zhou, L. Li, Y. Li, J. Zhang, G. Xue, Macromolecules 36 (12): 4609 (2003).
G. Xue, Y. Wang, X. Gu, and Y. Lu, Macromolecules 27 (14): 4016 (1994).
G. Xue, Y. Wang, S. Liu, and Y. -T. Liao, Macromolecules 28 (12): 4344 (1995).
H. Bu, F. Gu, L. Bao, and M. Chen, Macromolecules 31 (20): 7108 (1998).
Y. Li and G. Xue, Polymer 40 (11): 3165 (1999).
Y. Li and G. Xue, Macromolecules 32 (12): 3984 (1999).
Z. Xiao, Q. Sun, G. Xue, Z. Yuan, Q. Dai, Y. Hu, Eur. Polym. J. 39 (5): 927 (2003).
Q. Sun, Q. Fu, G. Xue, and W. Chen, Macromol. Rapid Commun. 22 (14): 1182 (2001).
L. Chen, Y. Wang, X. Zhu, and D. Yan, Polym. Int. 53 (2): 131 (2004).
G. Ji, G. Xue, J. Ma, C. Dong, X. Gu, Polymer 37 (15): 3255 (1996).
G. Ji, F. Li, W. Zhu, Q. Dai, G. Xue, X. Gu, J. Macromol. Sci., Pure Appl. Chem. 34 (2): 369 (1997).
G. Xue, Y. Wang, S. Liu, and Y.-T. Liao, Macromolecules 28 (9): 3476 (1995).
G. Ji, H. Ni, C. Wang, G. Xue, Y.-T. Liao, Macromolecules 29 (7): 2691 (1996).
T. Sasaki, N. Yamauchi, S. Irie, and K. Sakurai, J. Polym. Sci., Polym. Phys. Ed. 43 (2): 115 (2005).
J. Chen, G. Zheng, L. Xu, Y. Lu, G. Xue, Y. Yang, J. Zhang, Polymer 42 (9): 4459 (2001).
M. V. Massa and K. Dalnoki-Veress, Phys. Rev. Lett. 92 (25): 255509 (2004).
M. V. Massa, M. S. M. Lee, and K. Dalnoki-Veress, J. Polym. Sci., Polym. Phys. Ed. 43 (23): 3438 (2005).
M. V. Massa, J. L. Carvalho, and K. Dalnoki-Veress, Phys. Rev. Lett. 97 (24): 247802 (2006).
J. L. Carvalho, M. V. Massa, and K. Dalnoki-Veress, J. Polym. Sci., Polym. Phys. Ed. 44 (24): 3448 (2006).
J. L. Carvalho and K. Dalnoki-Veress, Phys. Rev. Lett. 105 (23): 237801 (2010).
M. V. Massa, J. L. Carvalho, and K. Dalnoki-Veress, Eur. Phys. J. 12 (1): 111 (2003).
D. H. Reneker and I. Chun, Nanotecnology 7 (3): 216 (1996).
J. M. Deitzel, J. Kleinmeyer, D. Harris, and N. C. Beck Tan, Polymer 42 (1): 261 (2001).
J. H. Yu, S. V. Fridrikh, and G. C. Rutledge, Adv. Mater. 16 (17): 1562 (2004).
D. Li and Y. Xia, Adv. Mater. 16 (14): 1151 (2004).
D. H. Reneker and A. L. Yarin, Polymer 49 (10): 2387 (2008).
A. L. Yarin, Polym. Adv. Technol. 22 (3): 310 (2011).
Z.-M. Huang, Y. Z. Zhang, M. Kotaki, and S. Ramakrishna, Compos. Sci. Technol. 63 (15): 2223 (2003).
A. Greiner and J. H. Wendorff, Angew. Chem., Int. Ed. Engl. 46 (30): 5670 (2007).
J. J. Feng, Phys. Fluids 14 (11): 3912 (2002).
J.-H. He and H.-M. Liu, Nonlinear Anal. 63 (2005).
E. Zhmayev, D. Cho, and Y. L. Joo, Polymer 51 (1): 274 (2010).
Y. Jin, A. Hiltner, and E. Baer, J. Polym. Sci., Polym. Phys. Ed. 45 (10): 1138 (2007).
R. Chen and D. Huang, Front. Chem. Eng. China 6 (4): 332 (2011).
K. Landfester, Adv. Mater. 13, 765 (2001).
M. Antonietti and K. Landfester, Prog. Polym. Sci. 27, 689 (2002).
F. Price, Nucleation in Polymer Crystallization in Nucleation, Ed. by A. C. Zettlemoyer (Marcel Dekker, New York, 1969).
B. Vonnegut, J. Colloid Sci. 3, 563 (1948).
D. Turnbull and R. E. Cech, J. Appl. Phys. 21 (8): 804 (1950).
G. Pound and V. La Mer, J. Am. Chem. Soc. 74 (9): 2323 (1952).
D. Turnbull, J. Chem. Phys. 20 (3): 411 (1952).
D. Turnbull and R. Cormia, J. Chem. Phys. 34 (3): 820 (1961).
R. L. Cormia, F. P. Price, and D. Turnbull, J. Chem. Phys. 37, 1333 (1962).
J. R. Burns and D. Turnbull, J. Appl. Phys. 37, 4021 (1966).
J. Koutsky, A. Walton, and E. Baer, J. Appl. Phys. 38 (4): 1832 (1967).
F. Gornick, G. S. Ross, and L. J. Frolen, J. Polym. Sci., Part C: Polym. Symp. 18 (1): 79 (1967).
R. Montenegro, M. Antonietti, Y. Mastai, and K. Landfester, J. Chem. Phys. (in press).
Polymer Blends, Ed. by C. B. Bucknall and D. R. Paul (Wiley, Weinheim, 2000).
M. L. Arnal, M. E. Matos, R. A. Morales, O. O. Santana, A. J. Müller, Macromol. Chem. Phys. 199 (10): 2275 (1998).
H. Frensch, P. Harnischfeger, and B. J. Jungnickel, Fractionated Crystallization in Incompatible Polymer Blends in Multiphase Polymers: Blends and Ionomers, Ed. by L. A. Utracki and R. A. Weiss (Am. Chem. Soc., Canada, 1989), Vol. 395.
G. Zhong, K. Wang, L. Zhang, Z.-M. Li, H. Fong, L. Zhu, Polymer 52 (24): 5397 (2011).
H. Luo, Y. Huang, D. Wang, and J. Shi, J. Polym. Sci., Polym. Phys. Ed. 51 (5): 376 (2013).
Y. He, B. Zhu, W. Kai, and Y. Inoue, Macromolecules 37 (9): 3337 (2004).
D. S. Langhe, J. K. Keum, A. Hiltner, and E. Baer, J. Polym. Sci., Polym. Phys. Ed. 49 (2): 159 (2011).
R. V. Castillo, M. L. Arnal, A. J. Müller, I. W. Hamley, V. Castelletto, H. Schmalz, V. Abetz, Macromolecules 41 (3): 879 (2008).
H.-L. Chen, J.-C. Wu, T.-L. Lin, and J. S. Lin, Macromolecules 34 (20): 6936 (2001).
A. Röttele, T. Thurn-Albrecht, J.-U. Sommer, and G. Reiter, Macromolecules 36 (4): 1257 (2003).
Y.-Y. Huang, H.-L. Chen, H.-C. Li, T.-L. Lin, J. S. Lin, Macromolecules 36 (2): 282 (2002).
Y.-Y. Huang, C. H. Yang, H.-L. Chen, F.-C. Chiu, T.-L. Lin, W. Liou, Macromolecules 37 (2): 486–493 (2004).
A. J. Müller, V. Balsamo, and M. L. Arnal, Adv. Polym. Sci. 190, 1 (2005).
A. J. Müller, V. Balsamo, M. L. Arnal, T. Jakob, H. Schmalz, V. Abetz, Macromolecules 35 (8): 3048 (2002).
D. J. Quiram, R. A. Register, G. R. Marchand, and D. H. Adamson, Macromolecules 31 (15): 4891 (1998).
R. M. Michell, A. J. Müller, G. Deshayes, and P. Dubois, Eur. Polym. J. 46 (6): 1334 (2010).
Z. Li, R. Liu, B. Mai, W. Wang, Q. Wu, G. Liang, H. Gao, F. Zhu, Polymer 54 (6): 1663 (2013).
L. Yin and M. A. Hillmyer, Macromolecules 44 (8): 3021 (2011).
Y. Suzuki, H. Duran, M. Steinhart, H.-J. Butt, G. Floudas, Macromolecules 47 (5): 1793 (2014).
G. Floudas, G. Reiter, O. Lambert, and P. Dumas, Macromolecules 31 (21): 7279 (1998).
G. Floudas, G. Reiter, O. Lambert, P. Dumas, F. J. Yeh, B. Chu, Block Crystallization in Model Triarm Star Block Copolymers with Two Crystallizable Blocks: A Time-Resolved SAXS-WAXD Study in Scattering from Polymers (Am. Chem. Soc, New York, 1999).
S. Jiang, C. He, Y. Men, X. Chen, L. An, S. S. Funari, C.-M. Chan, Eur. Phys. J. E 27, 357 (2008).
U. W. Gedde, Polymer Physics (Chapman & Hall, London; New York, 1995).
J. L. Tell and H. J. Maris, Phys. Rev. B: Solid State 28, 5122 (1983).
S. Sawamura, H. Miyaji, K. Izumi, S. J. Sutton, Y. Miyamoto, J. Phys. Soc. Jpn. 67 (10): 3338 (1998).
K. Dalnoki-Veress, J. A. Forrest, M. V. Massa, A. Pratt, A. Williams, J. Polym. Sci., Polym. Phys. Ed. 39 (21): 2615 (2001).
S. Ok and A. L. Demirel, J. Macromol. Sci., Part B: Phys. 42 (3–4), 611 (2003).
H. Schönherr and C. W. Frank, Macromolecules 36 (4): 1199 (2003).
Physics of Polymer Surfaces and Interfaces, Ed. by I. C. Sanchez (Butterworth-Heinemann, Boston, 1992).
C. W. Frank, V. Rao, M. M. Despotopoulou, R. F. W. Pease, W. D. Hinsberg, R. D. Miller, J. F. Rabolt, Science 273, 912 (1996).
M. M. Despotopoulou, C. W. Frank, R. D. Miller, and J. F. Rabolt, Macromolecules 28 (19): 6687 (1995).
M. M. Despotopoulou, C. W. Frank, R. D. Miller, and J. F. Rabolt, Macromolecules 29 (18): 5797 (1996).
J. H. Kim, J. Jang, and W. Zin, Macromol. Rapid Commun. 22, 386 (2001).
Y. Wang, S. Ge, M. Rafailovich, J. Sokolov, Y. Zou, H. Ade, J. Luening, A. Lustiger, G. Maron, Macromolecules 37, 3319 (2004).
H. Schonherr, L. E. Bailey, and C. W. Frank, Langmuir 18, 490 (2002).
G. Reiter, J. Polym. Sci., Polym. Phys. Ed. 41 (16): 1869 (2003).
J. S. Langer, Rev. Mod. Phys. 52, 1 (1980).
S. Napolitano and M. Wübbenhorst, Macromolecules 39 (18): 5967 (2006).
M. Imai, K. Kaji, T. Kanaya, and Y. Sakai, Phys. Rev. B 52 (17): 12696 (1995).
T. A. Ezquerra, E. López-Cabarcos, B. S. Hsiao, and F. J. Baltà-Calleja, Phys. Rev. E: Stat., Nonlinear, Soft Matter Phys. 54 (1): 989 (1996).
P. D. Olmsted, W. C. K. Poon, T. C. B. McLeish, N. J. Terrill, A. J. Ryan, Phys. Rev. Lett. 81 (2): 373 (1998).
Y.-L. Loo, R. A. Register, and A. J. Ryan, Phys. Rev. Lett. 84 (18): 4120 (2000).
L. P. Chang and H. Morawetz, Macromolecules 20 (2): 428 (1987).
P. -D. Hong and J.-H. Chen, Polymer 39 (23): 5809 (1998).
J. Ding, G. Xue, Q. Dai, and R. Cheng, Polymer 34 (15): 3325 (1993).
G. Xue, Y. Lu, G. Shi, and Q. Dai, Polymer 35 (4): 892 (1994).
P. Bernazzani, S. L. Simon, D. J. Plazek, and K. L. Ngai, Eur. Phys. J. E 8 (2): 201 (2002).
S. L. Simon, P. Bernazzani, and G. B. McKenna, Polymer 44 (26): 8025 (2003).
W. Zheng and S. L. Simon, Polymer 47 (10): 3520 (2006).
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Original Russian Text © A.L. Volynskii, A.Yu. Yarysheva, E.G. Rukhlya, L.M. Yarysheva, N.F. Bakeev, 2015, published in Vysokomolekulyarnye Soedineniya. Ser. A, 2015, Vol. 57, No. 5, pp. 398–436.
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Volynskii, A.L., Yarysheva, A.Y., Rukhlya, E.G. et al. Effect of spatial restrictions at the nanometer scale on structuring in glassy and crystalline polymers. Polym. Sci. Ser. A 57, 515–551 (2015). https://doi.org/10.1134/S0965545X15050168
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DOI: https://doi.org/10.1134/S0965545X15050168