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Products of direct hydroalkoxylation of norbornene with alcohols over H-beta zeolite catalyst

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Abstract

The reaction of direct hydroalkoxylation of norbornene in the presence of H-beta zeolite catalyst has been studied. It has been found that the selectivity for exo-alkoxynorbornanes of the reaction of norbornene with monohydric alcohols (saturated, unsaturated, or aromatic) reaches 98% at a conversion of 78–98% of the unsaturated compound. The reaction of norbornene with diols (ethylene glycol and 2-butene-1,4-diol) in the presence of H-beta zeolite affords mono- and diethers, whose yield and ratio can be controlled by varying reaction parameters.

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Authors and Affiliations

  1. Ufa State Technological University of Petroleum, Ufa, Bashkortostan, Russia

    G. Z. Raskil’dina, A. N. Kazakova & S. S. Zlotskii

  2. Institute of Petroleum Chemistry and Catalysis, Russian Academy of Sciences, Ufa, Bashkortostan, Russia

    A. M. Suleimanova, N. G. Grigor’eva & B. I. Kutepov

Authors
  1. G. Z. Raskil’dina
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  2. A. M. Suleimanova
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  3. A. N. Kazakova
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  4. N. G. Grigor’eva
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  5. B. I. Kutepov
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  6. S. S. Zlotskii
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Corresponding author

Correspondence to N. G. Grigor’eva.

Additional information

Original Russian Text © G.Z. Raskil’dina, A.M. Suleimanova, A.N. Kazakova, N.G. Grigor’eva, B.I. Kutepov, S.S. Zlotskii, 2015, published in Neftekhimiya, 2015, Vol. 55, No. 2, pp. 162–170.

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Raskil’dina, G.Z., Suleimanova, A.M., Kazakova, A.N. et al. Products of direct hydroalkoxylation of norbornene with alcohols over H-beta zeolite catalyst. Pet. Chem. 55, 154–162 (2015). https://doi.org/10.1134/S0965544115020164

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  • DOI: https://doi.org/10.1134/S0965544115020164

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