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Mixed Micellar Solutions of Hexadecylpiperidinium Surfactants and Tween 80: Aggregation Behavior and Solubilizing Properties

  • PHYSICAL CHEMISTRY OF SURFACE PHENOMENA
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Abstract

The aggregation behavior of mixed micellar solutions of cationic hexadecylpiperidinium surfactants and nonionic surfactant Tween 80 is studied. The critical micelle concentration is determined by varying the component ratios, and a negative deviation from the ideal mixing model can be observed (synergistic effect). The adsorption parameters and surface potential of mixed micelles are estimated. The solubilizing effect individual and mixed compositions have on such hydrophobic biologically active compounds as bioflavonoid quercetin and systemic fungicide carboxin is characterized quantitatively via spectrophotometry.

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Funding

This work was supported by the Russian Foundation for Basic Research; and by the Government of the Republic of Tatarstan, project no. 18-43-160015.

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Authors and Affiliations

  1. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, 420088, Kazan, Russia

    A. B. Mirgorodskaya, R. A. Kushnazarova, S. S. Lukashenko & L. Ya. Zakharova

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  1. A. B. Mirgorodskaya
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  2. R. A. Kushnazarova
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  3. S. S. Lukashenko
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  4. L. Ya. Zakharova
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Corresponding author

Correspondence to A. B. Mirgorodskaya.

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Translated by O. Kadkin

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Mirgorodskaya, A.B., Kushnazarova, R.A., Lukashenko, S.S. et al. Mixed Micellar Solutions of Hexadecylpiperidinium Surfactants and Tween 80: Aggregation Behavior and Solubilizing Properties. Russ. J. Phys. Chem. 94, 1902–1907 (2020). https://doi.org/10.1134/S0036024420090198

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  • DOI: https://doi.org/10.1134/S0036024420090198

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