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Thermodynamic Properties of a Hyperbranched Pyridine-Containing Polyphenylene in the Range of T → 0 to 650 K

  • CHEMICAL THERMODYNAMICS AND THERMOCHEMISTRY
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Abstract

The thermodynamic properties of amorphous hyperbranched pyridine-containing polyphenylene in the 6 to 650 K range of temperatures are studied for the first time via high-precision adiabatic vacuum calorimetry and differential scanning calorimetry. In the low-temperature range of 9 to 14 K, the polymer shows an anomalous change in heat capacity resembling the G transition in its shape. An exothermic effect is detected starting at T = 400 K, and is thought to be due to cross-linking in the studied sample. Standard thermodynamic functions of the polymer for the range of T → 0 to 400 K and the standard entropy of its formation at T = 298.15 K are calculated from the experimental data by means of classical thermodynamics.

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Funding

This work was supported by the Russian Foundation for Basic Research, project nos. 19-03-00248 and 17-03-00578; and by the RF Ministry of Science and Higher Education (project no. 4.5510.2017/8.9).

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Authors and Affiliations

  1. Lobachevsky State University of Nizhny Novgorod, 603950, Nizhny Novgorod, Russia

    N. N. Smirnova, A. V. Markin & S. S. Sologubov

  2. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia

    E. S. Serkova, N. V. Kuchkina & Z. B. Shifrina

Authors
  1. N. N. Smirnova
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  2. A. V. Markin
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  3. S. S. Sologubov
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  4. E. S. Serkova
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  5. N. V. Kuchkina
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  6. Z. B. Shifrina
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Correspondence to N. N. Smirnova.

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Translated by K. Utegenov

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Smirnova, N.N., Markin, A.V., Sologubov, S.S. et al. Thermodynamic Properties of a Hyperbranched Pyridine-Containing Polyphenylene in the Range of T → 0 to 650 K. Russ. J. Phys. Chem. 94, 261–269 (2020). https://doi.org/10.1134/S0036024420010318

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  • DOI: https://doi.org/10.1134/S0036024420010318

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