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Physics and Chemistry of Creating New Titanates with Perovskite Structure

  • To the 100Th Anniversary of the Karpov Institute of Physical Chemistry
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Abstract

The phase formation, structural features, and dielectric, ferroelectric, and piezoelectric properties of ceramics with compositions from the region of the morphotropic phase boundary in the (Na0.5Bi0.5)TiO3–BaTiO3–Bi(Mg0.5Ti0.5)O3 system modified by different low-melting additives (Bi2O3, V2O5, KCl, NaCl–LiF, LiF, CuO, and MnO2) are studied. First-order phase transitions are detected near 700–800 and 400 K that display relaxor behavior and are indicative of the presence of polar regions in a nonpolar matrix. Prospects for improving the piezoelectric properties of the modified ceramic samples are confirmed.

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Authors and Affiliations

  1. Karpov Institute of Physical Chemistry, Moscow, 105064, Russia

    E. D. Politova, G. M. Kaleva, N. V. Golubko, A. V. Mosunov, N. V. Sadovskaya & S. Yu. Stefanovich

  2. Department of Chemistry, Moscow State University, Moscow, 119991, Russia

    D. A. Bel’kova, D. A. Strebkov & S. Yu. Stefanovich

  3. National Research Technological University (MISiS), Moscow, 119049, Russia

    D. A. Kiselev & A. M. Kislyuk

Authors
  1. E. D. Politova
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  2. G. M. Kaleva
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  3. N. V. Golubko
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  4. A. V. Mosunov
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  5. N. V. Sadovskaya
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  6. D. A. Bel’kova
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  7. D. A. Strebkov
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  8. S. Yu. Stefanovich
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  9. D. A. Kiselev
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  10. A. M. Kislyuk
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Corresponding author

Correspondence to E. D. Politova.

Additional information

Original Russian Text © E.D. Politova, G.M. Kaleva, N.V. Golubko, A.V. Mosunov, N.V. Sadovskaya, D.A. Bel’kova, D.A. Strebkov, S.Yu. Stefanovich, D.A. Kiselev, A.M. Kislyuk, 2018, published in Zhurnal Fizicheskoi Khimii, 2018, Vol. 92, No. 6, pp. 947–952.

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Politova, E.D., Kaleva, G.M., Golubko, N.V. et al. Physics and Chemistry of Creating New Titanates with Perovskite Structure. Russ. J. Phys. Chem. 92, 1132–1137 (2018). https://doi.org/10.1134/S0036024418060146

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  • DOI: https://doi.org/10.1134/S0036024418060146

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