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Zinc(II) complexes of 4-aminoantipyrine (AAP). Crystal structure of [Zn(AAP)2Cl2]

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Abstract

Zinc(II) complexes of 4-aminoantipyrine (AAP), [Zn(AAP)2X2] (X = Cl–, I–) and [Zn(AAP)(CN)2] · 2H2O were prepared and characterized by elemental analysis, IR and NMR (1H & 13C) spectroscopy. The crystal structure of [Zn(AAP)2Cl2] (1) was determined by X-ray crystallography. The structural analysis of 1 shows that the complex exists as a monomeric nonionic molecule with zinc atom bound to two AAP ligands and two chloride ions adopting a distorted tetrahedral geometry. In [Zn(AAP)2(CN)2] · 2H2O, the appearance of a band at 2162 cm–1 in IR and resonances around 142 ppm in the 13C NMR spectra indicated the binding of cyanide to zinc(II).

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Authors and Affiliations

  1. Department of Chemistry, Minhaj University, Township, Lahore, Pakistan

    Muhammad Muhsin Faraz

  2. Department of Chemistry, King Fahd University of Petroleum and Minerals, Dhahran, 31261, Saudi Arabia

    Anvarhusein A. Isab

  3. Department of Chemistry, College of Sciences and Humanities, Prince Sattam bin Abdulaziz University, Al-Kharj, 11942, Saudi Arabia

    Mshari A. Alotaibi, Abdulrahman I. Alharthi & Saeed Ahmad

  4. Department of Physics, University of Sargodha, Sargodha, 40100, Pakistan

    Muhammad Nawaz Tahir

  5. Department of Chemistry, Government Islamia by Dyal Singh College, Lahore, Pakistan

    Muhammad Monim-ul-Mehboob

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  1. Muhammad Muhsin Faraz
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  2. Anvarhusein A. Isab
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  3. Mshari A. Alotaibi
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  4. Abdulrahman I. Alharthi
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  5. Muhammad Nawaz Tahir
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  7. Saeed Ahmad
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Correspondence to Saeed Ahmad.

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Faraz, M.M., Isab, A.A., Alotaibi, M.A. et al. Zinc(II) complexes of 4-aminoantipyrine (AAP). Crystal structure of [Zn(AAP)2Cl2]. Russ. J. Inorg. Chem. 62, 925–930 (2017). https://doi.org/10.1134/S0036023617070075

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  • DOI: https://doi.org/10.1134/S0036023617070075

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