Skip to main content
SpringerLink
Log in

Hydroxyapatite nanoparticle prepared by controlled precipitation from aqueous phase

  • Synthesis and Properties of Inorganic Compounds
  • Published:
Russian Journal of Inorganic Chemistry Aims and scope Submit manuscript

Abstract

Hydroxyapatite nanoparticles (NPs) were prepared by controlled precipitation in the presence of stabilizers that confined growth and inhibited the aggregation of nanoparticles. Electrostatically stabilized NPs were prepared in the presence of sodium citrate; Tween 80 was used for steric stabilization. At low stabilizer concentrations, nanorods were formed of grown together, spheroidal hydroxyapatite NPs of ~20 nm in diameter. The rod length decreased as ether sodium citrate or Tween 80 concentration increased. When Cit3–/Ca2+ = 3mol/mol, platelike NPs were formed 20–45 nm long and ~10 nm wide; for Cit3–/Ca2+ = 4 mol/mol, NPs had sizes of 10–15 nm. At relatively high Tween 80 concentrations (>0.05 mol/L), foamlike structures were obtained.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. S. V. Dorozhkin, Acta Biomater. 6, 715 (2010).

    Article  CAS  Google Scholar 

  2. V. P. Orlovskii, V. S. Komlev, and S. M. Barinov, Inorg. Mater. 38, 973 (2002).

    Article  CAS  Google Scholar 

  3. J. L. Ong and D. C. N. Chan, Crit. Rev. Biomed. Eng. 28, 667 (1999).

    Article  Google Scholar 

  4. T. T. Morgan, H. S. Muddana, E. I. Altinoglu, et al., Nano Lett. 8, 4108 (2008).

    Article  CAS  Google Scholar 

  5. Y. Guo, D. Shi, J. Lian, et al., Nanotecnology 19, 175102 (2008).

    Article  Google Scholar 

  6. S.-D. Jiang, Q. -Z. Yao, G.-T. Zhou, and S.-Q. Fu, J. Phys. Chem. C 116, 4484 (2012).

    Article  CAS  Google Scholar 

  7. C. C. Fuller, J. R. Bargar, J. A. Davis, and M. J. Piana, Environ. Sci. Technol. 36, 158 (2002).

    Article  CAS  Google Scholar 

  8. J. Morales, J. Torrent-Burgués, T. Boix, et al., Cryst. Res. Technol. 36, 15 (2001).

    Article  Google Scholar 

  9. K. H. Prakash, R. Kumar, C. P. Ooi, et al., J. Phys. Chem. B 110, 24457 (2006).

    Article  CAS  Google Scholar 

  10. J. Wang and L. L. Shaw, Adv. Mater. 19, 2364 (2007).

    Article  CAS  Google Scholar 

  11. S. Meejoo, W. Maneeprakorn, and P. Winotai, Thermochim. Acta 447, 115 (2006).

    Article  CAS  Google Scholar 

  12. A. V. Kuznetsov, A. S. Fomin, A. G. Veresov, et al. Russ. J. Inorg. Chem. 53, 1 (2008).

    Article  Google Scholar 

  13. M. Jevtic, M. Mitric, S. Škapin, et al., Cryst. Growth & Des. 8, 2217 (2008).

    Article  CAS  Google Scholar 

  14. C. Zhang, J. Yang, Z. Quan, et al., Cryst. Growth & Des. 9, 2725 (2009).

    Article  CAS  Google Scholar 

  15. I. S. Neira, Y. V. Kolen’ko, O. I. Lebedev, et al. Cryst. Growth & Des. 9, 466 (2009).

    Article  CAS  Google Scholar 

  16. M. Uota, H. Arakawa, N. Kitamura, et al., Langmuir 21, 4724 (2005).

    Article  CAS  Google Scholar 

  17. Y.-Y. Hu, X. P. Liu, X. Ma, et al., Chem. Mater. 23, 2481 (2011).

    Article  CAS  Google Scholar 

  18. L. S. Skogareva, V. K. Ivanov, A. E. Baranchikov, et al., Russ. J. Inorg. Chem. 60, 1 (2015).

    Article  CAS  Google Scholar 

  19. C. Andres, V. Sinani, D. Lee, et al., J. Mater. Chem. 16, 3964 (2006).

    Article  CAS  Google Scholar 

  20. J. Turkevich, P. L. Stevenson, and J. Hillier, Discuss. Faraday Soc. 11, 55 (1951).

    Article  Google Scholar 

  21. M. Yu. Koroleva, D. A. Kovalenko, V. M. Shkinev, et al., Russ. J. Inorg. Chem. 56, 6 (2011).

    Article  CAS  Google Scholar 

  22. M. Yu. Koroleva, E. V. Gulyaeva, E. V. Yurtov, et al., Russ. J. Inorg. Chem. 58, 1034 (2013).

    Article  CAS  Google Scholar 

  23. T. R. Bates, C. H. Nightingale, and E. Dixon, J. Pharm. Pharmac. 25, 470 (1973).

    Article  CAS  Google Scholar 

  24. G. Rong, J. Yang, and S. E. Friberg, Langmuir 12, 4286 (1996).

Download references

Author information

Authors and Affiliations

  1. Mendeleev University of Chemical Technology, Miusskaya sq. 9, Moscow, 125047, Russia

    M. Yu. Koroleva, E. Yu. Fadeeva & E. V. Yurtov

  2. Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences, ul. Kosygina 4, Moscow, 119991, Russia

    V. M. Shkinev & O. N. Katasonova

Authors
  1. M. Yu. Koroleva
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. Yu. Fadeeva
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. M. Shkinev
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. O. N. Katasonova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. E. V. Yurtov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to M. Yu. Koroleva.

Additional information

Original Russian Text © M.Yu. Koroleva, E.Yu. Fadeeva, V.M. Shkinev, O.N. Katasonova, E.V. Yurtov, 2016, published in Zhurnal Neorganicheskoi Khimii, 2016, Vol. 61, No. 6, pp. 710–716.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Koroleva, M.Y., Fadeeva, E.Y., Shkinev, V.M. et al. Hydroxyapatite nanoparticle prepared by controlled precipitation from aqueous phase. Russ. J. Inorg. Chem. 61, 674–680 (2016). https://doi.org/10.1134/S0036023616060127

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036023616060127

Search

Navigation