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Influence of the fluoride ion on the aggregation and catalytic properties of micellar solutions of cetyltrimethylammonium bromide

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Abstract

The influence of the fluoride ion on the aggregation behavior and catalytic properties of neutral and alkaline aqueous solutions of cetyltrimethylammonium bromide in nucleophilic substitution reactions of phosphorus acid esters was studied by tensiometry, small-angle neutron scattering, and UV spectrophotometry. The critical micelle concentrations and the radii, aggregation numbers, and shape of micelles forming in these systems, as well as the kinetic parameters of the nucleophilic substitution reactions of phosphorus acid esters, were determined.

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Authors and Affiliations

  1. Kazan State Technological University, Kazan, 420015, Tatarstan, Russia

    R. F. Bakeeva, I. S. Razina & V. F. Sopin

  2. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center, Russian Academy of Sciences, Kazan, 420083, Tatarstan, Russia

    E. M. Kosacheva, D. B. Kudryavtsev & L. A. Kudryavtseva

  3. Joint Institute for Nuclear Research, Dubna, Moscow oblast, 141980, Russia

    Yu. S. Kovalev & A. I. Kuklin

Authors
  1. R. F. Bakeeva
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  2. E. M. Kosacheva
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  3. I. S. Razina
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  4. D. B. Kudryavtsev
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  5. Yu. S. Kovalev
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  6. A. I. Kuklin
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  7. L. A. Kudryavtseva
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  8. V. F. Sopin
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Correspondence to R. F. Bakeeva.

Additional information

Original Russian Text © R.F. Bakeeva, E.M. Kosacheva, I.S. Razina, D.B. Kudryavtsev, Yu.S. Kovalev, A.I. Kuklin, L.A. Kudryavtseva, V.F. Sopin, 2008, published in Kinetika i Kataliz, 2008, Vol. 49, No. 5, pp. 661–668.

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Bakeeva, R.F., Kosacheva, E.M., Razina, I.S. et al. Influence of the fluoride ion on the aggregation and catalytic properties of micellar solutions of cetyltrimethylammonium bromide. Kinet Catal 49, 631–637 (2008). https://doi.org/10.1134/S0023158408050066

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  • DOI: https://doi.org/10.1134/S0023158408050066

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