skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Effect of A–site substitutions on energy storage properties of BaTiO3–BiScO3 weakly coupled relaxor ferroelectrics

Abstract

Abstract Weakly coupled relaxors based on compositions (1‐ x ) BaTiO 3 ‐ x Bi Me O 3 , where Me is a metal ion, have attracted attention as potential candidates for high‐temperature high‐energy density capacitors. However, the necessary Bi content is typically high with x  = 0.3‐0.4. In order to reduce problems associated with compatibility for base metal electrodes and due to additional problems due to Bi volatility, it is desirable to lower the Bi content in the overall composition for these materials. Here, we have explored a possible way to reduce BiMeO 3 content through additional A‐site substitutions viz. Ca and Sn. The relaxor nature and energy storage properties of Sn‐modified (Ba,Ca)(Ti)O 3 ‐BiScO 3 ceramics were determined from their dielectric and ferroelectric behaviors. The material showed attractive properties in terms of a frequency‐independent (200 Hz‐1 MHz) dielectric response from room temperature to 200°C, extremely low loss and high‐energy storage efficiency. The structural phenomena underlying the functional properties of Sn‐modified (Ba,Ca)TiO 3 ‐BiScO 3 are characterized from temperature‐dependent X‐ray diffraction and pair distribution function analysis. In broader terms, the study illustrates the potential for tailoring relaxor behavior in Pb‐free ferroelectrics by combining phenomena, such as quantum fluctuations and lone pair stereochemicalmore » effect associated with different solid‐solution substitutions.« less

Authors:
 [1];  [1];  [1]; ORCiD logo [2];  [3];  [3]; ORCiD logo [1]
  1. City Univ. of Hong Kong (Hong Kong)
  2. Aarhus Univ., Aarhus C (Denmark); Lund Univ., Lund (Sweden)
  3. Argonne National Lab. (ANL), Argonne, IL (United States)
Publication Date:
Research Org.:
Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Org.:
City University of Hong Kong; Aarhus University; Danish Ministry of Higher Education and Science - Danish Agency for Science, Technology and Innovation; Danish National Research Foundation; USDOE
OSTI Identifier:
1561219
Alternate Identifier(s):
OSTI ID: 1506133
Grant/Contract Number:  
AC02-06CH11357
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Journal of the American Ceramic Society
Additional Journal Information:
Journal Volume: 102; Journal Issue: 10; Journal ID: ISSN 0002-7820
Publisher:
American Ceramic Society
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE; ferroelectric materials; structure; X-ray methods; capacitors; dielectric relaxation; ferroelectricity

Citation Formats

Nayak, Sanjib, Venkateshwarlu, Sarangi, Budisuharto, Anthony Setiadi, Jørgensen, Mads Ry Vogel, Borkiewicz, Olaf, Beyer, Kevin A., and Pramanick, Abhijit. Effect of A–site substitutions on energy storage properties of BaTiO3–BiScO3 weakly coupled relaxor ferroelectrics. United States: N. p., 2019. Web. doi:10.1111/jace.16449.
Nayak, Sanjib, Venkateshwarlu, Sarangi, Budisuharto, Anthony Setiadi, Jørgensen, Mads Ry Vogel, Borkiewicz, Olaf, Beyer, Kevin A., & Pramanick, Abhijit. Effect of A–site substitutions on energy storage properties of BaTiO3–BiScO3 weakly coupled relaxor ferroelectrics. United States. https://doi.org/10.1111/jace.16449
Nayak, Sanjib, Venkateshwarlu, Sarangi, Budisuharto, Anthony Setiadi, Jørgensen, Mads Ry Vogel, Borkiewicz, Olaf, Beyer, Kevin A., and Pramanick, Abhijit. 2019. "Effect of A–site substitutions on energy storage properties of BaTiO3–BiScO3 weakly coupled relaxor ferroelectrics". United States. https://doi.org/10.1111/jace.16449. https://www.osti.gov/servlets/purl/1561219.
@article{osti_1561219,
title = {Effect of A–site substitutions on energy storage properties of BaTiO3–BiScO3 weakly coupled relaxor ferroelectrics},
author = {Nayak, Sanjib and Venkateshwarlu, Sarangi and Budisuharto, Anthony Setiadi and Jørgensen, Mads Ry Vogel and Borkiewicz, Olaf and Beyer, Kevin A. and Pramanick, Abhijit},
abstractNote = {Abstract Weakly coupled relaxors based on compositions (1‐ x ) BaTiO 3 ‐ x Bi Me O 3 , where Me is a metal ion, have attracted attention as potential candidates for high‐temperature high‐energy density capacitors. However, the necessary Bi content is typically high with x  = 0.3‐0.4. In order to reduce problems associated with compatibility for base metal electrodes and due to additional problems due to Bi volatility, it is desirable to lower the Bi content in the overall composition for these materials. Here, we have explored a possible way to reduce BiMeO 3 content through additional A‐site substitutions viz. Ca and Sn. The relaxor nature and energy storage properties of Sn‐modified (Ba,Ca)(Ti)O 3 ‐BiScO 3 ceramics were determined from their dielectric and ferroelectric behaviors. The material showed attractive properties in terms of a frequency‐independent (200 Hz‐1 MHz) dielectric response from room temperature to 200°C, extremely low loss and high‐energy storage efficiency. The structural phenomena underlying the functional properties of Sn‐modified (Ba,Ca)TiO 3 ‐BiScO 3 are characterized from temperature‐dependent X‐ray diffraction and pair distribution function analysis. In broader terms, the study illustrates the potential for tailoring relaxor behavior in Pb‐free ferroelectrics by combining phenomena, such as quantum fluctuations and lone pair stereochemical effect associated with different solid‐solution substitutions.},
doi = {10.1111/jace.16449},
url = {https://www.osti.gov/biblio/1561219}, journal = {Journal of the American Ceramic Society},
issn = {0002-7820},
number = 10,
volume = 102,
place = {United States},
year = {Fri Mar 22 00:00:00 EDT 2019},
month = {Fri Mar 22 00:00:00 EDT 2019}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record

Citation Metrics:
Cited by: 27 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Current Understanding of Structure–Processing–Property Relationships in BaTiO 3 –Bi( M )O 3 Dielectrics
journal, September 2016


Local structure in BaTi O 3 BiSc O 3 dipole glasses
journal, March 2016


High-Energy Density Capacitors Utilizing 0.7 BaTiO 3 -0.3 BiScO 3 Ceramics
journal, August 2009


Recent progress in relaxor ferroelectrics with perovskite structure
journal, January 2006


Ferroelectric and Piezoelectric Properties of KNbO 3 Ceramics Containing Small Amounts of LaFeO 3
journal, September 2003


Relaxor Behavior and Dielectric Properties of Bi(Zn2/3Nb1/3)O3-Modified BaTiO3 Ceramics
journal, September 2015


Analysis of Recent Measurements of the Viscosity of Glasses
journal, June 1925


Anomalous Phase Diagram of Ferroelectric ( Ba , Ca ) TiO 3 Single Crystals with Giant Electromechanical Response
journal, June 2008


Electric vehicles with individually controlled on-board motors: Revisiting the ABS design
conference, March 2015


Re-entrant relaxor behavior in BaTiO 3 -Bi(Zn 2/3 Nb 1/3 )O 3 ceramics
journal, November 2016


Ferroelectric phase transition in Sn2+ ions doped (Ba,Ca)TiO3 ceramics
journal, March 2010


Crossover from relaxor to normal ferroelectric behaviour in (1−x)Pb(Mg1/3Nb2/3)O3−xPbZrO3 ceramic near x=0.5
journal, May 2001


Giant Dielectric Permittivity Observed in Pb-Based Perovskite Ferroelectrics
journal, April 2001


Correlated rattling-ion origins of dielectric properties in reentrant dipole glasses BaTiO 3 -BiScO 3
journal, November 2015


Recent advances in magnetic structure determination by neutron powder diffraction
journal, October 1993


Effect of Sn 2+ Ion Substitution on Dielectric Properties of (Ba,Ca)TiO 3 Ferroelectric Ceramics
journal, September 2010


Soft Ferroelectric Modes in Lead Titanate
journal, July 1970


Relaxor Ferroelectric BaTiO 3 -Bi(Mg 2/3 Nb 1/3 )O 3 Ceramics for Energy Storage Application
journal, November 2014


The Changing Automotive Environment: High-Temperature Electronics
journal, July 2004


Structure and Dielectric Properties of BaTiO 3 -BiYO 3 Perovskite Solid Solutions
journal, February 2014


A low-inductance DC bus capacitor for high power traction motor drive inverters
conference, January 2002


Average and local structure of the Pb-free ferroelectric perovskites ( Sr , Sn ) TiO 3 and ( Ba , Ca , Sn ) TiO 3
journal, December 2015


Lead-free BaTiO 3 –Bi(Zn 2/3 Nb 1/3 )O 3 weakly coupled relaxor ferroelectric materials for energy storage
journal, January 2016


Local and average structures of BaTiO3-Bi(Zn1/2Ti1/2)O3
journal, November 2016


BaTiO 3 -Bi(Zn 1/2 Ti 1/2 )O 3 -BiScO 3 Ceramics for High-Temperature Capacitor Applications
journal, July 2012


Weakly Coupled Relaxor Behavior of BaTiO 3 -BiScO 3 Ceramics
journal, January 2009


Neutron-Scattering Study of Soft Modes in Cubic BaTi O 3
journal, July 1971


Relaxor ferroelectrics
journal, December 1987


Kinetic study of the disproportionation of tin monoxide
journal, September 2001


Relaxing with relaxors: a review of relaxor ferroelectrics
journal, April 2011


Phase transition characteristics and dielectric properties of rare-earth (La, Pr, Nd, Gd) doped Ba(Zr0.09Ti0.91)O3 ceramics
journal, February 2011


Critical exponents of the dielectric constants in diffused-phase-transition crystals
journal, April 1982


Large electrocaloric response and high energy-storage properties over a broad temperature range in lead-free NBT-ST ceramics
journal, February 2016


The large Debye–Scherrer camera installed at SPring-8 BL02B2 for charge density studies
journal, December 2001


Dielectric Relaxation in BaTiO3-Bi(Zn1/2Ti1/2)O3 Ceramics
journal, December 2011


Critical exponents of the dielectric constants in diffused-phase-transition crystals
journal, January 1982


Analysis of Recent Measurements of the Viscosity of Glasses
journal, May 1992


The large Debye–Scherrer camera installed at SPring-8 BL02B2 for charge density studies
journal, July 2001


Giant Dielectric Permittivity Observed in Pb-Based Perovskite Ferroelectrics
text, January 2001


Relaxor Ferroelectrics
journal, January 1991