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Inhibition effect of some organic N‐containing compounds in acidic corrosion of carbonized steel

Florida I. Halilova (Department of Chemistry, Baku State University, Baku, Azerbaijan)
Ramiz M. Aliguliyev (Azerbaijan State Research Institute of Olefins, Baku, Azerbaijan)
Zakir M.O. Rzaev (Department of Chemistry, Hacettepe University, Ankara, Turkey)

Anti-Corrosion Methods and Materials

ISSN: 0003-5599

Article publication date: 1 February 2001

458

Abstract

The influence of some N‐containing organic compounds such as tetraethanol‐β‐octadecenyl succinylamide (TOSA), morphonil‐β‐hexenyl succinylamide (MHSA), ammonium naphthenyltri‐n‐butyl chloride (ANBC) and 1‐(2,4,6‐trimethylphenyl)‐3‐diethylaminopropanol‐2 (TMAP) as inhibitors for the corrosion of carbonized steel in mineral acid (HCl and H2SO4) solutions with different concentrations has been studied by using gravimetrical, electrochemical and polarization corrosion test methods. Observes that all compounds having surface active properties behave as inhibitors of a functional active cathodic type and have an inhibition effect at the first stage of corrosion in both acids, but more effectively in H2SO4. Shows that inhibition effect increases with increase of temperature in 0.5N H2SO4 solution and decreases with increase of temperature for the higher concentrations of acidic solutions. Shows that TOSA and TMAP compared with MHSA and ANBC enchance protection properties of adsorption layer.

Keywords

Citation

Halilova, F.I., Aliguliyev, R.M. and Rzaev, Z.M.O. (2001), "Inhibition effect of some organic N‐containing compounds in acidic corrosion of carbonized steel", Anti-Corrosion Methods and Materials, Vol. 48 No. 1, pp. 18-31. https://doi.org/10.1108/00035590110365282

Publisher

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MCB UP Ltd

Copyright © 2001, MCB UP Limited

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