The study of simple metal clusters has burgeoned in the last decade, motivated by the growing interest in the evolution of physical properties from the atom to the bulk solid, a progression passing through the domain of atomic clusters. On the experimental side, the rapid development of new techniques for producing the clusters and for probing and detecting them has resulted in a phenomenal increase in our knowledge of these systems. For clusters of the simplest metals, the alkali and noble metals, the electronic structure is dominated by the number of valence electrons, and the ionic cores are of secondary importance. These electrons are delocalized, and the electronic system exhibits a shell structure that is closely related to the well-known nuclear shell structure. In this article the results from a broad range of experiments are reviewed and compared with theory. Included are the behavior of the mass-abundance spectra, polarizabilities, ionization potentials, photoelectron spectra, optical spectra, and fragmentation phenomena.

DOI:https://doi.org/10.1103/RevModPhys.65.611