Low-Temperature Anomalies in Strong and Fragile Glass Formers

A. P. Sokolov, R. Calemczuk, B. Salce, A. Kisliuk, D. Quitmann, and E. Duval
Phys. Rev. Lett. 78, 2405 – Published 24 March 1997
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Abstract

The low-temperature anomalies of glass forming systems are analyzed focusing on the concept of fragility. It is shown that two extremes on the fragility plot, SiO2 and Ca0.4K0.6(NO3)1.4, show a strong difference in specific heat in the range of excess vibrational contribution. This difference cannot be explained in the framework of the soft potential model in its present state. A relation between the excess vibrational contribution and the amount of structural fluctuations is suggested. It is shown that the suggested relation explains the found difference in low-temperature specific heat between strong and fragile glass formers.

  • Received 9 May 1996

DOI:https://doi.org/10.1103/PhysRevLett.78.2405

©1997 American Physical Society

Authors & Affiliations

A. P. Sokolov

  • Max-Planck-Institut für Polymerforschung, 55128 Mainz, Germany

R. Calemczuk and B. Salce

  • Commissariat à l'Energie Atomique, SPSMS/LCP, 38054 Grenoble Cedex 9, France

A. Kisliuk and D. Quitmann

  • Institut für Experimentalphysik, FU-Berlin, 14195 Berlin, Germany

E. Duval

  • Laboratoire de Physico-Chimie des Materiaux Luminescents, Universite Lyon 1, France

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Vol. 78, Iss. 12 — 24 March 1997

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