Viscous flow in supercooled liquids analyzed in terms of transport theory for random media with energetic disorder

H. Bässler
Phys. Rev. Lett. 58, 767 – Published 23 February 1987
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Abstract

Viscosity data for supercooled liquids are reexamined in terms of the random-potential model with use of the concept developed for treatment of electronic transport in random media with energetic disorder. η(T) is found to obey the predicted exp[(T0/T)2] law covering 10 decades in η and extending to the glass transition which is considered to be a kinetic localization phenomenon. The crucial system paramter is the width σ of the (Gaussian) distribution of states which determines both the glass transition temperature and the T dependence of η via the characteristic temperature T0∝σ.

  • Received 9 September 1986

DOI:https://doi.org/10.1103/PhysRevLett.58.767

©1987 American Physical Society

Authors & Affiliations

H. Bässler

  • Fachbereich Physikalische Chemie, Philipps-Universitat, D-3550 Marburg, Federal Republic of Germany

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Issue

Vol. 58, Iss. 8 — 23 February 1987

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