Anomalous Frequency-Dependent Conductivity of Polyacetylene

A. J. Epstein, H. Rommelmann, M. Abkowitz, and H. W. Gibson
Phys. Rev. Lett. 47, 1549 – Published 23 November 1981
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Abstract

The frequency (f) and temperature (T) dependent conductivity (σ) is reported for cis-(CH)x, trans-(CH)x, and ammonia-compensated (CH)x. A strongly T-dependent dc σ together with a weakly T-dependent ac σ were observed for predominantly cis-(CH)x and for NH3-compensated samples, similar to σ(f,t) of many semiconductors. The trans-(CH)x has a larger "weakly" T-dependent dc σ and anomalous strongly T-dependent ac σ. The latter results are in good agreement with Kivelson's theory of charge transport via intersoliton electron hopping.

  • Received 10 August 1981

DOI:https://doi.org/10.1103/PhysRevLett.47.1549

©1981 American Physical Society

Authors & Affiliations

A. J. Epstein, H. Rommelmann, M. Abkowitz, and H. W. Gibson

  • Xerox Webster Research Center, Webster, New York 14580

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Issue

Vol. 47, Iss. 21 — 23 November 1981

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