Relaxor Pb(Mg1/3Nb2/3)O3: A Ferroelectric with Multiple Inhomogeneities

Desheng Fu, Hiroki Taniguchi, Mitsuru Itoh, Shin-ya Koshihara, N. Yamamoto, and Shigeo Mori
Phys. Rev. Lett. 103, 207601 – Published 9 November 2009

Abstract

Despite intensive studies on Pb(Mg1/3Nb2/3)O3 (PMN) relaxor, understanding the exact nature of its giant dielectric response and of its physical ground state is a fundamental issue that has remained unresolved for decades. Here, we report a comprehensive study of PMN relaxor crystal, and show that (i) its anomalous dielectric behavior in a broad temperature range results from the reorientation of polarization in the crystal, and (ii) the PMN relaxor is essentially a nanosized ferroelectric material with multiscale inhomogeneities of domain structure in addition to the well-known inhomogeneities of chemical composition and local symmetry. Such inhomogeneities are believed to play a crucial role in producing the huge and enigmatic physical effects in relaxor system, and may be used to design other new systems with giant effects such as a relaxor system.

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  • Received 2 July 2009

DOI:https://doi.org/10.1103/PhysRevLett.103.207601

©2009 American Physical Society

Authors & Affiliations

Desheng Fu1,2,3, Hiroki Taniguchi3, Mitsuru Itoh3, Shin-ya Koshihara2,4, N. Yamamoto5, and Shigeo Mori6

  • 1Division of Global Research Leaders, Shizuoka University, Johoku 3-5-1, Naka-ku, Hamamatsu 432-8561, Japan
  • 2ERATO, Japan Science and Technology Agency, 3-5 Sanbanchou, Chiyoda-ku, Tokyo 102-0075, Japan
  • 3Materials and Structures Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Yokohama 226-8503, Japan
  • 4Frontier Collaborative Research Center & Department of Materials Science, Tokyo Institute of Technology, Meguro-ku, Tokyo 152-8551, Japan
  • 5Department of Physics, Tokyo Institute of Technology, Oh-okayama, Meguro-ku, 152-8551, Japan
  • 6Department of Materials Science, Osaka Prefecture University, Sakai, Osaka 599-8531, Japan

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Issue

Vol. 103, Iss. 20 — 13 November 2009

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