Abstract
We present a refractive-index-matched colloidal system that allows direct observation of critical Casimir induced aggregation with a confocal microscope. We show that in this system, in which van der Waals forces are negligible, a simple competition between repulsive screened Coulomb and attractive critical Casimir forces can account quantitatively for the reversible aggregation. Above the temperature , the critical Casimir force drives aggregation of the particles into fractal clusters, while below , the electrostatic repulsion between the particles breaks up the clusters, and the particles resuspend by thermal diffusion. The aggregation is observed in a remarkably wide temperature range of as much as . We derive a simple expression for the particle pair potential that accounts quantitatively for the temperature-dependent aggregation and aggregate breakup.
- Received 12 February 2009
DOI:https://doi.org/10.1103/PhysRevLett.103.156101
©2009 American Physical Society