Variation with amphiphilic strength of the properties of ternary mixtures

James Lerczak, M. Schick, and G. Gompper
Phys. Rev. A 46, 985 – Published 1 July 1992
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Abstract

Properties of a ternary system with fixed oil and water components, but an amphiphile of varying strength, are calculated by means of a lattice model and the Landau-Ginzburg free energy it generates. Using the lattice model, we calculate the variation of the amphiphile concentration at the base and apex of the three-phase triangle from the tricritical to the four-phase point, as well as the oil-water interfacial tension and interfacial profiles. These profiles are combined with the Landau-Ginzburg free energy to determine, for the same range of amphiphiles, the bending moduli that describe the nature of the surfactant sheet separating oil and water within the microemulsion.

  • Received 21 February 1992

DOI:https://doi.org/10.1103/PhysRevA.46.985

©1992 American Physical Society

Authors & Affiliations

James Lerczak and M. Schick

  • Department of Physics FM-15, University of Washington, Seattle, Washington 98195

G. Gompper

  • Sektion Physik der Ludwig-Maximilians-Universität München, 8000 München 2, Germany

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Vol. 46, Iss. 2 — July 1992

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